• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.470-475
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• 2013

Zr-benzendicarboxylate structure, UiO-66 was prepared in 1-L batch scale by using a unique sonochemical-solvothermal combined synthesis method. The produced UiO-66 showed uniform particles of ca. $0.2{\mu}m$ in size with the BET surface area of $1,375m^2/g$ in high product yield (>95%). The UiO-66 showed 198 and 84 mg/g $CO_2$ adsorption capacity at 273 K and 298 K, respectively, with excellent $CO_2$ selectivity ($CO_2:N_2=32:1$) at ambient conditions. The isosteric heat of $CO_2$ adsorption varied from 33 to 25 kJ/mol as the adsorption progressed. The UiO-66 tested for xylene isomer separation in a liquid-phase batch mode confirmed preferential adsorption of the adsorbent for o-xylene over m-, and p-xylene.

• Resources Recycling
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• v.17 no.3
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• pp.35-41
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• 2008

The study of coking technology to upgrade oil sand bitumen which is considered as alternative fuel was performed by using thermogravity analyzer and delayed coking reactor(600ml). To analyzed and compared coking characteristics of oil sand bitumen, the reactivities of oil sand bitumen were measured in the TGA. At the temperature conditions of $400{\sim}550^{\circ}C$ and the temperature rising velocity of $50^{\circ}C/min$. the termination time of coking reaction and conversion efficiencies increased with an increase of bed temperature. However the increase rate decreased over $450^{\circ}C$. So the coking reaction with oil sand bitumen might be over $450^{\circ}C$. Also the termination time decreased with increasing the temperature rising velocity. But the content of coke increased with increasing temperature rising velocity. At the experiments in the delayed coker, the temperature condition at maximum oil yield was $475^{\circ}C$ and the fuel properties of oil from coking reaction was almost equal with conventional diesel. It was verified that the coking process might be useful process to upgrade the oil sand bitumem by using API and SIMDAS.

• KSBB Journal
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• v.11 no.6
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• pp.636-641
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• 1996

The production of extracellular mannitol by a new mannitol-producing bacterium, Leuconostoc sp. KY-002 was studied in shake flask cultures. The new isolate has a capability of utilizing fructose and sucrose for mannitol formation. Maximum mannitol production was obtained with fructose as the sole carbon source. Under the optimal culture conditions, within 70 hours of incubation, a final concentration of 26 g/L of mannitol from 50 g/L fructose was obtained with an indicated yield of 52% based on fructose consumed. However, higher concentrations of fructose ranging from 100 to 250 g/L could not effectively be transformed to mannitol due to a lack of osmotolerance. The strain produced no other polyols such as glycerol and sorbitol as by-products. Yeast extract was the best nitrogen source and high levels of inorganic phosphate up to 10 g/L promoted mannitol formation. Any mineral ions and salts did not play important role in both cell growth and mannitol production. Nicotinic acid enhanced mannitol production by 16%. The optimum culture temperature and initial pH were $35^{\circ}C$ and 6, respectively.

• Composites Research
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• v.23 no.6
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• pp.32-38
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• 2010

The effect of the atmospheric pressure plasma(APP) treatments is experimentally investigated to ascertain the optimum condition to yield the best adhesive properties between a polyamide woven fabric and acrylonitrile butadiene rubber(NBR). For the atmospheric pressure flame plasma(APFP) treatment, the optimum number of treatment at given conditions is 2 times. The thermal deformation of the fabric is more serious with increasing the number of APFP treatment. The adhesive strength of the case with APFP treated fabric is increased about 35% when compare to the case with non-APFP treated one for the interface(bonding agent one or two coatings). When the surface is coated twice with the bonding agent, the adhesive energy with APFP treated fabric is increased about 4 times. It was found that the surface modification of polyamide woven fabric by APFP treatment is a fast, economic and applicable method to improve the adhesive properties between woven fabric and rubber when compared to other APP treatments.

