Three-dimensional structures of unsteady detonation wave propagating through a square-shaped tube is studied using computational method and parallel processing. Inviscid fluid dynamics equations coupled with variable-${\gamma}$ formulation and simplified one-step Arrhenius chemical reaction model were analysed by a MUSCL-type TVD scheme and four stage Runge-Kutta time integration. Results in three dimension show the two unsteady detonation wave propagating mode, the Rectangular and diagonal mode of detonation wave instabilities. Two different modes of instability showed the same cell length but different cell width and the geometric similarities in smoked-foil record.

I consider the structure of steady wave system which is admitted by the continuum equations for materials that undergo phase transformations with exothermic chemical reaction. In particular, the dynamic phase front structures between liquid and gas phases, and solid and liquid phases are computationally investigated. Based on the one-dimensional continuum shock structure analysis, the present approach can estimate the nano-width of waves that are present in combustion. For illustration purpose, n-heptane is used in the evaporation and condensation analysis and HMX is used in the melting and freezing analysis of energetic materials of interest. On-going effort includes extension of this idea to include broad range of liquid and solid fuels, such as rocket propellants.

The numerical simulation is conducted for analysis flame structure of superdetonative ram accelerator experiment by ISL(French-German Research Institute in Saint Louis). Fully coupled chemically non-equilibrium Navier-Stokes equation is used. Shockwave structure of superdetonative ram accelerator and behavior of detonation wave is studied. Maintaining of detonation wave is very important to accelerate projectile, Because detonation wave make high pressure gases and this high pressure accelerate projectile.

Recently, renewed interest on the scramjet engine has been demonstrated through the many international activities along the several Asia-Pacific countries. Here, a short review of current activities on supersonic combustion in a scramjet engine will be addressed followed by the discussions on the review of numerical simulation on supersonic combustion phenomena related with scramjet engine combustors and ram accelerator. Emphasis was put on the grid refinement, scheme, unsteadiness and phenomenological differences.

Social interest and request about low pollution waste treatment process are growing and gasification melting method, as a new technology concept, is risen. The necessity of engineering analysis to determine design standards and operation condition is required. In this study, the objective and function of components and operation process of various gasification melting furnaces such as shaft type, fluidized bed and Rotary Kiln type gasification melting furnace are reviewed and the design standard and operation range of gasification melting furnace are determined by inspecting the change of output and operation condition with input condition change.

The aim of this study is to numerically investigate a compact reformer system currently under development and to design a better reforming system with more efficient heat transfer and reforming reactions. Numerical models were established separately for both the combustion part and the reforming reaction part. A comparison between the calculation results and experimental data showed that the concentration of the reformate at the exit of the reforming system was in good agreement with the measured data, but for the temperature at the exit little difference between them was found. After checking the validity of the numerical models, the heat transfer between the combustion gas and reforming catalysts was estimated and the behavior of the catalyst bed was investigated as a function of the operation parameters.

As fuel cells approach commercialization, hydrogen production becomes a critical step in the overall energy conversion pathway. Reforming is a process that produces a hydrogen-rich gas from hydrocarbon fuels. Hydrogen production via autothermal reforming (ATR) is particularly attractive for applications that demand a quick start-up and response time in a compact size. However, further research is required to optimize the performance of autothermal reformers and accurate models of reactor performance must be developed and validated. The design includes the requirement of accommodating a wide range of experimental set ups. Factors considered in the design of the reformer are capability to use multiple fuels, ability to vary stoichiometry, precise temperature and pressure control, implementation of enhancement methods, capability to implement variable catalyst positions and catalyst arrangement, ability to monitor and change reactant mixing, and proper implementation of data acquisition. A model of the system was first developed in order to calculate flowrates, heating, space velocity, and other important parameters needed to select the hardware that comprises the reformer. Predicted performance will be compared to actual data once the reformer construction is completed. This comparison will quantify the accuracy of the model and should point to areas where further model development is required. The end result will be a research tool that allows engineers to optimize hydrogen production via autothermal reformation.

