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Optimization of Electro-Optical Properties of Acrylate-based Polymer-Dispersed Liquid Crystals for use in Transparent Conductive ZITO/Ag/ZITO Multilayer Films (투명 전도성 ZITO/Ag/ZITO 다층막 필름 적용을 위한 아크릴레이트 기반 고분자분산액정의 전기광학적 특성 최적화)

  • Cho, Jung-Dae;Kim, Yang-Bae;Heo, Gi-Seok;Kim, Eun-Mi;Hong, Jin-Who
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.291-298
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    • 2020
  • ZITO/Ag/ZITO multilayer transparent electrodes at room temperature on glass substrates were prepared using RF/DC magnetron sputtering. Transparent conductive films with a sheet resistance of 9.4 Ω/㎡ and a transmittance of 83.2% at 550 nm were obtained for the multilayer structure comprising ZITO/Ag/ZITO (100/8/42 nm). The sheet resistance and transmittance of ZITO/Ag/ZITO multilayer films meant that they would be highly applicable for use in polymer-dispersed liquid crystal (PDLC)-based smart windows due to the ability to effectively block infrared rays (heat rays) and thereby act as an energy-saving smart glass. Effects of the thickness of the PDLC layer and the intensity of ultraviolet light (UV) on electro-optical properties, photopolymerization kinetics, and morphologies of difunctional urethane acrylate-based PDLC systems were investigated using new transparent conducting electrodes. A PDLC cell photo-cured using UV at an intensity of 2.0 mW/c㎡ with a 15 ㎛-thick PDLC layer showed outstanding off-state opacity, good on-state transmittance, and favorable driving voltage. Also, the PDLC-based smart window optimized in this study formed liquid crystal droplets with a favorable microstructure, having an average size range of 2~5 ㎛ for scattering light efficiently, which could contribute to its superior final performance.

Growth of ZnS nanocluster thin films by growth technique and investigation of structural and optical properties (용액성장법(Solution growth technique)에 의한 ZnS nano 입자 박막성장 및 구조적, 광학적 특성)

  • 이종원;임상철;곽만석;박인용;김선태;최용대
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.3
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    • pp.199-204
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    • 2000
  • In this study, the ZnS nanosized thin films that could be used for fabrication of blue light-emitting diodes, electro-optic modulators, and n-window layers of solar cells were grown by the solution growth technique (SGT), and their structural and optical properties were examined. Based on these results, the quantum size effects of ZnS were systematically investigated. Governing factors related to the growth condition were the concentration of precursor solution, growth temperature, concentration of aq. ammonia, and growth duration. X-ray diffraction patterns showed that the ZnS thin film obtained in this study had the cubic structure ($\beta$-ZnS). When the growth temperature was $75^{\circ}C$, the surface morphology and the grain size uniformity were the best. The energy band gaps of samples were determined from the optical transmittance valued, and were shown to vary from 3.69 eV to 3.91 eV. These values were substantially higher than 3.65 eV of bulk ZnS, demonstrating that the quantum size effect of SGT grown ZnS is remarkable. Photoluminescence (PL) peaks were observed at the positions corresponding to the lower energy than that to energy band gap, illustrating that the surface states were induced by the ultra-fineness of grains in ZnS films. Particularly, for the first time, it is reported for the SGT grown ZnS that the PL peaks were shifted depending on the grain size.

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Effects of CdCl2 Heat Treatment on the Qualities of CdS Thin Films Deposited by RF Magnetron Sputtering Technique (RF 마그네트론 스퍼터링법으로 증착된 CdS 박막의 CdCl2 열처리 효과)

