• Title/Summary/Keyword: ${\Delta}E$

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Genotypic Difference in Tocopherol and Tocotrienol Contents of Rice Bran (벼 품종별 미강의 Tocopherol과 Tocotrienol 함량 평가)

  • 박경열;강창성;조영철;이용선;이영현;이영상
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.6
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    • pp.469-472
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    • 2003
  • The rice bran has been known to contain tocopherols and tocotrienols carrying antioxidant and cholesterol-lowing activities. The content of 8 isomers of vitamin E : $\alpha\textrm{-}$, $\beta\textrm{-}$, $\gamma\textrm{-}$, $\delta\textrm{-}$tocoperols (T) and tocotrienols ($\textrm{T}_3$) were extracted from 18 major rice varieties and quantified with an HPLC. Tested varieties exhibited T, $\textrm{T}_3$ and total vitamin E ($\textrm{TT}_3$) contents ranging 9.1-14.8, 22.4-37.1, 34.9-46.5 mg/100g with averages of 11.1, 28.0, 39.2 mg/100g, respectively. Among tested varieties, Seojinbyeo and Hwasungbyeo showed high T contents and Andabyeo, Damakum were high in $\textrm{T}_3$, and Andabyeo and Seojinbyeo were high in total $\textrm{TT}_3$ contents. Regardless of varieties, the average 8 isomer contents (in mg/100g) were in descending order of $\gamma\textrm{-}$$\textrm{T}_3$(17.9) >$\alpha\textrm{-}$$\textrm{T}_3$(8.8) >$\alpha\textrm{-}$T (7.8) >$\gamma\textrm{-}$T(2.6) >$\delta\textrm{-}$$\textrm{T}_3$ (0.9)>$\beta\textrm{-}$T (0.7)>$\beta\textrm{-}$$\textrm{T}_3$ (0.4)>$\delta\textrm{-}$T (0.1). In most varieties, $\gamma\textrm{-}$$\textrm{T}_3$, a strong antioxidant and anticancer compound, consisted 64% of total tocotrienol and 46% of total vitamin E in vice bran.

A SPECTROPHOTOMETRIC STUDY ON DISCOLORATION OF RESTORATIVE COMPOSITE RESINS IN COFFEE AND ARTIFICIAL SALIVA (분광광도계를 이용한 커피와 인공타액에서의 수복용 복합레진의 변색에 대한 연구)

  • Eom, Seung-Hee;Cho, Hyo-Sun;Lee, Chung-Sik
    • Restorative Dentistry and Endodontics
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    • v.21 no.2
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    • pp.530-545
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    • 1996
  • The purpose of this study was to investigate by spectrophotometry the changes in color parameters of composite resins after exposure to distilled water, filtered coffee, and artificial saliva. Five kinds of fine particle composite resin in experiment 1, and six kinds of composite resin in experiment 2 were used. In experiment 1, each group of composite resin was stored in distilled water at $4^{\circ}C$, $50^{\circ}C$, and filtered coffee solution at $4^{\circ}C$, $50^{\circ}C$. And then each specimen was measured by spectrophotometer. Measurements were repeated in 1 hour, 2 hours, 4 hours, 8 hours, 16 hours, 24 hours, and 48 hours. In experiment 2, all specimens of each brand were stored in distilled water at $37^{\circ}C$, artificial saliva not contained mucin at $37^{\circ}C$, and artificial saliva contained mucin at $37^{\circ}C$. All specimens of each brand were measured by spectrophotormeter in 1 week, 2 weeks, 4 weeks, 8 weeks, and up to 12 weeks. The results were as follows : 1. In cold coffee, five of fine particle composite resins showed ${\Delta}E{^*}_{ab}$ values less than 2. However, in hot coffee ${\Delta}E{^*}_{ab}$ values of Amelogen Universal and Prisma TPH were higher than those of Conquest Crystal, ${\AE}$litefil and Z100. 2. Z100 and ${\AE}$litefil had better cleansibility of extrinsic coffee staining than Amelogen Universal, Conquest Crystal and Prisma TPH. 3. In distilled water and artificial saliva not contained mucin, five of fine particle composite resin showed ${\Delta}E{^*}_{ab}$ values less than 2 up to 12 weeks. However, Silux Plus showed higher than ${\Delta}E{^*}_{ab}$ values of fine particle composite resin. 4. As an immersion solution for discoloration experiment, artificial saliva not contained mucin showed similar appearance as distilled water. However, artificial saliva contained mucin had different appearance from the others. 5. In artificial saliva contained mucin, ${\AE}$litefil, Prisma TPH and Z100 showed ${\Delta}E{^*}_{ab}$ values less than 1 up to 12 weeks. However, Silux Plus, Amelogen Universal and Conquest Crystal showed ${\Delta}E{^*}_{ab}$ values more than 1 up to 12 weeks. But, Conquest Crystal showed different characteristics of chromacity difference value(less chromatic) and lightness difference value(lighter) from Silux Plus and Amelogen Universal.

