• Title/Summary/Keyword: $D_2{^+}$ retention

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Influence factors and Efficiencies Characteristics for Treatment of Wastewater Containing Phenol (Phenol 함유폐수의 처리를 위한 영향인자와 성능특성)

  • Kang, Sun-Tae;Kim, Jeong-Mog
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.4
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    • pp.119-126
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    • 1996
  • Influence factors and efficiency characteristics for treatment of wastewater containing phenol were studied with using Pseudomonas sp. B3. It took 130 hours to remove phenol, when only activated sludge of terminal disposal palnt of sewage was innoculated in batch culture, but it was required just 36 hours, when bacteria degrading phenol and activated sludge were simultaneously innoculated. If only phenol an carbon source was used, it necessary 36 hours for biodegradation of phenol, while glucose was added to medium, it took 73 hours. It was revealed as excellent effluent and SVI, when the F/M ratio, COD and phenol concentration were 53mg/l and 1.2mg/l, respectively, and optimum F/M ratio was revealed 0.31. The reactor were seriously shocked as reducing hydraulic retention time at constant phenol concentration more than increasing phenol concentration at constant hydraulic retention time, when volumetric loading rate was increased to $0.8kg\;phenol/m^3{\codt}d$ from $1.6kg\;phenol/m^3{\codt}d$. And also the effluent phenol concentration was 34mg/l after starting 12 hours of shocking and reactor was recovered as steady state after 65 hours of changing in the former test. Although the effluent phenol concentration was maximum value with 12mg/l after starting 20 hours of shocking and reactor was recovered as steady state after 54 hours of changing in the later test.

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Enhanced Stability of LiCoO2 Cathodes in Lithium-ion Batteries Using Surface Modification by Atomic Layer Deposition

  • Jung, Yoon-S.;Cavanagh, Andrew S.;Dillon, Anne C.;Groner, Markus D.;George, Steven M.;Lee, Se-Hee
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.61-65
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    • 2010
  • Ultrathin atomic layer deposition (ALD) coatings were found to enhance the performance of lithium-ion batteries (LIBs). Previous studies have demonstrated that $LiCoO_2$ cathode powders coated with metal oxides with thicknesses of $\sim100-1000{\AA}$ grown using wet chemical techniques improved LIB performance. In this study, $LiCoO_2$ powders were coated with conformal $Al_2O_3$ ALD films with thicknesses of only $\sim3-4{\AA}$ established using 2 ALD cycles. The coated $LiCoO_2$ powders exhibited a capacity retention of 89% after 120 charge-discharge cycles in the 3.3~4.5 V (vs. $Li/Li^+$) range. In contrast, the bare $LiCoO_2$ powders displayed only a 45% capacity retention. This dramatic improvement may result from the ultrathin $Al_2O_3$ ALD film acting to minimize Co dissolution or to reduce surface electrolyte reactions.

A study of Recess Channel Array Transistor with asymmetry channel for high performance and low voltage Mobile 90nm DRAMs (고성능 저전압 모바일향 90nm DRAM을 위한 비대칭 채널구조를 갖는 Recess Channel Array Transistor의 제작 및 특성)

  • Kim, S.B.;Lee, J.W.;Park, Y.K.;Shin, S.H.;Lee, E.C.;Lee, D.J.;Bae, D.I.;Lee, S.H.;Roh, B.H.;Chung, T.Y.;Kim, G.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.163-166
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    • 2004
  • 모바일향 90nm DRAM을 개발하기 위하여 비대칭 채널 구조를 갖는 Recess Channel Array Transistor (RCAT)로 cell transistor를 구현하였다. DRAM cell transistor에서 junction leakage current 증가는 DRAM retention time 열화에 심각한 영향을 미치는 요인으로 알려져 있으며, DRAM의 minimum feature size가 점점 감소함에 따라 short channel effect의 영향으로 junction leakage current는 더욱 더 증가하게 된다. 본 실험에서는 short channel effect의 영향에 의한 junction leakage current를 감소시키기 위하여 Recess Channel Array Transistor를 도입하였고, cell transistor의 채널 영역을 비대칭으로 형성하여 data retention time을 증가시켰다. 비대칭 채널 구조을 이용하여 Recess Channel Array Transistor를 구현한 결과, sub-threshold 특성과 문턱전압, Body effect, 그리고, GIDL 특성에는 큰 유의차가 보이지 않았고, I-V특성인 드레인 포화전류(IDS)는 대칭 채널 구조인 transistor 대비 24.8% 정도 증가하였다. 그리고, data retention time은 2배 정도 증가하였다. 본 실험에서 얻은 결과는 향후 저전압 DRAM 개발과 응용에 상당한 기여를 할 것으로 기대된다.