  • Choi, Su-Young;Chun, Seung-Ju;Jung, Young-Hun;Lee, Seung-Hun;Bae, Soo-Hyun;Tark, Sung-Ju;Kim, Ji-Hyun;Kim, Dong-Hwan
    • Korean Journal of Materials Research
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    • v.21 no.9
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    • pp.497-501
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    • 2011
  • The CdS thin film used as a window layer in the CdTe thin film solar cell transports photo-generated electrons to the front contact and forms a p-n junction with the CdTe layer. This is why the electrical, optical, and surface properties of the CdS thin film influence the efficiency of the CdTe thin film solar cell. When CdTe thin film solar cells are fabricated, a heat treatment is done to improve the qualities of the CdS thin films. Of the many types of heat treatments, the $CdCl_2$ heat treatment is most widely used because the grain size in CdS thin films increases and interdiffusion between the CdS and the CdTe layer is prevented by the heat treatment. To investigate the changes in the electrical, optical, and surface properties and the crystallinity of the CdS thin films due to heat treatment, CdS thin films were deposited on FTO/glass substrates by the rf magnetron sputtering technique, and then a $CdCl_2$ heat treatment was carried out. After the $CdCl_2$ heat treatment, the clustershaped grains in the CdS thin film increased in size and their boundaries became faint. XRD results show that the crystallinity improved and the crystalline size increased from 15 to 42 nm. The resistivity of the CdS single layer decreased from 3.87 to 0.26 ${\Omega}cm$, and the transmittance in the visible region increased from 64% to 74%.

A Study on $NO_x$ Reduction in a Light Duty Diesel Vehicle Equipped with a SCR Catalyst (선택적환원촉매를 적용한 중소형 경유차량의 질소산화물 저감 특성 연구)

  • Park, Young-Joon;Hong, Woo-Kyoung;Ka, Jae-Geum;Cho, Yong-Seok;Joo, Jae-Geon;Kim, Hyun-Ok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.5
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    • pp.118-124
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    • 2011
  • To reach the Euro-6 regulations of PM and $NO_x$ for light-duty diesel vehicles, it will be necessary to apply the CDPF and the de-$NO_x$ catalyst. The described system consists of a catalytic configuration, where the CDPF is placed downstream of the diesel engine and followed by a urea injection unit and a urea-SCR catalyst. One of the advantages of this system configuration is that, in this way, the SCR catalyst is protected from PM, and both white PM and deposits become reduced. In the urea-SCR system, the injection control of reductant is the most important thing in order to have good performance of $NO_x$ reduction. The ideal ratio of $NH_3$ molecules to $NO_x$ molecules is 1:1 based on $NH_3$ consumption and having $NH_3$ available for reaction of all of the exhaust $NO_x$. However, under the too low and too high temperature condition, the $NO_x$ reduction efficiency become slower, due to temperature window of SCR catalyst. And space velocity also affects to $NO_x$ conversion efficiency. In this paper, rig-tests were performed to evaluate the effects of $NO_x$ and $NH_3$ concentrations, gas temperature and space velocity on the $NO_x$ conversion efficiency of the urea-SCR system. And vehicle test was performed to verify control strategy of reductatnt injection. The developed control strategy of reductant injection was improved over all $NO_x$ reduction efficiency and $NH_3$ consumption in urea-SCR system. Results of this paper contribute to develop urea-SCR system for light-duty vehicles to meet Euro-5 emission regulations.

A Signal Detection Technique for OFDMA-based Wireless Mesh Networks with Different Time Delays (서로 다른 지연 시간을 갖는 OFDMA 기반의 Wireless Mesh Networks를 위한 신호 검출 기법)

  • Park, Chang-Hwan;Yoo, Hyun-Il;Kim, Yeong-Jun;Kwon, Dong-Seung;Cho, Yong-Soo
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.6C
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    • pp.495-505
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    • 2010
  • In this paper, the effect of Near-Far Problem (NFP) among distributed nodes in OFDMA-based Wireless Mesh Networks (WMNs) is analyzed by investigating statistical characteristics of Time Difference of Arrival (TDoA) and Desired-to-Undesired power Ratio (DUR). In order to overcome the effects of Inter-Symbol Interference (ISI), Inter-Carrier Interference (ICI), and Inter Link Interference (ILI), caused by TDoA in WMNs, we derive effective SINR for each subcarrier, and then, propose the optimal starting point of FFT window which can minimize BER for each subcarrier. In addition, we propose a subcarrier-based Zero Forcing - 2 Dimensional Ordered Successive Interference Cancellation (ZF-2DOSIC) technique for signal detection in WMNs with TDoA. It is verified by simulation that the effective SINR and uncoded BER performances of the proposed signal detection technique for OFDMA-based WMNs are significantly improved, compared with those of conventional technique.