Methane reforming processes to obtain hydrogen were investigated experimentally by using atmospheric plasma source. Among possible reforming processes, such as a $CO_2$ reforming(dry reforming), a partial oxidation (POx), a steam reforming(SR), and a steam reforming with oxygen(SRO or auto-thermal reforming), partial oxidation and the steam reforming with oxygen were considered. We choose a rotating arc plasma as an atmospheric plasma source, since it shows the best performances in our preliminary tests in terms of a methane conversion, a hydrogen production, and a power consumption. Then, the effects of a feeding flow-rate, an electrical power input to a plasma reaction, an $O_2/C$ ratio and a steam to carbon ratio in the case of SRO on the reforming characteristics were observed systematically. As results, at a certain condition almost 100% of methane conversion was obtained and we could achieve the same hydrogen production rate by consuming a half of electrical power which was used by the best results for other researchers.

Combustion of RDF and wastewater sludge was performed in a 0.1MWth bench scale circulating fluidized bed combustor(CFBC), Combustion characteristics of the RDF and sludge mixture demonstrated stable combustion conditions. Component analysis, Combustion characteristics was measured before and after the test, and applications for commercial 1MWe CFBC boiler were prepared. The release of hazardous components such as $SO_2$ and HCl was relatively low values of 50 and 150ppm, respectively.

The development of eco-friendly low pressure carburizing system with high pressure gas quenching (LPC_GQ, 500kg/charge) led to new stage in the fundamental case-hardening treatments. This is due to its ability to provide tighter tolerances on the carburizing process with notable reductions in distortion of the carburized and hardened workpiece. This system is characteristics by high uniformity and reproducibility of heat treatment results, absence of an intergranular oxidation layer, carburizing of complex shapes, reduced cycle time, low operating costs, simplified production, eliminate post washing, and reduced grinding costs.

Oil-fired power plants usually use several burners and the combustion air is supplied to each burner through the complicated duct which is called windbox. A windbox should be designed to supply combustion air to each burner evenly but, due to the complicated duct shape, flow distribution in the windbox is unbalanced and uneven supplies of combustion air to each burner are induced by these unbalanced flow distribution in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated for the uniform flow distribution. In this study, computational simulation method was used to investigate the flow distribution in the windbox and measured the velocities at the exit of burners in the real windbox to compare with CFD results. The results show two significant flow patterns. One is that the flow rates of each burner are different from each other and this means that all burners operate in different conditions of air to fuel ratio. The other is that the flow distribution at the exit of each burner is not axi-symmetric although the burner shape is axi-symmetric and this increases the pollutant products like CO.

High temperature furnace such as Steam power plant and incinerator contribute considerable part of NOx generation and face urgent demand of De-NOx system. Reducing agents are necessary to use De-NOx system. In this study mixing caused by direct injection of reducing agent solution spray into flue gas duct was measured. Carbonated water was used as tracer and simulated agent because ammonia as a reducing agent is not proper to experiment. Mixing and evaporation must occur simultaneously and quickly enough to achieve desirable efficiency. To achieve that, the angle of attack of static mixer and the location is simulated and $CO_2$ concentration is measured.

This study focused on the use of orimulsion in industrial combustion systems. Orimulsion is a bitumen-in-water emulsified fuel, which contains a thirty percent water. Orimulsion has relatively high levels of sulfur and nitrogen compared to many fuel oils, and has been the subject of much debate regarding the environmental impacts of its use. The goal of this research is to analyse the effect of flash spray combustion characteristics of orimulsion on NOx and particulate material reduction. For the flash spray of orimulsion, it is heated by $150^{\circ}C$. The effects of fuel heating temperatures on NOx and particulate material emissions were investigated experimentally. As the fuel temperature was increased, NOx and particulate material concentrations in flue gas were decreased.

This paper describes the effect of the split injection on combustion and emission characteristics in a common rail diesel engine at various operating conditions. The combustion pressures and exhaust emissions such as $NO_x$ and soot were measured at various split injection timings. The experimental apparatus of this study is composed of 4 cylinder engine installed with piezoelectric pressure sensor, EC dynamometer, and exhaust gas analyzer for the measurement of $NO_x$, CO, HC and soot emissions. Results show that the split injection has a great effect on reducing the rapid premixed combustion and $NO_x$ emissions.