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Electric Power Generation and Treatment Efficiency of Organic Matter on Hydraulic Retention Time in Microbial Fuel Cell Reactor (미생물 연료전지 반응조의 수리학적 체류시간에 따른 유기물질 처리효율과 전력생산)

  • Choi, Chansoo;Lim, Bongsu;Xu, Lei;Song, Gyuho
    • Journal of Korean Society on Water Environment
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    • v.25 no.1
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    • pp.159-166
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    • 2009
  • This study has been attempted to generate electricity, while simultaneously treating artificial organic wastewater using both batch and continuous microbial fuel cells (MFCs). In the batch MFC, current-voltage curve showed an onset potential of -0.69 V vs. Ag/AgCl. The potential range between this potential and 0 potential displayed an available voltage for an automatic production of electric energy and glucose, which was oxidized and treated at the same time. The 486 mg/L glucose solution showed the maximum power of $30mW/m^2$ and the maximum current density of $75mA/m^2$ shown in the power curve. As a result, discharging of the cell containing COD 423 mg/L at the constant current density of $60mA/m^2$ showed a continuous electricity generation for about 22 hours that dropped rapidly due to dissipating of organic material. Total electric energy production was 18.0 Wh. While discharging, the pH change was low and dropped from pH 6.53 to 6.20 then increased to 6.47, then stabilized at this charge. The COD treatment efficiency was found to be 72%. In the continuous MFC, COD removal tends to increase as the hydraulic retention time is increased. At one day of hydraulic retention time as the maximum value reaches the COD removal efficiency, power production rate and power production rate per COD removal that were obtained were 68.8%, $14mW/m^2$, and $20.8mW/m^2/g$ CODrm, respectively. In the continuous MFC, the power production rate per COD removal increases as the hydraulic retention time is increased and decreases as the organic loading rate is increased. At the values lower than an organic loading rate of $1kgCOD/m^3/d$, the values higher than about $18.1mW/m^2/g$ CODrm could be obtained.

Comparison of nitrogen removal efficiency on process stability for granular and immobilized anammox bacteria (공정 안정성에 대한 입상 및 고정화 혐기성 암모늄 산화균의 질소제거효율 비교)

  • Choi, Daehee;Bae, Hyokwan;Jung, Jinyoung;Kim, Sang-Hyoun
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.2
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    • pp.195-206
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    • 2014
  • Immobilization of anaerobic ammonium oxidizing bacteria has been studied to enhance the biomass retention of the slowly growing bacteria and the process stability. The purpose of this study was to compare the nitrogen removal efficiency of granular and immobilized anammox bacteria with poly vinyl alcohol and alginate. The specific anammox activity of the granular, homoginized and immobilized anammox bacteria were $0.016{\pm}0.0002gN/gVSS/d$, $0.011{\pm}0.001gN/gVSS/d$ and $0.007{\pm}0.0005gN/gVSS/d$, respectively. Although the activity decreased to 43.7 % of the original one due to low pH and $O_2$ exposure during the homogination and the immobilization, it was rapidly recovered within 7 days in the following continuous culture. When synthetic T-N concentrations of 100, 200, 400, 800 mg/L were fed, the immobilized anammox bacteria showed higher nitrogen removal efficiencies at all operational conditions than those of granular anammox bacteria. When the sludge retention time was shorten below 30.7 days and the reject water was fed, the nitrite removal efficiency of the granular anammox bacteria dropped to 8 % of the initial value, while that of the immobilized anammox bacteria was maintained over 95 % of the initial one. The immobilization with poly vinyl alcohol and alginate would be a feasible method to improve the performance and stability of the anammox process.