Experimental Study on Interaction of Water Sprayed Curtain on Hot Surface of a Window Glass and its Effects on Glass Surface Temperature in Room Fires (구획화재 시 국부복사열에 노출된 유리면의 수막접촉에 따른 급냉파열특성 관한 실험적 연구)

  • 박형주;지남용
    • Fire Science and Engineering
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    • v.17 no.4
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    • pp.124-130
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    • 2003
  • This research focuses on analysis of a interaction fracture of various glasses due to contact of water sprayed curtain on hot glass surface with high temperature produced from convective heat source near glass wall. A large scaled experimental test was done in order to find the range of the glass surface temperature to be able to cause the breakage of the glasses when water droplets reach on the hot surface. This paper shows the allowable temperature of the glass surface for prevention of the cooling down breakage before water curtain droplets contact the surface. Allowable Temperature if $250^{\circ}C$ for the tempered glass but general glass is very relatively low. Therefore if the water curtain spray system was adequately activated by a thermal detector installed below ceiling adjacent glass wall with water curtain nozzle system, all hot glass would not break out by cooling water droplet's contact on the hot surface due to convective heat released by adjacent fire source near the glass wall.

Application of the Theory of Planned Behavior toward the Elders -Focus on Pre-service Childcare Teachers who have living Grandparents- (계획된 행동이론을 적용한 경로행동 연구 -조부모가 생존한 예비보육교사 중심으로-)

  • Ko, Eun-kyo;Shin, Su-kyung
    • The Journal of the Korea Contents Association
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    • v.16 no.12
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    • pp.749-760
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    • 2016
  • The purpose of this study was to identify the effects influencing path behaviors of pre-service childcare teachers to present the educational and social welfare measures for promoting children's character development and preventing the alienation of the elderly. The subjects for this study are 176 students who completed the childcare teacher course in four universities located in G city and J province. The scale of this study utilized modified, supplemented scale used in previous studies[1][2] that was constituted for a newly transformed model based on planned behavior theories. The contents of research design include salience beliefs such as attitude beliefs, normative beliefs, control beliefs, etc. as well as a model of planned behavior theories such as attitudes, subjective norms, perceived behavior control, behavior intension, behavior, etc. This study conducted frequency analysis and regression analysis for the data collected by using the SPSS 18.0 for Windows. From the results of verification, all hypothesis was supported. Thus, usefulness of this theory was reconfirmed, and the results of this study are to be utilized as basic materials for professionals who make every endeavor in a perspective of children's character development and in a perspective of reducing alienation phenomenon of the elderly.

Effects of Career Barriers, Perceived by Undergraduate Students Majoring in Public Health in Technical Colleges, on Career Preparation Behavior (전문대학 보건계열 학부생이 지각하는 진로장벽이 진로준비행동에 미치는 영향)

  • Park, Dae-sung;Yu, Eun-yeong
    • Journal of Digital Convergence
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    • v.14 no.12
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    • pp.313-321
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    • 2016
  • This study identified factors that have an influence on career preparation behavior in undergraduate students majoring in public health in technical colleges with the aim to provide basic data for the development of an employment counselling program which can have a positive influence on career preparation behavior. The subjects of this study were 556 college students studying public health in technical colleges in J $province^1$, J $province^2$, and G metropolitan city and they were randomly selected and sampled in convenience. The period of the survey was from September 7 to 9, 2015 and the survey was made with the use of a self-essay type questionnaire. 510 copies of the survey collected were analysed with the use of SPSS 14.0 for Windows. As a result it is shown that career barriers perceived by students studying public health in technical colleges had a negative effect on career preparation behavior. Therefore, organized and practical career counselling should be provided and career education programs should be developed to encourage subjects to have positive career preparation behavior. Therefore, it is suggested that practical career counselling and career education program should be developed to lead students studying public health to positive career preparatory activity, and research to verify its effect should be conducted.

