• 제목/요약/키워드: $Bi_{2}O_{2}$

검색결과 1,544건 처리시간 0.032초

울산광산산(蔚山鑛山産) 유비철석(硫砒鐵石)의 조성변화(組成變化) 및 지질온도계(地質溫度計)에 대(對)한 적용(適用) (Compositional Variation of Arsenopyrites in Arsenic and Polymetallic Ores from the Ulsan Mine, Republic of Korea, and their Application to a Geothermometer)

  • 최선규;정재일;이마이 나오야
    • 자원환경지질
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    • 제19권3호
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    • pp.199-218
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    • 1986
  • 울산(蔚山)의 철 중석 스카른광상에서 산출되는 유비철석(硫砒鐵石)은 그의 산출상태(産出狀態) 광물공생관계(鑛物共生關係) 화학조성(化學組成)을 근거로 세 가지 유형으로 구분된다. 유비철석(硫砒鐵石) I 은 다금속광화작용(多金屬鑛化作用) 초기에 정출된 것으로 주로 스카른대 내에서 산점상으로 분포하며, Ni-Fe-Co계 유화물과 밀접한 공생관계를 보여준다. 유비철석(硫砒鐵石) I 의 화학조성은 Ni, Co의 함량이 현저하게 높고 As/S(원자비(原子比))>1으로 과잉(過剩)의 비소를 함유한다. 유비철석(硫砒鐵石) II는 Cu 또는 As 광석중에서 산출되며, 비독사석 휘창연석 비스무스 황동석 섬아연석과 밀접한 공생관계를 보여준다. 유비철석(硫砒鐵石) II의 화학조성은 Ni, Co의 함량이 극히 미량이며, As/S>1으로 과잉(過剩)의 비소를 함유한다. 유비철석(硫砒鐵石) III은 최후기 열수광맥 형성시기에 정출되었으며, 황철석 방연석 섬아연석 자류철석과 밀접한 공생관계(共生關係)를 보여준다. 유비철석(硫砒鐵石) III의 화학조성(化學組成)은 $$As/S1{\leq_-}1$$로 과잉(過剩)의 S를 함유한다. 유비철석(硫砒鐵石) I 은 Ni, Co의 함유량이 1%이상이므로 지질온도계(地質溫度計)로 사용할 수 없지만, 유비철석(硫砒鐵石) II 는 비스무스-휘창연석의 공생관계(共生關係)를 보여 주고 있으므로, 이를 Kretschmar and Scott (1976)에 의한 $1/T-f(S_2)$도에 적용시켜보면 유비철석(硫砒鐵石) II의 정출환경은 $T=460{\sim}470^{\circ}C$, log $f(S_2)=-7.4{\sim}7.0$이고, 유비철석(硫砒鐵石) III의 정출환경은 $T=320{\sim}440^{\circ}C$, log $f(S_2)=-9.0{\sim}7.0$으로 추정된다.

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우리 나라 복식(服飾)과 서역복식간(西域服飾間)의 공통성(共通性)에 관(關)한 연구(硏究) - 삼국시대(三國時代), 통일신라시대( 統一新羅時代)를 중심(中心)으로 - (A Study on the Common Features of Western Clothing Style and the Style of Korean clothing - Focusing on the Three Kingdom and Unified Shilla era -)

