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Diozonides from Coozonolyses of Cyclodienes and Carbonyl Compounds

  • Published : 2002.03.20
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Abstract

Treatment of conjugated cyclodienes (5a-5c) with excess ozone in dichoromethane in the presence of added carbonyl compounds (3) resulted to give the corresponding diozonides 10 and cross-ozonides 14. Similarly, ozonolysis of the nonconjugated 1,4-cyclohexadiene (6a) and 1,5-cyclooctadiene (6b) under same conditions afforded both diozonides 20 and cross-ozonides 14. On the other hand, Ozonolysis of bicyclo[2.2.0]hepta-2,5-diene (6c) in the presence of 3A provided the corresponding diozonide 19.

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References

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Cited by

  1. ChemInform Abstract: Diozonides from Coozonolyses of Cyclodienes and Carbonyl Compounds. vol.33, pp.33, 2010, https://doi.org/10.1002/chin.200233146
  2. Matrix Isolation Study of the Ozonolysis of 1,3- and 1,4-Cyclohexadiene: Identification of Novel Reaction Pathways vol.117, pp.20, 2013, https://doi.org/10.1021/jp402981n