A Study on the Occurrences and Preventive Strategies of Accident in Children (초등학생의 안전사고 실태 및 예방전략에 관한 조사 연구)

  • Bae Jeong-Yi
    • Child Health Nursing Research
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    • v.8 no.4
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    • pp.435-448
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    • 2002
  • Accidents are important causes of death and disability in children. They also have enormous financial implications. Young children become an victim of accidents easily because of their physical fragileness and their coping behavior being vulnerable to any actions taken by accidents. Once they have a accident, the children whose not fully developed, suffer from devastating long-term after-effects. Lee, Lee, Kang and Han(1995) reported that ninety percent of accidents can be prevented. But there is no national system to manage, evaluate and analyse the information about child accidents, even though it is necessary for accident prevention policies and health promotion of the general public. The purpose of the study was to determine how often children have accidents and define the accident prevention strategies in children. The investigator conducted a descriptive study by performing the surveys, interviews, and workshops for the 2,458 young children, 10 teachers, and 1,494 parents. The data collection for the study began on September 2000 and completed on April 20, 2001. The analysis of the data was done with Window SPSS 10.0 for descriptive statistics. Among those children, 1,298 children(52.8%) injured from accidents. The children who had accident answered that they injured from traffic accident(27.3%), inside the home(26.3%), on the playground(17.0%), during playtime(13.6%), in the school(5.9%) and food poisoning(7.1%). To define accident prevention strategies for the school children, the parents and the teachers who had a special interest in this topic formed a special task force under the guidance of the investigator. The team was charged to prepare the basis of content materials by identifying the problems, setting standards for the program, prioritizing the process, and selecting the methods of implementation and evaluation. Eight issues and concerns identified by the team were: 1)allowing young children to learn undesirable habits and behaviors that would bother others without knowing; 2) not guarding young children from car accident; 3)unattended accident at playground; 4) considering home places safe; 5)unattended accident at school. These issues were found to be coinciding with the actual child accident cases occurred recent years in Korea. Greater efforts are required to reduce unnecessary deaths and disability from childhood accidents. This study gave a very useful and important data to prepare accident prevention educational program and to prepare accident prevention strategies.

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Efficacy and Safety of Electroacupuncture and Acupuncture in Postmenopausal Women with Overactive Bladder; a Pilot Study of Randomized Clinical Controlled Trial (폐경 여성의 과민성 방광에 대한 전침 치료와 침 치료의 유효성과 안전성 평가 ; 무작위 대조군 예비 임상시험)

  • Nam, Eun-Young;Jung, Seung-Hyun;Bae, In-Suk;Choi, Su-Ji;Kim, Dong-Il
    • The Journal of Korean Obstetrics and Gynecology
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    • v.31 no.1
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    • pp.84-98
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    • 2018
  • Objectives: The purpose of this pilot study was to examine the feasibility of recruiting women into a clinical trial designed to examine the effects of acupuncture and electroacupuncture in treating overactive bladder (OAB) in menopause women. We tried to determine if there was preliminary evidence to suggest that acupuncture may be effective in reducing OAB symptoms and improving disease-specific quality of life. We also tried to determine the appropriate treatment duration of OAB, with safety of performing acupuncture and electroacupuncture treatment. Methods: This study was a randomized clinical trial. 7 menopause women were randomly assigned to a electroacupuncture group (EA group) (n=4) or acupuncture group (AC group) (n=3) and received electroacupuncture or acupuncture treatment twice a week (16 sessions) in 8 weeks, and follow up assessment was performed after the end of treatment. Overactive Bladder Symptom Score (OABSS), 3-day bladder diary, and King's Health Questionnaire (KHQ) were performed 4 times (at baseline (visit 0), the middle of treatment (visit 8), after the end of treatment (visit 16), and at 4 weeks of follow-up (visit 17)) and analyzed. 2 subjects were dropped out, and finally 5 subjects completed the study. Statistical analysis was performed using SPSS 18.0 for window program. Results: There was an significant improvement in night-time frequency after the treatment (visit 17) in PP (Per-protocol) group analysis (p=0.042). In additional ITT (Inter-to-treat) group analysis, the OABSS (p=0.042) and night-time frequency (p=p=0.017) were improved significantly after the treatment (visit 17). But there was no significant difference of KHQ before and after the treatment. Also there was no significant difference between EA and AC group after the treatment (visit 16, 17). Conclusions: The results of this pilot study suggested that it was feasible to recruit subjects and perform the study procedures, after reconstructing several details of study protocol in performing further clinical trial.