• Smart Structures and Systems
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• v.32 no.3
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• pp.167-177
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• 2023

A probabilistic micromechanical framework is proposed to quantify numerically the self-healing capabilities of polymers containing microcapsules. A two-step self-healing process is designed in this study: A probabilistic micromechanical framework based on the ensemble volume-averaging method is derived for the polymers, and a hitting probability model combined with a crack nucleation model is then utilized for encountering microcapsules and microcracks. Using this framework, a series of parametric investigations are performed to examine the influence of various model parameters (e.g., the volume fraction of microcapsules, microcapsule radius, radius ratio of microcracks to microcapsules, microcrack aspect ratio, and scale parameter) on the self-healing capabilities of the polymers. The proposed framework is also implemented into a finite element code to solve the self-healing behavior of tapered double cantilever beam specimens.

• Polymer(Korea)
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• v.37 no.3
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• pp.356-361
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• 2013

Microcapsules of two different self-healing agents, 5-ethylidene-2-norbornene (ENB) and ENB with a crosslinker, surrounded by a melamine-urea-formaldehyde shell were manufactured. In this work, a red dye was incorporated into the self-healing agents as a tracer for better visual observations. It revealed that the incorporation of a red dye into self-healing agents did not disturb the formation of microcapsules from the examination of thermal resistance, particle size/size distribution and morphology of the resulting microcapsules. Releasing of self-healing liquid into the induced crack from ruptured microcapsules and filling between crack planes were observed using an optical microscope. Also observed was the reaction of filled healing agent with embedded Grubbs' catalyst in an epoxy coating layer.

• Journal of the Korean Society for Precision Engineering
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• v.18 no.4
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• pp.135-141
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• 2001

An experimental study to find the effect of processing parameters for self-healing microcapules is performed. These microcapsules can be applied to accomplish the healing of delamination damage in woven E-glass/epoxy composites. This paper introduces the self-healing concept and presents a method for solving the microcapsule size and shape. Additionally, processing parameters are varied during the formation of microcapsules and these capsules are observed through optical microscope. To obtain thermogravimetric(TG) curve for the manufactured microcapsules, TGA tests are executed. From these results, the best processing conditions for the formation of capsules are found as follows: (1) temperature of solution $ 50^{\circ}C$, (2) potential of hytdrogen(pH) 3.5ppm, and (3) agitation 500~600rpm.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.508-511
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• 2004

This study focused on the effect of autonomic microcapsules on the mechanical properties of structural material. Several types of microcapsules with healing agents were manufactured by varying agitation speed of high speed stirrer. The size distribution of microcapsules was measured by a particle size analzer. The epoxy specimens embedded with microcapsules were manufactured and the degree of cure of such epoxy specimen was measured by a differential scanning calorimetry. The tensile modulus and tensile strength in epoxy specimens embedded with microcapsules were evaluated in order to investigate the effects of microcapsules on mechanical properties of structural materials. The configuration of microcapsules and morphology of fracture surfaces for the epoxy specimen were examined by an optical microcope and a scanning electron microscope. According to the results, tensile strength of the epoxy specimen embedded with microcapsules was indicated a little reduction, but tensile modulus was not much affected on microcapsules.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.1
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• pp.113-121
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• 2019

In this study, self - healing microcapsules which can be mixed directly with cement composites were prepared, and the quality and crack healing performance of cement composites with self - healing microcapsules were evaluated. In the past, it has been focused on evaluating self-healing capsules and crack healing properties. Therefore, self - healing microcapsules have been studied for their effect on the quality of cement composites when mixed with cement composites. The table flow and the air flow rate of the cement composite material mixed with self-healing microcapsules were found to have no significant influence on table flow and air volume regardless of mixing ratio. Compressive strength and splitting tensile strength tended to decrease with increasing capsule mixing ratio. As a result of evaluation of crack healing properties according to water flow, initial water permeability decreased, and reaction products were generated over time and cracks were healed.