  • 전지은;심화진
    • 패션비즈니스
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    • 제5권4호
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    • pp.127-143
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    • 2001
  • This thesis looks into the characteristics and compares the clothing styles between the Three Kingdom to the Unified Shilla era. The purpose of this study is to see what common themes exists between the foundation of Korean clothing and how it has evolved and through see to what extent the Chinese influence has been to Korean clothing culture. Also by explaining the originality and creativity of Korean clothing, we will be able to make clear the status of Korean culture. These findings include the following; 1. The Korean strait line Gik-ryong Kyo-im can also be found at the Gochang region in the west. 2. The Ban-ryong-ui, worn by the aristocrats of the Three kingdom and Unified Shilla era, began to appear from the nobles from the Nam-Buk cho(South-north era). This combined with a Bokdu(headwear) became a part of casual dress wear. 3. Go(pants) became a traditional part of clothing for Unified Shilla and the west. 4. Ban-bi and Bae-dang, all forms of Bansu-ui ( short sleeve), came from Chinas Kucha and Hotan and came to Korea. 5. Chinas Pae-baek and Pae-za (Shawl) which is the same as Unified Shillas Peo was also to be found to have come from the west. 6. The way a different color line was added to clothing both can be found in Korean and western clothing. Similarities to material used are; First, expensive wool was used and mostly originated from the west. From far away Rome came the O-saek-gae (Five-color wool). Secondly, Kong-gak me (peacock feather) and Bi-chi mo were all originated from the west. Third, Sil-sil is stated in the Sam-kuk Sa-ki (Three Kingdom records) as being prohibited to be worn by Jin-gol women (Highest nobility during Shilla era) as headwear or comb (pin) or as a comb(pin) for yuk-doo poom ( 6th class nobility) women. Suggesting that it existed and other sources tell us that it came from Tashkent region of Russia and was a jewelry of some sort. From what we have seen above, we can see the similarities between Korean and western clothing cultures and that these interactions not only occurred with China but with many other nations. We can see that our ancestors were creative and original that when importing foreign cultures that they transformed them into a Korean style. That these foreign cultures were transformed into our own style is good evidence to these facts.

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담배 형질전환체를 이용한 포도 UDP-glucose flavonoid glucosyl transferase (UFGT) 유전자의 기능 분석 (Functional Analysis of a Grapevine UDP-Glucose Flavonoid Glucosyl Transferase (UFGT) Gene in Transgenic Tobacco Plants)

  • 박지연;박성출;피재호
    • 생명과학회지
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    • 제20권2호
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    • pp.292-297
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    • 2010
  • 페놀화합물인 안토시아닌은 과일, 꽃잎 등 식물 조직에서 청 혹은 적색을 나타내는 색소이다. 포도의 경우, 안토시아닌은 적포도 품종의 과피에만 축적되는데, 이것은 안토시아닌 생합성에 관여하는 효소 중에서 UDP-glucose: flavonoid 3-O-glucosyltransferase(UFGT)를 암호화하는 ufgt 유전자에 의해 조절된다고 보고된 바 있다. ufgt 유전자에 의해 안토시아닌의 축적 양상이 변하는지를 검증하기 위해, 포도로부터 ufgt cDNA를 분리한 다음, 각각 sense와 antisense 방향으로 발현하는 벡터를 제작하고, 이를 야생형 담배에 도입하였다. 담배 형질전환체를 선발하여 RT-PCR을 수행한 결과, 포도 ufgt 유전자가 sense 방향으로 들어간 snese 형질전환체에서는 야생형 담배에 비해 ufgt 전사체의 양이 증가하였고, antisense 방향으로 들어간 antisense 형질전환체에서는 전사체의 양이 도리어 감소하였다. 한편, 담배 형질전환체의 꽃을 분석한 결과, sense 형질전환체의 안토시아닌 함량은 야생형 담배에 비해 최고 44% 증가하였고, antisense 형질전환체에서는 최고 88% 감소하였다. 또한 sense 형질전환체의 꽃 색깔은 야생형 담배에 비해 더 진해졌다. 이러한 결과는 외부로부터 도입된 포도 ufgt 유전자의 발현으로 ufgt 전사체의 양이 증가하면 담배 내 안토시아닌의 함량이 높아지고 꽃 색깔이 진해진다는 것을 시사한다.

청송광산의 동-연-아연 광화작용 (Cu-Pb-Zn Mineralization of the Cheongsong Mine)