• Smart Structures and Systems
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• v.20 no.5
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• pp.619-636
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• 2017

Magnetorheological (MR) damper is a type of controllable device widely used in vibration mitigation. This device is highly nonlinear, and exhibits strongly hysteretic behavior that is dependent on both the motion imposed on the device and the strength of the surrounding electromagnetic field. An accurate model for understanding and predicting the nonlinear damping force of the MR damper is crucial for its control applications. The MR damper models are often identified off-line by conducting regression analysis using data collected under constant voltage. In this study, a MR damper model is integrated with a model for the power supply unit (PSU) to consider the dynamic behavior of the PSU, and then a real-time nonlinear model updating technique is proposed to accurately identify this integrated MR damper model with the efficiency that cannot be offered by off-line methods. The unscented Kalman filter is implemented as the updating algorithm on a cyber-physical model updating platform. Using this platform, the experimental study is conducted to identify MR damper models in real-time, under in-service conditions with time-varying current levels. For comparison purposes, both off-line and real-time updating methods are applied in the experimental study. The results demonstrate that all the updated models can provide good identification accuracy, but the error comparison shows the real-time updated models yield smaller relative errors than the off-line updated model. In addition, the real-time state estimates obtained during the model updating can be used as feedback for potential nonlinear control design for MR dampers.

• Elastomers and Composites
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• v.44 no.3
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• pp.209-221
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• 2009

Polyolefins are important commodity polymers with the largest volume of business owing to their outstanding combination of cost performance and excellent physical properties. However, the lack of functional groups often has limited their end uses, such as compatibilizer, modifier and adhesive, where the interaction with other materials is especially important. The incorporation of functional groups as polymer segments to afford block or graft polyolefin copolymers has been extensively investigated in the context of the functional polyolefin hybrids. Living polymerization processes have been considered to be an efficient method to prepare the polyolefin hybrids with precisely controlled architecture and compositions. Among the living polymerization techniques, controlled/"living" radical polymerization (CRP) methods are very effective not only because of the controllability of polymerization but also because of the versatility of monomers and polymerization conditions. In this review paper, progresses on the preparations of polyolefin graft or block copolymers through CRP techniques are summarized. The commodity polymers such as polyisobutylene, polyethylene and polypropylene are combined with polar segments such as polyacrylate, polymethacrylate, polystyrene to yield functionalized polyolefins.

• International Journal of Industrial Entomology and Biomaterials
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• v.23 no.2
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• pp.187-191
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• 2011

An attempt was made to assess the potentiality of bivoltine double hybrids under simulated conditions of farmers to identify the suitable bivoltine double hybrid combination. Four bivoltine double hybrids developed at Central Sericultural Research and Training Institute (CSRTI), Mysore along with popular single hybrid, $CSR2{\times}CSR4$ as control was assessed for economic traits. The rearing results showed significant improvement of 20-24% in fecundity of the double hybrids studied over single hybrid. Among the double hybrids, $[D7{\times}S5]{\times}[D13{\times}S1]$ recorded significantly higher survival (89.58 %), cocoon yield (76.328 kg/ 50,000 eggs), cocoon price (Rs. 180.87/kg) and lower cocoon leaf ratio of 1: 21.80. The performance of the reeling traits were also found significantly superior in $[D7{\times}S5]{\times}[D13{\times}S1]$ with higher filament length (1100 m), reelability (88%), raw silk (18.55%) and neatness (92 points) compared to $CSR2{\times}CSR4$ and other double hybrids evaluated. Besides, the cocoons of $[D7{\times}S5]{\times}[D13{\times}S1]$ exhibit uniformity in size with a standard deviation of < 8. Overall data indicated the superiority of $[D7{\times}S5]{\times}[D13{\times}S1]$ compared to the other hybrids evaluated and it has profound influence in expressing the full potentiality in the field.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.3
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• pp.141-146
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• 2014