The combustion characteristics of binary component single droplets hanging at the tip of a quartz fiber are studied experimentally at different environmental pressures and temperatures under normal gravity. Normal Heptane and Normal Hexadecane are selected as two fuels with high difference in boiling temperatures. A falling electrical furnace in a high pressure vessel has provided high temperature environment. Nitrogen and air have formed the environment to study evaporation and combustion, respectively. The initial diameter of droplet was ranging from 1.1 to 1.3 mm. The evaporation and combustion processes were recorded by a high speed digital camera. Some characteristics of droplet burning under different environment conditions and different droplet composition have been investigated. Microexplosion of droplet take places under atmospheric pressure. Bubble formation and its consequent result, incomplete droplet disintegration which presents in all binary compositions, do not appear at high pressure. The initiation of combustion, always takes place in the bottom of droplet due to buoyancy effect of relatively cold fuel vapor. Also, the burning of binary droplet produces soot when the pressure is high.

The evaporation characteristics of single and multicomponent droplets hanging at the tip of a quartz fiber are studied experimentally at the different environmental conditions under normal gravity. Heptane and Hexadecane are selected as two fuels with different evaporation rates and boiling temperatures. At the first step, the evaporation of single component droplet of both fuels has been examined separately. At the next step the evaporation of several blends of these two fuels, as a binary component droplet, has been studied. The temperature and pressure range is selected between 400 and 700 $^{\circ}C$, and 0.1 and 2.5 MPa, respectively. High temperature environment has been provided by a falling electrical furnace. The initial diameter of droplet was in range of 1.1 and 1.3 mm. The evaporation process was recorded by a high speed CCD camera. The results of binary droplet evaporation show the three staged evaporation. In the the first stage the more volatile component evaporates. The droplet temperature rises after an almost non evaporating period and in the third stage a quasi linear evaporation takes place. The evaporation of the binary droplet at low pressure is accompanied with bubble formation and droplet fragmentation and leads to incomplete microexplosion. The component concentration affects the evaporation behavior of the first two stages. The bubble formation and droplet distortion does not appear at high environment pressure. Nomenclature

The burning characteristics of interacting spherical droplet in a turbulent flow are numerically investigated. The transient combustion of 3-dimensionally arranged droplets, both the fixed streamwise droplet distances of 3 radii and 10 radii and different turbulence intensities, is studied. The results obtained from the present numerical analysis show that droplet vaporization rate for heptane droplet is insensitive to turbulence intensity, and that the transient flame configuration and retardation of droplet surface temperature augmentation with streamwise droplet spacing substantially influence vaporization process of interacting droplets. Single flame mode in which individual flames are merged into single flame, with decreasing streamwise droplet spacing, becomes faster. Therefore, vaporization rate of the second droplet with decreasing streamwise droplet spacing decreases remarkably with flame movement.

LNG combustion characteristics of oxygen carrier particles were investigated in a batch type bubbling fluidized bed reactor. Three particles, NiO/bentonite, $NiO/NiAl_2O_4$, $CO_xO_y/CoAl_2O_4$, were used as oxygen carrier particles and LNG and air were used as reactants for reduction and oxidation, respectively. In the reducer, high gas conversion and high $CO_2$ selectivity were achieved for all three particles. In the oxidizer, NOx was not detected. The results of exhaust gas analysis showed that inherent $CO_2$ separation and NOx-free combustion are possible in the LNG fueled chemical-looping combustion system with NiO/bentonite, $NiO/NiAl_2O_4$ and $Ca_xO_y/CoAl_2O_4$ particles.

In this study, Development of 300,000kcal/hr high velocity Injection burner with fuel multi-stage was performed using experiments. The characteristics of NOx emission in multi fuel/air staged combustor have been experimentally studied. The design concept of multi fuel/air staged combustor is creation of two separate flame, a primary flame is largest access air combustion and the secondary flame is complete combustion zone, where most of fuel bums. Experiments were performed on an industrial scale in a laboratory furnace and Liquefied Natural Gas(LNG) was used as primary and secondary fuels. Comparison of outlet NOx and outlet Temperature under various air rate and primary/ secondary fuel ratio was performed. The test demonstrated that NOx emission con be reduced by 70% in accordance with operating conditions.

Two and Three dimensional numerical simulations have been carried out to understand the combustion characteristics of LNG-fueled gas turbine combustor for power generation. Focus of the study was given to the influences of different fuel composition of imported and domestic natural gases with the flow conditions selected from the gas turbine operation data. Reacting flow characteristics of the swirl stabilized natural gas combustor were understood from the comparison of the two-dimensional and three-dimensional results. The thermal influences of different natural gases were very small and the fuel composition and flow rate were considered to be tuned well.