  • 이현구;김상중
    • 자원환경지질
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    • 제30권3호
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    • pp.197-207
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    • 1997
  • Rocks in the Cheongsong mine area consist of Precambrian gneiss, Cretaceous sedimentry rocks and late Cretaceous quartz porphyry. The Cheongsong deposit is composed of many hydrothermal quartz veins of strikes $N30^{\circ}{\sim}60^{\circ}W$, dips $60{\sim}85^{\circ}E$ which fill WNW fault system. Pyrite and hematite occur within transparent quartz near margins of early stage II, and milky quartz of middle stage II coexists with sphalerite, chalcopyrite and galena coexisting with Cu-Pb-Bi minerals in center part of stage II quartz veins. Stage III calcite vein filled cracks or fractures of earlier quartz veins contains native copper and chalcopyrite. Supergene minerals are chalcocite, covellite, malanchite and chrysocolla. Alteration minerals are sericite, chlorite, argillite, epitode and pyrite. Ranges of salinities and homogenization temperatures for fluid inclusions in the individual periods of stage II are: 3.7 to 7.8 wt.% eq. NaCl and 200 to $380^{\circ}C$ in transparent quartz of early stage II; 0.7 to 6.4 wt.% eq. NaCl and 200 to $320^{\circ}C$ in milky quartz of middle stage II; 0.0 to 0.9 wt.% eq. NaCl and 250 to $320^{\circ}C$ in calcite of late stage II. Those of stage III calcite range about 0 wt.% eq. NaCl, and from 140 to $260^{\circ}C$, respectively. The relationship between salinities and temperatures shows decrease tendency with paragenetic time from stage II to III. The ${\delta}^{18}O_{H_2O}$ value is 0.5‰ in stage I, range from 0.5 to -0.4‰ in stage II, and from -3.2 to -3.7‰ in stage III. Calcite in the stage II and stage III has ${\delta}^{13}C$ values of -5.0‰ and -4.5 to -4.9‰, respectively. There is a decrease in sulfur fugacity values with paragenetic time of stage II, from $10^{-6.3}$ atm for early mineralization, to $10^{-6.5}$ atm for middle stage, to $10^{-8.0}$ atm for late mineralization of stage II. The results of stable isotope and fluid inclusion indicate that ore fluids reacted with meteoric water and wall rock in the Cheongsong hydrothermal system.

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중량식 라이시미터에서 배추 재배에 따른 질소 용탈과 수지 (Nitrogen Leaching and Balance of Soils Grown with Cabbage in Weighing Lysimeter)

  • 이예진;옥정훈;이슬비;성좌경;송요성;이덕배
    • 한국환경농학회지
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    • 제37권3호
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    • pp.166-171
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    • 2018
  • 중량식 라이시미터를 활용하여 배추 재배 중 식양토와 사양토의 질소 용탈과 질소 수지를 평가하였다. 생육 초기인 9월 초 강우로 인해 식양토와 사양토 모두 토심 150 cm 이하로 배수가 있었다. 식양토는 점토의 수축 및 작물 뿌리 등에 의해 형성된 대공극을 통해 일시적으로 배수량이 증가하였으나, 사양토는 식양토와 달리 강우량에 따라 일정하게 배수량이 증가하고, 감소하였다. 토성별로 질소 용탈량을 분석한 결과, 식양토에서는 비료의 용탈이 거의 없는 반면, 사양토에서는 식양토에 비해 5배 많은 질소 용탈이 있었다. 질소수지에서 작물 흡수량에 비해 질소 용탈량이 차지하는 비율은 적었으나 식양토에 비해 사양토에서의 용탈량이 많아 질소 수지 산정에 토성에 따른 용탈특성을 고려할 필요가 있다.

리튬이온배터리용 도파민이 코팅된 실리콘/실리콘 카바이드 음극복합소재의 전기화학적 특성 (Electrochemical Characteristics of Dopamine coated Silicon/Silicon Carbide Anode Composite for Li-Ion Battery)

  • 김은비;이종대
    • Korean Chemical Engineering Research
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    • 제61권1호
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    • pp.32-38
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    • 2023
  • 본 연구에서는 리튬 이온 배터리 용 음극활물질인 실리콘의 사이클 안정성 및 율속 특성을 개선하기 위해 도파민이 코팅된 실리콘/실리콘카바이드/카본(Si/SiC/C) 복합소재의 전기화학적 특성을 조사하였다. Stöber 법에 CTAB을 추가하여 CTAB/SiO2를 합성한 후 열 흡수제로써 NaCl을 첨가한 마그네슘 열 환원법을 통해 Si/SiC 복합소재를 제조하였으며, 도파민의 중합반응을 통해 탄소코팅을 하여 Si/SiC/C 음극소재를 합성하였다. 제조된 Si/SiC/C 음극소재의 물리적 특성 분석을 위해 SEM, TEM, XRD와 BET를 사용하였으며, 1 M LiPF6 (EC : DEC = 1 : 1 vol%) 전해액에서 리튬 이온 배터리의 사이클 안정성, 율속 특성, 순환전압전류 및 임피던스 테스트를 통해 전기화학적 특성을 조사하였다. 제조된 1-Si/SiC는 100사이클, 0.1 C에서 633 mAh/g의 방전용량을 나타냈으며, 도파민이 코팅된 1-Si/SiC/C는 877 mAh/g으로 사이클 안정성이 향상된 것을 확인할 수 있었다. 또한 5C에서 576 mAh/g의 높은 용량과 0.1 C/0.1 C 일 때 99.9%의 용량 회복 성능을 나타내었다.