The necessity to develop economical and eco-friendly technologies is steadily increasing. Plant growth promoting rhizomicrobial strains PGPR are a group of microorganisms that actively colonize plant roots and increase plant growth and yield. Pot experiments were used to investigate the potential of some rhizobacterial strains to enhance the Brassica rapa growth. Microbial strains were successfully isolated from the rhizosphere of Panax ginseng and characterized based on its morphological and plant growth promotion characters. Surface disinfected seeds of Wisconsin Fast B. rapa were inoculated with the selected PGPR microorganisms. The different pots treatments were inoculated by its corresponding PGPR ($10^7cfu\;mL^{-1}$) and incubated in the growth chamber at $25^{\circ}C$ and 65% RH, the light period was adjusted to 24 hours (day). NPK chemical fertilizer and trade product (EMRO, USA) of effective microorganisms as well as un-inoculated control were used for comparison. Plants harvested in 40 days were found to have significant increase in leaf chlorophyll units and plant height and also in dry weight of root and shoot in the inoculated seedlings. Root and shoot length and also leaf surface area significantly were increased by bacterial inoculation in sterile soil. The study suggests that Rhodobacter capsulatus and Azotobacter chroococcum are beneficial for B. rapa growth as they enhance growth and induced IAA production and phosphorus solubilization. This study presents some rhizomicrobial strains that significantly promoted growth of Wisconsin Fast Plant B. rapa in pot experiment under different soil conditions.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.5
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• pp.469-479
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• 2016

Kimchi cabbage is one of the most important vegetables in Korea and a target crop for market stabilization as well. In particular Kimchi cabbages in a highland area are very sensitive to the fluctuations in supply and demand. Yield variability due to growth conditions dictates the market fluctuations of Kimchi cabbage price. This study was carried out to understand the distribution of the highland Kimchi cabbage growth status in Anbandeok. Anbandeok area in Gangneung, Gangwon-do, Korea is one of the main producing districts of highland Kimchi cabbage. The highland Kimchi cabbage status map of each growth factor was obtained from unmanned aerial vehicle (UAV) imagery and field survey data. Six status maps include UAVRGB image map, normalized difference vegetation index (NDVI) distribution/anomaly map, Crop distribution map, Planting/Harvest distribution map, Growth parameter map and Growth disorder map. As a result, the highland Kimchi cabbage status maps from May 31 to Sep. 6 in 2016 were presented to show spatial variability in the field. The benefits of the highland Kimchi cabbage status map can be summarized as follows: crop growth monitoring, reference for field observations and survey, the relative comparison of the growth condition in field scale, evaluation of growth in comparison of average year, change detection of annual crops or planting areas, abandoned fields monitoring, prediction of harvest season etc.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3617-3622
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• 2010

The reaction of stoichiometric amount of $FeCl_2{\cdot}4H_2O$, (2-pyridylmethyl, 3-pyridylmethyl)amine (2,3-pyma) and sodium azide/sodium thiocyanate in methanol under aerobic conditions affords the dinuclear Fe(III) complexes, [(2,3-pyma) $(N_3)_2Fe({\mu}-OCH_3)_2Fe(N_3)_2$(2,3-pyma)]${\cdot}CH_3OH$ (1) and [(2,3-pyma)$(NCS)_2Fe({\mu}-OCH_3)_2Fe(NCS)_2$(2,3-pyma)] (2) in good yield. Two bis-methoxy-bridged diiron(III) complexes are isolated and characterized. The coordination geometries around iron(III) ions in 1 and 2 are the same tetragonally distorted octahedron. The iron(III) ions are coordinated by two nitrogens of a 2,3-pyma, two nitrogens of two azide/thiocyanate ions, and two oxygens of two methoxy groups. Both compounds are isomorphous. The structures of 1 and 2 display the C-$H{\cdots}\pi$ and/or $\pi-\pi$ stacking interactions as well as hydrogen bonding interactions, respectively. Compounds 1 and 2 show significant antiferromagnetic couplings through the bridged methoxy groups between the iron(III) ions in the temperature range from 5 to 300 K ($H=-2JS_1{\cdot}S_2$, J=-19.1 and $-13.9\;cm^{-1}$ for 1 and 2).