• Title/Summary/Keyword: well diffusion

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High energy laser heating and ignition study

  • Lee, K.C.;Kim, K.H.;Yoh, J.J.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.525-530
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    • 2008
  • We present a model for simulating high energy laser heating and ignition of confined energetic materials. The model considers effect of ablation of steel plate with long laser pulses and continuous lasers of several kilowatts and the thermal response of well-characterized high explosives for ignition. Since there is enough time for the thermal wave to propagate into the target and to create a region of hot spot in the high explosives, electron thermal diffusion of ultra-short(femto- and pico-second) lasing is ignored; instead, heat diffusion of absorbed laser energy in the solid target is modeled with thermal decomposition kinetic models of high explosives are used. Numerically simulated pulsed-laser heating of solid target and thermal explosion of cyclotrimethylenetrinitramine(RDX), triaminotrinitrobenzene(TATB), and octahydrotetranitrotetrazine(HMX) are compared to experimental results. The experimental and numerical results are in good agreement.

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Prediction of Chloride Profile considering Binding of Chlorides in Cement Matrix

  • Song, Ha-Won;Lee, Chang-Hong;Ann, Ki Yong
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.81-88
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    • 2009
  • Chloride induced corrosion of steel reinforcement inside concrete is a major concern for concrete structures exposed to a marine environment. It is well known that transport of chloride ions in concrete occurs mainly through ionic/molecular diffusion, as a gradient of chloride concentration in the concrete pore solution is set. In the process of chloride transport, a portion of chlorides are bound in cement matrix then to be removed in the pore solution, and thus only the rest of chlorides which are not bound (i.e. free chlorides) leads the ingress of chlorides. However, since the measurement of free/bound chloride content is much susceptible to environmental conditions, chloride profiles expressed in total chlorides are evaluated to use in many studies In this study, the capacity of chloride binding in cement matrix was monitored for 150 days and then quantified using the Langmuir isotherm to determine the portions of free chlorides and bound chlorides at given total chlorides and the redistribution of free chlorides. Then, the diffusion of chloride ion in concrete was modeled by considering the binding capacity for the prediction of chloride profiles with the redistribution. The predicted chloride profiles were compared to those obtained from conventional model. It was found that the prediction of chloride profiles obtained by the model has shown slower diffusion than those by the conventional ones. This reflects that the prediction by total chloride may overestimate the ingress of chlorides by neglecting the redistribution of free chlorides caused by the binding capacity of cement matrix. From the evaluation, it is also shown that the service life prediction using the free chloride redistribution model needs different expression for the chloride threshold level which is expressed by the total chlorides in the conventional diffusion model.

Comparison of the ICT Adoption Pattern;In the Case of Korea and the U.S.

  • Yang, Kyung-Hoon;Lee, Sang-Gun
    • 한국경영정보학회:학술대회논문집
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    • 2007.06a
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    • pp.545-550
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    • 2007
  • The aim of this paper is to find out whether there is a difference in adopting and/or diffusing the information and communication technology (ICT) between countries. If there is, what are the primary factors that keep some countries from adopting and diffusing ICT while others do? To analyze the above problem, we adopted the Unified Theory of Acceptance and Use of Technology (UTAUT) suggested by Venkatesh et al. (2003), which consists of effort expectancy, performance expectancy and social influence. We also use the innovation diffusion functions, which are known to have the S-shape and are made up of the introduction, growth, maturity and decline phases. We do not, however, consider the decline phase, because the ICT that we are considering is not believed to be in that phase. Therefore, we researched how the three factors affect adoption in the three phases. We selected the cellular phone as the ICT, because it is considered to be the most popularly used ICT and its technology has been developing rapidly. We surveyed the cellular phone adopters in Korea, and the U.S. for 15 years from 1989 to 2003. Korea, and the U.S. represent newly developed and developed countries, respectively. For the data analysis, a survival analysis was used, as it could explain the characteristics of the potential adopters or non-adopters. We found that the ICT diffusion patterns, as well as the ICT diffusion factors, of the two countries were different. Therefore, we believe that the results of our research can be used in building strategies on reducing the digital divide gaps between countries.

