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마이크로캡슐이 폴리머 수지의 기계적 특성 및 열안정성에 미치는 영향

Effects of Microcapsules on Mechanical Properties and Thermal Stability of Microcapsule Embedded Polymeric Resins

  • Yoon, Sung Ho (Department of Mechanical Engineering, Kumoh National Institute of Technology) ;
  • Kim, Min Sik (Department of Mechanical Engineering, Kumoh National Institute of Technology) ;
  • Jang, Se Yong (The 7th R&D Institute, Agency for Defense Development)
  • 투고 : 2015.09.03
  • 심사 : 2015.10.27
  • 발행 : 2015.10.31

초록

본 연구에서는 자가치료용 마이크로캡슐이 함유된 복합재의 경우 함유된 마이크로캡슐이 복합재의 기계적 특성과 열안정성에 미치는 영향을 실험적으로 고찰하였다. 이를 위해 melamine-urea-formaldehyde(M-U-F) 박막을 갖는 $70{\sim}130{\mu}m$ 직경의 마이크로캡슐들이 함유된 인장시편과 굽힘시편을 에폭시 수지와 폴리에스터 수지로 제작하였다. 이때 마이크로캡슐의 함유량은 0 wt%, 0.5 wt%, 1.0 wt%이다. 인장시험과 굽힘시험을 통해 마이크로캡슐이 함유된 수지시편의 기계적 특성을 평가하였으며 열중량 분석시험을 통해 마이크로캡슐이 함유된 수지시편의 열안정성을 평가하였다. 연구결과에 따르면 인장탄성계수는 마이크로캡슐의 함유에 큰 영향을 받지 않지만 인장강도는 인장탄성계수에 비해 마이크로캡슐의 함유에 민감하게 나타났다. 그러나 인장강도의 저하는 마이크로캡슐의 함유량에 선형적으로 비례하지는 않았으며 굽힘시험의 결과에서도 유사한 양상이 관찰되었다. 또한 온도 변화에 따른 마이크로캡슐이 함유된 수지시편의 무게 변화는 마이크로캡슐이 함유되지 않은 수지시편의 경우와 유사하여 마이크로캡슐을 수지에 함유시키더라도 열안정성에는 큰 영향이 없음을 알 수 있었다.

This study investigated the effects of microcapsules on mechanical properties and thermal stability of the composite material containing self-healing microcapsules. To this end, tensile specimens and flexural specimens containing melamine-urea-formaldehyde (M-U-F) shell walled microcapsules with diameters of $70{\sim}130{\mu}m$ were manufactured. Varying amount of microcapsules in the specimens was considered: 0 wt%, 0.5 wt%, and 1.0 wt%. The tensile and flexural tests were conducted to evaluate mechanical properties of the specimens containing the microcapsules and the thermogravimetric analysis test was performed to evaluate the thermal stability of the specimens containing the microcapsules. The results show that the tensile strength of the specimens was sensitive to the amount of the microcapsules compared to the tensile modulus even though the tensile modulus of the specimens was not significantly affected by the amount of the microcapsules. However, reduction of the tensile strength was not linearly proportional to the amount of microcapsules; similar results were observed in the flexural test. The weight changes of the specimens containing the microcapsules, as a function of temperature, were similar to those specimens without microcapsules. The thermal stability of the specimens was not affected significantly by the microcapsules embedded in the specimens.

키워드

참고문헌

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