The performance of oxygen combustion with $CO_2$ feeding was investigated in a pyrex tube furnace. The inverse type multi-hole burner was used for improving mixing and wide operating range. It introduced oxygen, fuel, and oxygen, respectively, from center tube to outer tubes. Oxygen combustion characteristics with excess oxygen ratio, oxygen feeding ratio, and $CO_2$ feeding flow rate were studied to optimize the operating condition and to apply the oxygen combustion with recirculation of flue gas to a real furnace. This paper presents results on the effect of $CO_2$ feeding flow rate on the structure of the flames and concentrations of NO and CO emissions. The visible flame length was shortest due to well mixing between fuel and oxygen when the oxygen feeding ratio was 0.25. The NO emission was reduced drastically regardless of excess oxygen ratio when the $CO_2$ feeding flow rate was larger than 15 lpm. The CO emission is varied by changing the $CO_2$ feeding flow rate but the CO emission characteristics is highly affected by excess oxygen ratio. When the excess oxygen ratio is below ${\lamda}=1.1$, the CO emission increased as the $CO_2$ feeding flow rate increased.

Multi-hole type oxygen combustion burner was developed for industrial gasification and smelting furnace. We investigated characteristics of flame, radiation transfer, and soot emission in the convectional oxygen burner with respect to the feeding condition of fuel and oxygen. Regarding the results of the conventional burner, we designed new burners which have larger fuel consumption rate and radiation heat transfer. We changed the size and hole number and shape of the exit plane of the burner. In addition, the performance of the burner was tested with respect to the feeding condition of the fuel and air: Normal Diffusion flame(NDF) and Inverse Diffusion Flame(IDF). We investigated the flame configuration, radiation heat transfer, and soot formation by using a CCD camera, heat flux meter, and Laser Induced Incadescence(LII), respectively. The stable operating condition was obtained by the flame configuration and the flame of the burner which has dented exit plane was more stable in whole operating conditions. The characteristics of radiative heat transfer were sensitive to the feeding condition of reactants and the flame of 75% primary oxygen and 25% secondary oxygen of the IDF case shows maximum radiation heat transfer. The soot volume fraction of the flame was measured in the axial direction of the flame and the amount of soot volume fraction is proportion to the radiation heat transfer. As a result, we can get the optimal operating condition of the newly designed burner which enhances the characteristics of flame stabilization and radiation heat transfer.

Large eddy simulation(LES) methodology used to model the isothermal swirling flows in a dump combustor and the turbulent premixed flame in a model gas turbine combustor. The LES solver was implemented on parallel computer consisting 16 processors. In isothermal flow simulation, the results was compared with that of ${\kappa}-{\varepsilon}$ model as well as experimental data, in order to verify the capability of LES code. To model the turbulent premixed flame in a gas turbine, the G-equation flamelet model was used. The results showd that LES and RANS well predicted the mean velocity field of a non-swirling flow. However, in swirling flow, LES showed a better performance in predicting the mean axial and azimuthal velocities, and the central recirculation zone than those of RANS. In a model gas turbine combustor, the operation condition of high pressure and temperature induced the different phenomena, such as flame length and flow-field information, comparing with the condition of ambient pressure and temperature. Finally, it was identified that the flame and heat release oscillations are related to the vortex shedding generated by swirl flow and pressure wave propagation.

The usefulness of unsteady combustion was experimentally investigated using confined premixed flames stabilized by a rearward-facing step. For this purpose, apparatus of forced pulsating mixture supply, which could be modulated its amplitude and frequency, was designed. The unsteady combustion used in this experiment plays an important role in controlling self-excited combustion oscillations and furthermore it exhibits desirable performance, from a practical point of view, such as high combustion and reduction of pollutant emission like nitric oxide.

The LES-based level-set flamelet model has been applied to analyze the turbulent propane/air premixed bluff-body flame with a highly wrinkled flame fronts. The present study has been motivated to investigate the interaction between the flame front and turbulent eddies. Special emphasis is given to study the effect of G equation filtering treatment on the precise structure of turbulent premixed flames as well as the effect of sub-grid scale (SGS) eddies on the wrinkling of the flame surface. The level-set/flamelet model has been adopted to account for the effect of turbulence-flame interaction as well as to properly capture the flame front. Numerical results indicate that the present LES-based level-set flamelet approach has a capability to realistically simulate the highly non-stationary turbulent premixed flame.