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SNU 1.5 MV Van de Graaff Accelerator (V) -on the Operation of the High Voltage Stabilization System- (NU 1.5MV 반데그라프 가속기 (V) -고전압 안정화 계통의 동작-)

  • Bae, Y.D.;Bak, H.I.;Chung, K.H.;Woo, H.J.;Choi, B.H.
    • Nuclear Engineering and Technology
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    • v.19 no.2
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    • pp.115-121
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    • 1987
  • A high voltage stabilization system for the SNU 1.5MV Tandem Van do Graaff accelerator was set up and its operational characteristics were examined and optimized. The optimum parameters of beam transport system were experimentally determined, and under the proper condition the accelerated proton beam current of 350nA was obtained at the target chamber. Without the high voltage stabilization the observed magnitude of voltage fluctuation was $\Delta$V/ V=5.2$\times$10$^{-3}$ without ion beam and 7.2$\times$10$^{-3}$ with ion beam, respectively, and its apparent ripple frequency for voltage fluctuations was about 3Hz or less. Through the optimized operation of the high voltage stabilization system, the terminal voltage fluctuation was reduced to $\Delta$V/V=2.45$\times$10$^{-4}$ and the energy stability with $\Delta$E/E=2.44$\times$10$^{-4}$ was steadily maintained at the 247.3kV terminal voltage, and the stabilization factor was deduced to be 29.4.

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Derivation of Some Activation Parameters (새로운 활성화 파라메터의 유도)

  • Lee, Ik-Choon
    • Journal of the Korean Chemical Society
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    • v.12 no.2
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    • pp.61-64
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    • 1968
  • Compressibility and expansibility of activation, ${\Delta}K^{\neq}\;and\;{\Delta}E^{\neq},$ are defined with the use of general principles that an activation parameter is the difference in partial molar quantities of the parameter for the transition and initial state. Two related parameters, (${\partial}{\Delta}H^{\neq}/{\partial}P)_{\gamma}\;and\;{\Delta}W^{\neq}(=P{\Delta}V^{\neq}),$ are also derived. Simpler interpretation of the existing kinetic data are possible with these activation parameters, while other derivations lead to complicated expressions of no practical significance.

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2-TYPE SURFACES AND QUADRIC HYPERSURFACES SATISFYING ⟨∆x, x⟩ = const.

  • Jang, Changrim;Jo, Haerae
    • East Asian mathematical journal
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    • v.33 no.5
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    • pp.571-585
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    • 2017
  • Let M be a connected n-dimensional submanifold of a Euclidean space $E^{n+k}$ equipped with the induced metric and ${\Delta}$ its Laplacian. If the position vector x of M is decomposed as a sum of three vectors $x=x_1+x_2+x_0$ where two vectors $x_1$ and $x_2$ are non-constant eigen vectors of the Laplacian, i.e., ${\Delta}x_i={\lambda}_ix_i$, i = 1, 2 (${\lambda}_i{\in}R$) and $x_0$ is a constant vector, then, M is called a 2-type submanifold. In this paper we showed that a 2-type surface M in $E^3$ satisfies ${\langle}{\Delta}x,x-x_0{\rangle}=c$ for a constant c, where ${\langle},{\rangle}$ is the usual inner product in $E^3$, then M is an open part of a circular cylinder. Also we showed that if a quadric hypersurface M in a Euclidean space satisfies ${\langle}{\Delta}x,x{\rangle}=c$ for a constant c, then it is one of a minimal quadric hypersurface, a genaralized cone, a hypersphere, and a spherical cylinder.

Anaysis of the photoelastic of CR lens using circular polariscope (원편광기를 이용한 CR 렌즈의 광 탄성 해석 연구)

  • Kim, Yong-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.11-16
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    • 2001
  • The polariscope to measure :he stress in lens was made up quarter-wave plate polarizer and we analyzed two components of light's wave $E_1$ and $E_2$ following the steps. It is clear that the principal-stress difference ${\sigma}_1-{\sigma}_2$ can be determined in 2-D model if fringe order N is measured each point in sample moreover. the optical axes of sample coincide with the principal-stress directions. The birefringence acted to a light wave and a phase retardation were in proportioned to the principal-stressed difference (${\sigma}_1-{\sigma}_2$) and the intensity of final light wave was proportioned to $sin^2({\Delta}/2)$, when ${\Delta}/2=n^{\pi}$ (n=0, 1, 2, ...) and the extinction occurs. As a experimental result, the extinction band shifted owing to a magnitude of lens' external stress.