A Study on the Significance of the Colloidal Radiogold Disappearance Rate as a Simple Clinical Liver Function Test (임상간기능검사법(臨床肝機能檢査法)으로서의 교질형방사성금(膠質形放射性金)의 혈중소실율(血中消失率)의 의의(意義)에 관(關)한 연구(硏究))

  • Hong, Chang-Gi
    • The Korean Journal of Nuclear Medicine
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    • v.3 no.1
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    • pp.1-12
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    • 1969
  • Liver functions in diffuse parenchymal liver disease such as cirrhosis of the liver depend largely on the effective hepatic blood flow rather than on the individual cell functions. Clinical methods of measuring the hepatic blood flow were developed recently by the application of colloidal disappearance rate. In order to correlate the radiogold disappearance rate to conventional biochemical liver function tests, 21 normal subjects and 80 cases of cirrhosis of the liver were studied with both methods. The results are summarized as following: 1. The validity of external counting method to measure the blood disappearance rate of colloidal radiogold was confirmed by in vitro counting of the serial blood samples. 2. The blood disappearance rate of collidal radiogold was essentially the same. as the liver uptake rate of colloidal radiogold in normal and cirrhotic subjects with various degrees of functional disturbance. And it seemed there was no serious extrahepatic removal of the colloidal radiogold. 3. The disappearance rate of colloidal radiogold was not significantly changed by the posture change, but was enhanced by ingestion of 500 ml of water. 4. The disappearance rate of colloidal radiogold was not influenced by single dose of Telepaque, while BSP retention was increased after Telepaque. 5. The mean disappearance half time of colloidal radiogold in normal subjects was $2.49{\pm}0.391$(S.D.) minutes. The mean normal disappearance rate constant (K value) was $0.285{\pm}0.0428$(S.D.)/minute. 6. The colloidal radiogold disappearance half time was abnormally prolonged (over 3.2 min.) in $87.7{\pm}3.68$(S.D.) % of cirrhotic subjects. 7. In patients of liver cirrhosis the blood disappearance rate of colloidal radiogold correlated well to serum albumin and globulin levels and BSP retention which were considered to reflect functions of hepatic parenchymal cells. There was, however, no correlation between colloidal disappearance rate and thymol turbidity test, serum glutamic pyruvic transaminase, and serm alkaline phosphatase activities. The latters were considered to be associated with the activity of liver disease.

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Influence of Ionic Liquid for Separation of D-tryptophan and N-CBZ-D-phenylalanine (D-tryptophan과 N-CBZ-D-phenylalanine의 분리에서 이온성 액체의 영향)

  • Jin, Yinzhe;Zheng, Jinzhu;Polyakova, Yulia;Koo, Yoon Mo;Row, Kyung Ho
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.453-459
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    • 2006
  • D-tryptophan and N-CBZ-D-phenylalanine were separated using ionic liquid as additives for the mobile phase in high performance liquid chromatography (HPLC). The ionic liquid of 1-butyl-3- methylimidazolium tetrafluoroborate (${[BMIm]}^+{[BF_4]}^-$) was used. Mobile phases were 65%, 70%, and 80% methanol in water with addition of different concentrations (0.5, 1.0, 1.5, 2.0, 4.0, 6.0, 8.0, 10.0, 12.0, and 15.0 mmol/L) of the ionic liquid. The experiments were performed on stainless steel column, $3.9{\times}300mm$ i.d., packed with $15{\mu}m$ octadecyl-bonded silica gel at laboratory.The retention factor of D-tryptophan was not negligibly changed while that of N-CBZ-D-phenylalanine was decreased. The resolution between the two components were affected by the contents of methanol and ionic liquid in the mobile phase. With the small content of methanol and the high concentration of ionic liquid, the resolution was improved.

Water Purification Characteristics of Sedimentation Basin for Agricultural Water Quality Improvement (농업용수 수질개선을 위한 침강지의 수질정화 특성)

  • Kim, Hyungjoong;Kim, Donghwan
    • KCID journal
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    • v.21 no.1
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    • pp.55-63
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    • 2014
  • A sedimentation basin for agricultural water quality improvement was researched to analyze the water quality purification characteristics. The sedimentation basin constructed at the inlet of Gamdon reservoir in Muan-gun, Jeollanam-do was selected as the research field of this study. The surface area of the sedimentation basin is $34,000m^2$, volume is $122,000m^3$, and hydraulic retention time is 0.3hr~7.3day. The average influent loading of SS was 156.6kg-SS/d, and the effluent loading was 67.5kg-SS/d with the average removal rate of 56.9%. The average influent loadings of BOD and COD were 33.0kg-BOD/d and 60.3kg-COD/d respectively, and the effluent loadings were 26.4kg-BOD/d and 48.6kg-COD/d with the average removal rate of 20.1% and 19.3% respectively. Therefore, the results of this study show that a sedimentation basin can purify SS and organic matters. The average influent loadings of T-N and T-P were 28.7kg-TN/d and 2.97kg-TP/d respectively, and the effluent loadings were 16.3kg-TN/d and 1.41kg-TP/d with the average removal rate of 43.0% and 52.6% respectively. In conclusion, the overall results of this study show that a sedimentation basin is a feasible alternative to purify organic matters and nutrients.