화학적기계적연마 공정으로 제조한 BLT Capacitor의 Polishing Damage에 의한 강유전 특성 열화 (Degradation from Polishing Damage in Ferroelectric Characteristics of BLT Capacitor Fabricated by Chemical Mechanical Polishing Process)

  • 나한용;박주선;정판검;고필주;김남훈;이우선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.236-236
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    • 2008
  • (Bi,La)$Ti_3O_{12}$(BLT) thin film is one of the most attractive materials for ferroelectric random access memory (FRAM) applications due to its some excellent properties such as high fatigue endurance, low processing temperature, and large remanent polarization [1-2]. The authors firstly investigated and reported the damascene process of chemical mechanical polishing (CMP) for BLT thin film capacitor on behalf of plasma etching process for fabrication of FRAM [3]. CMP process could prepare the BLT capacitors with the superior process efficiency to the plasma etching process without the well-known problems such as plasma damages and sloped sidewall, which was enough to apply to the fabrication of FRAM [2]. BLT-CMP characteristics showed the typical oxide-CMP characteristics which were related in both pressure and velocity according to Preston's equation and Hernandez's power law [2-4]. Good surface roughness was also obtained for the densification of multilevel memory structure by CMP process [3]. The well prepared BLT capacitors fabricated by CMP process should have the sufficient ferroelectric properties for FRAM; therefore, in this study the electrical properties of the BLT capacitor fabricated by CMP process were analyzed with the process parameters. Especially, the effects of CMP pressure, which had mainly affected the removal rate of BLT thin films [2], on the electrical properties were investigated. In order to check the influences of the pressure in eMP process on the ferroelectric properties of BLT thin films, the electrical test of the BLT capacitors was performed. The polarization-voltage (P-V) characteristics show a decreased the remanent polarization (Pr) value when CMP process was performed with the high pressure. The shape of the hysteresis loop is close to typical loop of BLT thin films in case of the specimen after CMP process with the pressures of 4.9 kPa; however, the shape of the hysteresis loop is not saturated due to high leakage current caused by structural and/or chemical damages in case of the specimen after CMP process with the pressures of 29.4 kPa. The leakage current density obtained with positive bias is one order lower than that with negative bias in case of 29.4 kPa, which was one or two order higher than in case of 4.9 kPa. The high pressure condition was not suitable for the damascene process of BLT thin films due to the defects in electrical properties although the better efficiency of process. by higher removal rate of BLT thin films was obtained with the high pressure of 29.4 kPa in the previous study [2].

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상완 신경총 손상에서 Steindler 주관절 굴곡 성형술 (Steindler Flexoplasty of Elbow in Brachial Plexus Injuries)

  • 한정수;정덕환;정비오;이경원
    • Archives of Reconstructive Microsurgery
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    • 제14권1호
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    • pp.63-69
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    • 2005
  • Purpose: The purpose of this study was to analyze the clinical results after Steindler flexoplasty. Materials and Methods: We analyzed 6 cases who had nearly normal finger and wrist joint flexion function, but could not flex elbow joint actively because of upper arm type brachial plexus injury. We performed operation during the period from February 1997 to July 2003. There were 5 males and 1 female with mean age of 28 years (range: $19{\sim}51$ years) when Steindler flexoplasty was done. The average follow-up period was 3 years 11 months (range: 12 months${\sim}$7 years 4 months). We assessed active range of motion of elbow joint, muscle power and elbow function by Mayer & Green grade scale at last follow-up. We assessed how much they were favorable for Steindler flexoplasty and had improvement of upper extremity function and correction of deformity. Results: Postoperative, flexion range of elbow joint improved to average $111.7^{\circ}$ (range: $90{\sim}130^{\circ}$). $25.8^{\circ}$ (range: $15{\sim}45^{\circ}$) in flexion contracture and $16.6^{\circ}$ (range: $10{\sim}35^{\circ}$) in pronation contracture were remained. Range of motion of elbow joint improved to average $85.3^{\circ}$ (range: $45{\sim}105^{\circ}$). Flexion power of elbow joint improved to Grade 5 in all cases. Postoperatively on Mayer & Green grade scale, there were excellent in 3 cases(50%), good in 2 cases(33.3%), fair in 1 case(16.7%). On patient's own assessment of functional improvement, there were excellent in 4 cases(66.6%), good in 1 case(16.7%) and fair in 1 case(l6.7%). Conclusion: Steindler flexoplasty can reserve good clinical results with being improved to active flexion of elbow joint in cases who have functional hand and wrist, but paralysis upper arm muscle in brachial plexus injury.