Hydrogen safety is one of the key technical issue with growing attention on utilization of hydrogen energy. This study is aimed to predict behavior of momentum-controlling buoyant jet and flame caused by hydrogen leakage from a high pressured tank. Approximate solutions were derived for the case of turbulent buoyant jet and diffusion flame in still air. In case of hydrogen jet with low Froude number (100-4000), computed jet trajectories were compared with experimental data and showed good agreement with them. Jet and flame trajectories and flame length of hydrogen are predicted and compared with the buoyant flame of propane. The results well show that buoyancy is dominant in the range of low Froude number, while initial momentum is dominant in the range of high Froude number. That effect is more distinct for hydrogen flame than the case of propane.

When the fuel jet velocity is smaller than coflow velocity, the trend of decreasing liftoff height of highly diluted propane lifted flame with coflow velocity is observed experimentally. To investigate the mechanism of decreasing liftoff height with coflow velocity, lifted flames in propane jet has been studied numerically. Using one-step overall reaction mechanism the liftoff heights have been calculated for four cases of coflow velocity. The simulation agrees qualitatively with experimental observation that the liftoff height decreases with coflow velocity. As coflow velocity increases, the streamlines between nozzle and lifted flame diverge in radial direction due to the difference of momentum between coflow jet and fuel jet such that the local flow velocity ahead of lifted flame base decreases resulting in decrease of the liftoff height with coflow velocity.

The tribrachial flame in laminar coflow jet has been investigated experimentally with unsteady propagating condition. In this experiment, we found that the tribrachial point has an angle of flame surface because the location of tribrachial point is not on the base point of flame but on the inclined surface of flame. This angle of Flame surface at tribrachial point are increasing when the flame is approaching to the nozzle exit. With considering this angle of flame surface, the radial velocity gradient can affect flame propagation speed by increasing flow-stretch effect. The propagation speed of tribrachial flame was calculated with including above stretch effect. The speed decreases with increasing velocity gradient due to the increment of stretch effect.

Interruption of good fluidization in a fluidized bed ash cooler(FBAC) for discharging bed materials such as sand or coal ash particles from the CFB combustor is frequently happened because of agglomeration of the particles in the bed. This unstable operation may, in the worst case, result in an unscheduled boiler shut down. In this study, we examined the operation problems of the FBAC of Tonghae CFB boiler and studied and introduced the simple detection and solution techniques with analyzing the mixing property and the occurrence of defluidization in a simulated fluidized bed ash cooler system (0.5m-H x 0.5m-W x 1.0m-L). The bridge of the large particles at the bed surface could be observed, and this caused to form the defluidization area at the entrance of the FBAC. The defluidization was affected not only by airflow rates but also by the particles discharging rates as well as particle size distribution in the FBAC. The local defluidization could be detected by analysis of the accumulated standard deviation error at a given period of time. Also, the regulation of the overall or local airflow rate made clearing up the local defluidization possible.

This study performs the pilot-plant experiments to evaluate the effect of the oxygen enrichment on the co-incineration of municipal solid waste and organic sludge from a wastewater treatment facility. The design capacity of the stoker-type incinerator pilot-plant is 150 kg/h. Combustion chamber temperatures were measured as well as the stack gas concentrations, i.e., NOx, CO, and the residual oxygen. The maximum ratio of organic sludge waste to the total waste input is 30%. Also the oxygen-enriched air with 23% of oxygen in supplied air is used for stable combustion. As the co-incineration ratio of the sludge increased up to 30% of the total waste input, the primary and the secondary combustion chamber temperature was decreased $to900^{\circ}C$ (primary combustion chamber), $750^{\circ}C$(secondary combustion chamber), respectively, approximately $200^{\circ}C$ below the incineration temperature of the domestic waste only (primary: $1,100^{\circ}C$, secondary: $950^{\circ}C$). However, if the supplied air was enriched to 22% oxygen content in air, the incinerator temperature was high enough to burn the waste mixture with 30% sludge, which has the heating value of 1,600 kcal/kg.

