DOI QR코드

DOI QR Code

A Study on the Flux and Heat Transfer of Direct Contact Type Module Applied for a Pilot Scale Membrane Distillation Process

파일럿 규모 막 증발 공정 적용을 위한 직접 접촉식 모듈의 투과유속 및 열에너지 이동에 관한 연구

  • 김승환 (세종대학교 환경에너지공간융합학과) ;
  • 김세운 (세종대학교 환경에너지공간융합학과) ;
  • 이동우 ((주)EPS 솔루션) ;
  • 조진우 (세종대학교 환경에너지공간융합학과)
  • Received : 2017.05.10
  • Accepted : 2017.06.02
  • Published : 2017.06.15

Abstract

In this study, a direct contact membrane module was manufactured to be used in a pilot scale membrane distillation process to treat $3m^3/day$ of the digestate produced from anaerobic digestion of livestock manure. In order to investigate the performance of the membrane module, permeate flux was measured with and without spacer inside the module under various condition of temperature difference and cross flow velocity (CFV) through the membrane surfaces. Flux recovery rate after chemical cleaning was also investigated by applying three different cleaning methods. Additionally, thermal energy consumption was theoretically simulated based on actual pilot plant operation conditions. As results, we observed flux of the module with spacer was almost similar to the theoretically predicted value because the installation of spacer reduced the channeling effect inside the module. Under the same operating condition, the permeate flux also increased with increasing temperature difference and CFV. As a result of chemical in-line cleaning using NaOCl and citric acid for the fouled membranes, the recovery rate was 83.7% compared to the initial flux when NaOCl was used alone, and 87% recovery rate was observed when only citric acid was used. However, in the case of using only citric acid, the permeate flux was decreased at a rapid rate. It seemed that a cleaning by NaOCl was more effective to recover the flux of membrane contaminated by the organic matter as compared to a cleaning by citric acid. The total heat energy consumption increased with increasing CFV and temperature difference across the membrane. Thus, further studies should be intensively conducted to obtain a high permeate flux while keeping the energy consumption to a minimum for a practical application of membrane distillation process to treat wastewater.

Keywords

References

  1. Godino, P., Pena, L. and Mengual, J.I. (1996) Membrane distillation: theory and experiments, Journal of membrane Science, 121(1), pp. 83-93. https://doi.org/10.1016/0376-7388(96)00162-7
  2. Alkhudhiri, A., Darwish, N., Hial, N. (2012) Membrane distillation: a comprehensive review, Desalination, 287, pp. 2-18. https://doi.org/10.1016/j.desal.2011.08.027
  3. Lawson, K.W., and Lloyd, D.R. (1997) Membrane distillation, Journal of Membrane Science, 124, pp. 1-25. https://doi.org/10.1016/S0376-7388(96)00236-0
  4. Lagana, F., Barbien, G., Drioli, E. (2000) Direct contact membrane distillation: modelling and concentration experiments, Journal of Membrane Science, 166, pp. 1-11. https://doi.org/10.1016/S0376-7388(99)00234-3
  5. Macedonio, F., and Drioli, E. (2008) Pressure-driven membrane operations and membrane distillation technology integration for water purification, Desalination, 223, pp. 396-409. https://doi.org/10.1016/j.desal.2007.01.200
  6. Blanco Galvez, J., Garcia-Rodriguez, L. and Martin-Mateos, I. (2009) Seawater desalination by an innovative solar-powered membrane distillation system: the MEDESOL project, Desalination, 246(1), pp. 567-576. https://doi.org/10.1016/j.desal.2008.12.005
  7. Guillen-Burrieza, E., Ruiz-Aguirre, A., Zaragoza, G. and Arafat, H.A. (2014) Membrane fouling and cleaning in long term plant-scale membrane distillation operations. Journal of Membrane Science, 468, pp. 360-372. https://doi.org/10.1016/j.memsci.2014.05.064
  8. Gryta, M. (2008) Fouling in direct contact membrane distillation process. Journal of Membrane Science, 325(1), pp. 383-394. https://doi.org/10.1016/j.memsci.2008.08.001
  9. Khayet, M., and Matsuura, T. (2011) Membrane distillation: principles and applications, Elsevier, Oxford, pp.5.
  10. Schofield, R., Fane, A., Fell, C. and Macoun, R. (1990) Factors affecting flux in membrane distillation. Desalination, 77, pp. 279-294. https://doi.org/10.1016/0011-9164(90)85030-E
  11. Kim, S., Lee, D.W. and Cho, J. (2016) Application of direct contact membrane distillation process to treat anaerobic digestate. Journal of Membrane Science, 511, pp. 20-28. https://doi.org/10.1016/j.memsci.2016.03.038
  12. Souhaimi, M.K. and Matsuura, T. (2011) Membrane distillation: principles and applications, Elsevier.
  13. Kim, S.H. (2017) Flux model development for a membrane distillation with the effect of suspended solids in anaerobic digestate of livestock wastewater, M.S Thesis, Sejong University.
  14. Liu, H., and Wang, J. (2013) Treatment of radioactive wastewater using direct contact membrane distillation, Journal of Hazardous Materials, 261, pp. 307-315. https://doi.org/10.1016/j.jhazmat.2013.07.045

Cited by

  1. 가축분뇨 혐기 소화액 처리를 위한 막 증발과 역삼투 공정 성능 비교 vol.34, pp.4, 2017, https://doi.org/10.11001/jksww.2020.34.4.259