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레진 시멘트와 상아질접착제를 사용한 콤포지트 레진 코아의 전단결합강도에 관한 연구 (SHEAR BOND STRENGTH OF COMPOSITE RESIN CORE USED IN COMBINATION WITH VARIOUS RESIN CEMENTS AND DENTIN BONDING AGENTS)

  • 김현오;방몽숙
    • 대한치과보철학회지
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    • 제42권1호
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    • pp.30-40
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    • 2004
  • Purpose : The purpose of this study was aimed to compare the shear bond strength on dentin of three dentin bonding agents and two resin cements used in conjunction with self-cured composite resin core material. Material and method : Control group and six experimental groups were divided for this study. Control group was designated as specimens bonded with Tenure$ A&B^{(R)}$. Experimental groups were as follows : PB-BL group : specimens bonded with Prime&Bond $NT^{(R)}$, $BondLink^{(R)}$ SB-BL group : specimens bonded with $^{(R)}$, BondLink$SingleBond^{(R)}$ PB group : specimens bonded with Prime&Bond $NT^{(R)}$ SB group : specimens bonded with $SingleBond^{(R)}$ PF group : specimens bonded with $Panavia-F^{(R)}$ BI group specimens bonded with Bistite $II^{(R)}$ All specimens were stored in $37^{\circ}C$ distilled water for 24 hours, followed by the shear bond strength was tested by universal testing machine. The data was analysed statistically by Mann-Whitney test. Results : 1. For Prime&Bond $NT^{(R)}$ and $SingleBonde^{(R)}$, the shear bond strength was 0.24 MPa and 7.19 MPa each by each, while Tenure $A&B^{(R)}$ group control was measured at 13.93 MPa (p<0.05). Especially for Prime&Bond $NT^{(R)}$ it did not get conjunction with dentin. 2. For Prime&Bond $NT^{(R)}$ and $SingleBond^{(R)}$ using $BondLink^{(R)}$, there was no significant difference as a result of 11.73 MPa and 14.00 MPa each by each (p<0.05). 3. For $Panavia-F^{(R)}$ and Bistite $II^{(R)}$, they showed the highest shear bond strength as measured by 18.24 MPa and 16.09 MPa each (p<0.05).

실버 페이스트의 치밀화 및 비저항에 미치는 소결조제와 프릿의 영향 (Effect of Sintering Aid and Glass-Frit on the Densification and Resistivity of Silver Paste)

  • 이종국;박성현;양권승
    • 한국재료학회지
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    • 제18권5호
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    • pp.283-288
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    • 2008
  • The effect of sintering aids and glass-frit on the densification and resistivity of silver paste was investigated in an effort to enhance the sintered density and electrical conductivity of the silver electrode. To prepare Pb-free silver paste for use at low sintering temperatures, two commercial silver powders ($0.8\;{\mu}m$ and $1.6\;{\mu}m$ in size) and 5wt.% lab-synthesized nanoparticles (30-50 nm in size) as a sintering aids were mixed with 3 wt.% or 6 wt.% of glass frit ($Bi_2O_3$-based) using a solvent and three roll mills. Thick films from the silver paste were prepared by means of screen printing on an alumina substrate followed by sintering at $450^{\circ}C$ to $550^{\circ}C$ for 15 min. Silver thick films from the paste with bimodal particles showed a high packing density, high densification during sintering and low resistivity compared to films created using monomodal particles. Silver nanoparticles as a sintering aid enhanced the densification of commercial silver powder at a low sintering temperature and induced low resistivity in the silver thick film. The glass frit also enhanced the densification of the films through liquid phase sintering; however, the optimum content of glass frit is necessary to ensure that a dense microstructure and low resistivity are obtained, as excessive glass-frit can provoke low conductivity due to the interconnection of the glass phase with the high resistivity between the silver particles.