Recently, fuel reforming technology for the fuel cell vehicle has been applied to internal combustion engines, with various purpose. Syngas which is reformed from fossil fuel has hydrogen as a major component. It has better effort in combustion characteristics such as wide flammability and hig speed flame propagation. In this study, syngas was added to a gasoline engine for the improvement of combustion stability and exhaust emission in idle state. Combustion stability, exhaust emissions, fuel consumption and exhaust gas temperature were measured to investigate the effects of syngas addition on idle performance. Results showed that syngas has ability to extend lean operation limit and ignition retard range. with dramatical reduction of engine out emissions.

To achieve efficient combustion within a manageable length, a successful fuel injection scheme must provide rapid mixing between the fuel and airstreams. The aim of the present numerical research is to investigate the flame holding and combustion enhancement. Additional fuel into the cavity prevents shear flow impingement on the trailing edge of the cavity. The high temperature freestream flow mixes with the cold hydrogen fuel that is injected into the cavity and raises the fuel temperature remarkably and become to start combustion. The high pressure in the cavity due to the cavity structure and combustion leads the hydrogen fuel to upstream. The shock in the cavity to be generated by the fuel injection joins together and reflects off the ceiling wall. This makes high pressure and low mach number region and makes a small recirculation in this region. This high stagnation temperature is nearly recovered in the shear layer in front of the cavity and leads to start combustion. In the downstream of the cavity, the wall pressure drops significantly. This means that the combustion phenomenon is diminished. Because fuel lumps at the trailing edge of the cavity then it spreads after the cavity so, in this region there is a strong expansion.

A comprehensive DES quality numerical analysis has been carried out for reacting flows in constant-area and divergent scramjet combustor configuration with and without a cavity. Transverse injection of hydrogen is considered over a broad range of injection pressure. The corresponding equivalence ratio of the overall fuel-air mixture ranges from 0.167 to 0.50. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the pervious studies. Much of the flow unsteadiness is related not only the cavity, but also to the intrinsic unsteadiness in the flowfield. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The roles of the cavity, injection pressure, and heat release in determining the flow dynamics are examined systematically.

Due to the high density and heating value, liquid fuel is attractive for ramjet propulsion system. Liquid fuel requires time to evaporation and mix with incoming air before ignition; insufficient evaporation and mixing result in low combustion efficiency and instability. So the numerical studies are conducted to investigate the spray and combustion characteristics of a liquid-fueled dump type Integrated Rocket Ramjet combustor. The governing equations are solved by means of a finite-volume using time derivative preconditioning method for chemical reacting flow. The liquid phase is treated by solving Lagrangian equations of motion and transport for the life histories of a statistically significant sample of individual droplets.

At previous study, nitrogen oxide emission was decreased with decreasing pressure index. This tendency was explained by the flame oscillation with changing combustor pressure. In this study, the characteristics of flame oscillation with changing combustor pressure were investigated. It can be found that flame length is extended and flame width is narrowed by decreasing combustor pressure. It can be observed that pilot flame and the surrounding air converge on the inner flame in the $P^{\ast}{\geqq}1$ conditions and that surrounding air and flow pattern was widely dispersed in the $P^{\ast}<1$ conditions. In the respect of average flame length, low fluctuation was shown in the $P^{\ast}<1$ conditions. On the other hands, large fluctuation was shown in the $P^{\ast}<1$ conditions. Flame oscillation are observed from $P^{\ast}=$ 0.98 in the condition of $P^{\ast}<1$ and the amplitude of flame oscillation becomes larger when $P^{\ast}$ is lowered. These results demonstrate that low NOx phenomenon was caused by flame oscillation with changing combustor pressure.

To understand fundamental characteristics of combustion in a small scale device, the effects of the momentum and heat loss on the stability of laminar premixed flames in a narrow channel are investigated by two-dimensional high-fidelity numerical simulation. A general finding is that momentum loss promotes the Saffman-Taylor (S-T) instability which is additive to the Darrieus-Landau (D-L) instabilities, while the heat loss effects result in an enhancement of the diffusive-thermal (D-T) instability. These effects are also valid in nonlinear behavior of the premixed flame. The simulations of multiple cell interactions are also conducted with heat and momentum loss effects.