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Effect of Chemical Interaction on Flame Extinction in Interacting H2-air and CO-air Premixed Flames (H2-공기와 CO-공기의 예혼합화염의 화염소화에 있어서 화학적 상호작용의 효과)

  • Jung, Seongwook;Park, Jeong;Kwon, Ohboong;Keel, Sangin;Yun, Jinhan
    • Journal of the Korean Society of Combustion
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    • v.18 no.4
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    • pp.44-52
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    • 2013
  • Important role of chemical interaction in flame extinction was numerically investigated in downstream interaction among lean(rich) and lean(rich) premixed as well as partially premixed $H_2$-air and CO-air flames. The strain rate varied from 30 to $5917s^{-1}$ until interacting flame could not be sustained anymore. Flame stability diagrams mapping lower and upper limit fuel concentrations for flame extinction as a function of strain rate are presented. Highly stretched interacting flames were survived only within two islands in the flame stability map where partially premixed mixture consisted of rich $H_2$-air flame, extremely lean CO-air flame, and a diffusion flame. Further increase in strain rate finally converges to two points. Appreciable amount of hydrogen in the side of lean $H_2$-air flame also oxidized the CO penetrated from CO-air flame, and this reduced flame speed of the $H_2$-air flame, leading to flame extinction. At extremely high strain rates, interacting flames were survived only by a partially premixed flame such that it consisted of a very rich $H_2$-air flame, an extremely lean CO-air flame, and a diffusion flame. In such a situation, both the weaker $H_2$-air and CO-air flames were parasite on the stronger diffusion flame such that it could lead to flame extinction in the situation of weakening the stronger diffusion flame. Particular concerns are focused on important role of chemical interaction in flame extinction was also discussed in detail.

Evaluation on the Chloride Ion Diffusion Coefficient of Mortar Depending on Replacement Ratio of Recycled Fine Aggregate (순환잔골재 치환율에 따른 모르타르의 염화물이온확산계수 평가)

  • Lee, Sang-Yun;Yoo, Jae-Chul;Kim, Gyu-Yong;Yoon, Min-Ho;Nam, Jeong-Soo;Choi, Hyeong-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.6
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    • pp.479-485
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    • 2016
  • This paper presents an experimental study conducted to investigate the effect of recycled fine aggregate (RFA) on the mechanical properties and chloride diffusion behavior of mortar. The test results revealed that the addition of RFA plays an important role in the mechanical properties and pore structures of the investigated mortar specimens as well as chloride diffusion behavior. The mechanical properties such as compressive strength and flexural strength of recycled fine aggregate mortar (RFAM) were gradually decreased as RFA replacement ratio increase. The pore structure of RFAM was examined by permeability tests. The RFAM showed a increment in the permeability according to replacement ratio increase of RFA. But the chloride diffusion coefficient of RFAM was almost same up to 50% replacement ratio of RFA due to a chloride binding phenomenon of RFAM which may compensate the higher permeability of RFAM.

Fabrication of Lightweight Sandwich Structural Components with Superplastic Forming/Diffusion Bonding Technology (초소성/확산접합 기술을 이용한 티타늄 샌드위치 경량구조물 제작)

  • Lee, Ho-Sung;Yoon, Jong-Hoon;Yi, Yeong-Moo;Shin, Dong Hyuk
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.9
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    • pp.778-782
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    • 2007
  • In the present study, design and forming process of fabricating titianium lightweight components are developed with applicaton of superplastic forming and diffusion bonding technology. SPF/DB(Superplastic forming/Diffusion bonding) technology is one of the advanced technologies to reduce production cost and weight and currently applied to aircrafts and space launchers in foreign countries. The present study constructs an analysis model to predict superplastic forming behavior of titanium alloy, which is well known for its resistance to deform. The experimental results show the forming of titanium lightweight sandwich structure is successfully performed from 3 sheets of Ti-6Al-4V. The results demonstrate that the developed technology to process design of SPF/DB by the finite element method can be applied to various types of components.

Adsorption Characteristics of Antibiotics Amoxicillin in Aqueous Solution with Activated Carbon Prepared from Waste Citrus Peel (폐감귤박으로 제조한 활성탄을 이용한 수중의 항생제 Amoxicillin의 흡착 특성)

  • Kam, Sang-Kyu;Lee, Min-Gyu
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.369-375
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    • 2018
  • Batch experiments were conducted to investigate the effects of operating parameters such as the temperature, initial concentration, contact time and adsorbent dosage on the adsorption of antibiotics amoxicillin (AMX) by waste citrus peel based activated carbon (WCAC). The kinetics and isotherm experiment data can be well described with the pseudo-second order model and the Langmuir isotherm model, respectively. The maximum adsorption capacity of AMX by WCAC calculated from the Langmuir isotherm model was 125 mg/g. The adsorption of AMX by WCAC shows that the film diffusion (external mass transfer) and the intraparticle diffusion occur simultaneously during the adsorption process. The adsorption rate is more influenced by the intraparticle diffusion than that of the external mass transfer as the particle size of WCAC increases, and the intraparticle diffusion is the rate controlling step. The thermodynamic parameters indicated that the adsorption reaction of AMX by WCAC was an endothermic and spontaneous process.