• Macromolecular Research
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• v.12 no.5
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• pp.478-483
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• 2004

Two different diene monomers [dicyclopentadiene (DCPD) and 5-ethylidene-2-norbornene (ENB)] as self-healing agents for polymeric composites were microencapsuled by in situ polymerization of urea and formaldehyde. We obtained plots of the storage modulus (G') and tan $\delta$ as a function of cure time by using dynamic mechanical analysis to investigate the cure behavior of the unreacted self-healing agent mixture in the presence of a catalyst. Glass transition temperatures (T$\_$g/) and exothermic reactions of samples cured for 5 and 120 min in the presence of different amounts of the catalyst were analyzed by differential scanning calorimetry. Of the two dienes, ENB may have advantages as a self-healing agent because, when cured under same conditions as DCPD, it reacts much faster in the presence of a much lower amount of catalyst, has no melting point, and produces a resin that has a higher value of T$\_$g/. Microcapsules containing the healing agent were successfully formed from both of the diene monomers and were characterized by thermogravimetric analysis. Optical microscopy and a particle size analyzer were employed to observe the morphology and size distribution, respectively, of the microcapsules. The microcapsules exhibited similar thermal properties as well as particle shapes and sizes.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.793-796
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• 2003

This study dealt with the manufacturing process of self-healing microcapsules for damage repair in polymeric composites. The microcapsule was consisted with a DCPD (dicyclopentadiene) as the healing agent and a urea-formaldehyde resin as the wall section. The size distribution of microcapsules were measured by a particle size analyzer using a laser diffraction technique. Thermal stability of microcapsules was investigated by using a TGA under continuous and isothermal heating conditions. According to the results, these microcapsules were verified to be to thermally stable and have a great potential to be applicable for damage repair in polymeric composites.

• Proceedings of the KSR Conference
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• 2004.06a
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• pp.309-314
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• 2004

This study focused on the introduction of damage repair for polymeric composite carbody. called selfing tech-healinique. using microcapsules loaded with the healing agent The manufacturing process for microcapsules with the healing agent was introduced and tile characteristics of microcapsules manufactured by varying with various manufacturing process variables were evaluated. The DCPD was used for the healing agent and microcapsules were made of urea-formaldehyde resin. The magnitude and the size distribution of microcapsules were measured by a particle size analyzer using laser diffraction technique. Thermal stability was investigated by using a TGA under continuous and isothermal heating conditions for the healing agent. microcapsules without the healing agent. microcapsules with the healing agent.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.389-396
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• 2021

In this paper, it was evaluated that the effect of self-healing microcapsules on the quality and healing properties of cement composites. In the mixing of microcapsules, the plastic viscosity and yield stress of the cement composites decreased due to the particle properties of the microcapsules, and decreased in proportion to the mixing ratio. The table flow showed a tendency to decrease as the core material acted as a stimulant due to the loss of microcapsules, and the compressive strength could be supplemented through unit quantity correction. As a result of evaluating the effect of microcapsule mixing on the healing properties of cement composites, it was found that the unit water flow rate decreased by the healing reaction immediately after crack initiation. When more than 3% of microcapsules were mixed, it was found that there was a healing rate of more than 95% at 7 days of healing age.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.236-244
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• 2018

In this study, we tried to fabricate self - healing microcapsules using liquid inorganic materials which can be mixed directly with cement composites. The basic properties of the liquid inorganic material were evaluated and microencapsulation was performed. The focus of this paper is on the quality and manufacturing characteristics of cement composites rather than the healing effects of self - healing microcapsules according to mixed capsules. Test results, the self-healing microcapsules encapsulate liquid inorganic material which is stable at room temperature and has high crack followability, and the yield is over 90%. The size of self - healing microcapsule was able to change according to the synthetic agitation speed and it was able to secure more than 70% of target size. In addition, the loss of less than 10% was found to occur through the membrane strengthening of self - healing microcapsules, and it could be reduced by 50% compared with the case without membrane strengthening.