Most of all combustion system has combustion instability. It is a serious problem in combustion system. Unstable injection is one of the source of combustion instability. The experimental investigation of spray characteristics for simplex swirl injector were conducted experimentally. Two kerosene based fuels were chosen as the atomizing fluid. As the major operating parameters, fuel temperature and injection pressure were chosen, and varied in the range from 253 K to 293 K and from 0.2 MPa to 1.0 MPa, respectively. Direct spray images and mean diameter were measured for the various combination of operating parameters in the flow field. The results of present study show that the injection pressure and spray cone angle are fluctuated at specific conditions while it is continuous steady injection. As the fuel temperature changes continuously, spray cone angle varies discontinuously through the region of injection instability.

The instabilities in rocket engines and gas turbine combustors due to the interaction between the fluid flow (acoustics) and the heat transfer (thermal energy) are called thermoacoustic or combustion instabilities. Almost all analysis assumes constant hot section temperature for Modern mathematical analysis of acoustic oscillations in Rijke type devices. However, it is impossible to predict whether a system is stable or not because the flame or heater response model can have a dramatic effect on predicted growth rates. In this study, A standard ${\kappa}-{\varepsilon}$ turbulent model and hybrid combustion model(eddy breakup model and chemical reaction) were used. After steady solution was gotten, unsteady calculation is simulated by perturbating on pressure boundary. As a result, we obtained the relationship of equivalence ratio and frequency by numerical simulation, and they are comparable to the experimental result. In addition, in spite of these results, there are limitations of using turbulent and combustion model in simulation method of thermoacoutic instability

Measurements of flame length, width and NOx emissions have been conducted to investigate the effect of an acoustic excitation on flame structure in turbulent hydrogen diffusion flames with coaxial air. The resonance frequency of oscillations was varied between 259 ,514 and 728 Hz with power rate of 0.405 and 2.88w. When these frequencies imposed to hydrogen flames, dramatic reduction of flame length and NOx emission was achieved. And acetone planar laser-induced fluorescence technique was used to measure a concentration of the near field of driven axisymmetric jet. The air-fuel stoichiometric line was plotted to investigate the mixing layer and development of air entrainment to fuel jet. Consequently, acoustic excitation on flame could enhance the air-fuel mixing resulting in abatement of NOx emission quantitatively.

In this study, the combustion characteristics were investigated with the variation of design factors on multiple slit gas burner. The design factors consist of slit height, width, spacing, and inner length. The combustion characteristics were made analysis of the CO emission and NOx emission by using CO analyzer and NOx analyzer. The lower perimeter to area and the narrow spacing extends the lift-flame limit. The CO emission increases with the increasing perimeter to area ratio at the same condition. The NOx emission is found to be less significant with the port perimeter to area ratio. The flame interference might highly depend on the spacing and port perimeter to area ratio, and it also affects the burner performance.

An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $1.36{\sim}{\infty}$, and swirlers with swirl numbers of 0, 0.28, 0.64, and 1.32, on the characteristic of radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and pollutant emission in partially premixed swirling flames. The signal from the electronically excited state of $OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, and flow fields images were detected through a schlieren system. The results demonstrated that the flame height decreases and jet spreading angle increase with increasing a swirl number. The more momentum ratio and swirl number increase, the more decrease flame height, and the generation of sooting flame is promoted.

Effects of surface defect distribution on flame instability during flame-surface interaction are experimentally investigated. To examine the chemical quenching phenomenon, we prepared thermally grown silicon oxide plates with well-defined defect density. Ion implantation was used to control the number of defects, i.e. oxygen vacancies. In an attempt to preferentially remove the oxygen atoms from silicon dioxide surface, argon ions with low energy level from 3keV to 5keV were irradiated at the incident angle of $60^{\circ}C$. Compositional and structural modification of $SiO_2$ induced by low-energy $Ar^+$ ion irradiation has been characterized by Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS). The analysis shows that as the ion energy increases, the number of structural defect also increases and non-stoichiometric condition of $SiO_x(x{\le}2)$ plates is enhanced. From the quenching distance measurements, we found out that when the surface temperature is under $300^{\circ}C$, the quenching distance decreases on account of reduced heat loss; as the surface temperature increases over $300^{\circ}C$, however, quenching distance increases despite reduced heat loss effect. Such aberrant behavior is caused by heterogeneous chemical reaction between active radicals and surface defect sites. The higher defect density, the larger quenching distance. This results means that chemical quenching is governed by radical adsorption and can be parameterized by the oxygen vacancy density on the surface.