Introduction of Numerical Analysis Method for Calculation of Diffusion Property in Interlayer Water of Expansible Clay Mineral (팽창성 점토광물 내 층간수의 확산특성분석을 위한 수치해석학적 방법)

  • Choi, Jung-Hae;Chae, Byung-Gon;Chon, Chul-Min
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.211-220
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    • 2012
  • The numerical modeling and simulation have been used increasingly as tools for examining and interpreting the bulk structure and properties of materials. The use of molecular dynamics (MD) simulations to model the structure of materials is now both widespread and reasonably well understood. In this research, we introduced the numerical method to calculate the physico-chemical properties such as a diffusion coefficient and a viscosity of clay mineral. In this research, a series of MD calculations were performed for clay mineral and clay-water systems, appropriate to a saturated deep geological setting. Then, by using homogenization analysis (HA), the diffusion coefficients are calculated for conditions of the spatial distribution of the water viscosity associated with some configuration of clay minerals. This result of numerical analysis is quite similar to the previous experimental results. It means that the introduced numerical method is very useful to calculate the physico-chemical properties of clay minerals under various environmental conditions.

Removal of Trihalomethane Using Activated Carbon (활성탄(活性炭)을 이용(利用)한 Trihalomethane의 제거(除去)에 관한 연구(研究))

  • Chung, Tai Hak;Chung, Jae Chul
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.3 no.1
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    • pp.73-79
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    • 1983
  • Activated carbon has been widely used in water and wastewater treatment for removal of trace organics. The objective of this study was to define adsorption characteristics of trihalomethane(THM) on granular activated carbon(GAC) surfaces by laboratory experiments. Synthetic samples were prepared by adding chloroform into distilled and deionized water. The experiments conducted were a batch run and isotherm studies with five different temperature-pH levels. Adsorption of THM on GAC at an equilibrium condition was well described by the Freundlich isotherm equation. Lower temperature favored the adsorption, but the effect of pH was negligible. Utilizing the results of a batch run and the isotherm results, three parameters, mass transfer coefficient, pore diffusion coefficient, and surface diffusion coefficient, were evaluated by comparing with simulation results of an adsorption model. The results also showed that the pore diffusion was much greater than the surface diffusion.

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Susceptibility Testing of Helicobacter pylori to Metronidazole and DNA Fingerprints of Resistant Strains in Singapore

  • HUA, JIESONG;KHAY-GUAN YEOH;PENGYUAN ZHENG;HAN CHONG NG;BOW HO
    • Journal of Microbiology and Biotechnology
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    • v.9 no.3
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    • pp.328-333
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    • 1999
  • Susceptibility of 61 strains of Helicobacter pylori to metronidazole was examined by both the disk diffusion method using a cut-off of 15㎜ for resistance and the E test with a cut-off of 8㎎/l. The MIC/sub 50/ and MIC/sub 90/ by the E test were 2 ㎎/l and 256㎎/l, respectively. Metronidazole resistance was found in 22 (36%) out of the 61 H. pylori strains by the E test and in three additional strains by the disk diffusion method. Amongst the latter three isolates, the MICs by the E test were 4 ㎎/l, 6㎎/l, and 6㎎/l, respectively. These figures are one log₂ or half log₂ dilution lower than the cut-off of 8㎎/l recommended as resistance for the E test. All 22 metronidazole resistant H. pylori isolates by the E test that were subjected to random amplified polymorphic DNA (RAPD) fingerprinting showed different DNA fingerprints. Interestingly, >90% of resistant isolates possess two common DNA bands of 0.4 and 0.9 kb. This study demonstrates that the results of the disk diffusion method for testing H. pylori susceptibility to metronidazole correlates well with that of the E test. The criteria for interpretation need to be internationally standardized so that the results from different centers can be compared.

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