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Multi Analysis of Fumigants in Soil and Water (물과 토양에서 훈증제의 동시분석법 확립)

  • Kim, Jung-Ho
    • Environmental Analysis Health and Toxicology
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    • v.21 no.4 s.55
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    • pp.365-373
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    • 2006
  • Emission of methyl bromide (MeBr) from soil was implicated in stratospheric ozone depletion. To determine multi analysis of alternatives fumigants for MeBr, this paper describes the methods of analysis in water and soil. The MeBr, methyl iodide (Mel), propargyl bromide (PBr), cis 1,3-dichloropropene (cis 1,3-D), trans 1,3-dichloropropene (trans 1,3-D) and chloropicrin(CP) are separated on the base line on GC-ECD at three column of AT+DB+DB (90m) with temperature programing of $35^{\circ}C{\rightarrow}110^{\circ}C$ on GC-ECD. The relative retention time for MeBr, Mel, PBr, cis 1,3-D, trans 1,3-D and CP is 1.0, 1.4, 2.3, 3.2, 3.6 and 3.7, respertively. The detection limit for MeBr, Mel, PBr, cis 1,3-D, trans 1,3-D and CP is 469 pg, 5 pg, 21 pg, 79 pg, 101 PE and 5pg, respectively. Recovery of MeBr Mel, PBr, cis 1,3-D, trans 1,3-D and CP in water added 150 ppm fumigants were 81%, 96%, 95%, 97%, 98% and 99%, respectively. Recovery of MeBr, MeI, PBr, cis 1, 3-D, trans 1,3-D and CP in soil added 150ppm fumigants were 56%, 84%), 85%, 81%, 87% and 88%, respectively.

Nutrient Requirements of Exercising Swamp Buffalo, Bubalus bubalis, from Materials Balance and In Vivo Body Composition by the Body Density Method. I. Aspects of Energy and Protein Metabolism in Working Cows

  • Mahardika, IG.;Sastradipradja, D.;Sutardi, T.;Sumadi, IK.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.5
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    • pp.605-612
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    • 2000
  • Four young swamp buffalo cows of similar age ranging in weight between 280 to 380 kg and trained to do physical work were used in a study to determine energy and protein requirements for draught using a $4{\times}4$ Latin square designed experiment. The experiment consisted of field trials employing 4 levels of work load, e.g. no work as control, and loads amounting 450 to 500 Newton (N) pulled continuously for 1, 2 and 3 h daily for 14 consecutive days. Cows were fed king grass (Penisetum purpuroides) ad libitum and were subjected to materials balance trials. Body composition was estimated in vivo by the body density method and daily energy expenditure (EE) was calculated from ME minus retained energy (RE). The results show that EE while not working ($EE_{resting}$) was $0.42kgW^{0.75}MJ/d$ and maintenance ME ($ME_m$) was $0.37kgW^{0.75}MJ/d$. ME requirement increased to 1.65 times maintenance for the work of 3 hours. The energy expended for doing exercise ($E_{exercise}$) was 9.56, 20.0 and 25.86 MJ/cow for treatments 1, 2 and 3 II, respectively. Fat retention was absent in all groups of working cows, but protein retention was only negative for cows undertaking 3 h work. The relationship between $E_{exercise}$ (MJ), work load (F, kN), work duration (t, h) and body mass (W, kg) was found to be: $E_{exercise}=(0.003F^{1.43}t^{0.93})/W^{0.09}MJ$. The maintenance requirement for digestible protein was $2.51kgW^{0.75}g/d$, whereas digestible protein for growth ($DP_{growth}$) and for work ($DP_{work}$) followed the equations: $DP_{growth}=[(258+1.25W^{0.75}){\Delta}Wkg/d]g$ and $DP_{work}=[12.59e^{0.95t}]g$, respectively The coefficients a, b and c for the calculation of $E_{exercise}$ components according to the Lawrence equation were found to be 2.56 J/kgW.m, 5.2 J/kg load carried.m and 0.29, respectively, thus efficiencies to convert ME into work were 0, 16.09, 27.3 and 32.44% for control, 1, 2 and 3 h/d work, respectively. ME and DP requirements for a 250 to 400 kg working buffalo cow allowing to growth up to 0.5 kg/d are presented.