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Molecular Orbital Analyses on Hammett Substituent Constant (I) (Hammett 치환기 상수에 대한 분자궤도론적 해석 (I))

  • Byung-Kak Park;Gab-Yong Lee
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.172-180
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    • 1986
  • The Hammett's substituent constants were analyzed for the substituted-benzoic acid, -benzene and -naphthalene by LCAO MO method. Hammett's ${\sigma}$-values have been theoretically proved to treat as the sum of independent contribution of inductive effect and resonance effect. That is, Is (static inductive effect) and Id (dynamic inductive effect) corresponding to inductive effect are chosen as net charge and approximate self atom polarizability indices respectively, and ${\Delta}E^{HOMO}$ which is the difference in HOMO energy level between substituted molecule and unsubstituted molecule as resonance effect. In conclusion, it has been found that the observed ${\sigma}$-values depend on the sum of Id, Is and ${\Delta}E^{HOMO}$.

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Comparative Study on the Color Stability of Temporary Prosthetic Materials for Dental CAD-CAM (치과 CAD-CAM용 임시 수복재의 색 안정성 비교 연구)

  • Lee, Hye-Eun;Kim, Won-Soo;Kim, Jung-suk;Lee, Ju-hee;Won, Seuck-Jae
    • Journal of Technologic Dentistry
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    • v.38 no.3
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    • pp.165-173
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    • 2016
  • Purpose: This study was conducted to examine the color stability of temporary prosthetic materials for dental CAD-CAM. Method: 2 kinds of existing acrylic resin temporary filling materials and 2 kinds of polymer prosthetic materials for dental CAD-CAM were used for testing, and five specimens respectively were absorbed in soy sauce, red pepper paste, and coffee. A Chroma Meter was used as analysis equipment. The color change of the specimens was observed to calculate ${\Delta}E$ value throughout 2 days, 3 days, 4 days, and 5 days and this was analyzed and the following result was obtained. Results: Snap's ${\Delta}E$ value was bigger than Vipi block(p<0.05). Red pepper paste had the largest impact on the color change of resin(${\Delta}E$), followed by soy sauce and coffee(p<0.000). With the passage of time, ${\Delta}E$ value was inversely(-) related and decreased somewhat(p<0.000).

Purification of hemolysin in mosquitocidal delta-endotoxin from Bacillus thuringiensis subsp. darmstadiensis 73E10-2 (모기유충에 살충력이 있는 Bacillus thuringiensis subsp. darmstadiensis 73E10-2의 내독소의 용혈성 인자의 정제)

  • 김광현;이기희;홍용기
    • Microbiology and Biotechnology Letters
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    • v.19 no.3
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    • pp.303-307
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    • 1991
  • The hemolyic polypeptide in delta-endotoxin from Bacillus thun'ngiensis subsp. darmstadiensis 73ElO-2 was purified by Sephadex G-IOO gel filtration and DEAE-cellulose ion exchange column chromatography. The purity of hemolysin was confirmed by ouchterlony test and SDS-PAGE. The molecular weight of the purified hemolysin was approximately 64 KDa by SDS-PAGE. The purified hemolysin has not mosquitocidal activity against larvae of Aedes agypti, but hemolytic activity on red blood cells of rat. There is no serological relationship between delta-endotoxin from B. thuringiensis subsp. israelensis and the purified hemolysin from the . strain 73ElO-2.

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Protonation and Energetical Investigations of Calix[4]-cyclen-benzo-crown-6 and Its Complexes with Zinc and Copper

  • Boonchoo, Thanaporn;Pulpoka, Buncha;Ruangpprnvisuti, Vithaya
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.819-822
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    • 2004
  • Protonation constants of calix[4]-cyclen-benzo-crown-6, L in 1X$10^{-2}$ M $Bu_4NCF_3SO_3$ in 40% $CH_2Cl_2/CH_3OH$ at $25^{\circ}C$ determined by potentiometric titration are log $K_1$ = 10.91, log $K_2$ = 10.30, log $K_3$ = 6.24 and log $K_4$ = 2.55. Stability constants for the receptor L complexes with Cu(II) and Zn(II) in 1X$10^{-2}$ M $Bu_4NCF_3SO_3$ in 40% $CH_2Cl_2/CH_3OH$ at $25^{\circ}C$ were determined by UV-VIS spectrometric titration. Stability constants of the CuL and ZnL complexes as log $\beta$ are 4.37 and 3.45, respectively. Stabilization energies for protonations of receptor L, derived from ab initio Hartree-Fock method with 6-31G basis set, are ${\Delta}E_1$ = -290.1, ${\Delta}E_2$ = -205.0, ${\Delta}E_3$ = -124.9 and ${\Delta}E_4$ = -26.9 kcal/mol and complexation energy of ZnL complex is -370.3 kcal/mol.