• Title/Summary/Keyword: weathering product

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Evaluation method for time-dependent corrosion depth of uncoated weathering steel using thickness of corrosion product layer

  • Kainuma, Shigenobu;Yamamoto, Yuya;Ahn, Jin-Hee;Jeong, Young-Soo
    • Structural Engineering and Mechanics
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    • v.65 no.2
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    • pp.191-201
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    • 2018
  • The corrosion environments in a steel structure are significantly different depending on the individual parts of the members. To ensure the safety of weathering steel structures, it is important to evaluate the time-dependent corrosion behavior. Thus, the progress and effect of corrosion damage on weathering steel members should be evaluated; however, the predicted corrosion depth, which is affected by the corrosion environment, has not been sufficiently considered until now. In this study, the time-dependent thicknesses of the corrosion product layer were examined to quantifiably investigate and determine the corrosion depth of the corroded surface according to the exposure periods and corrosion environments. Thus, their atmospheric exposure tests were carried out for 4 years under different corrosion environments. The relationship between the thickness of the corrosion product layers and mean corrosion depth was examined based on the corrosion environment. Thus, the micro corrosion environments on the skyward and groundward surfaces of the specimens were monitored using atmospheric corrosion monitor sensors. In addition, the evaluated mean corrosion depth was calculated based on the thickness of the corrosion product layer in an atmospheric corrosion environment, and was verified through a comparison with the measured mean corrosion depth.

Mineralogical Characteristics and Formation Environment of Kaolin Minerals in the Weathering of Granitoids: Weathering of Biotite in Palgongsan Granite (팔공산 화강암내 흑운모의 풍화과정에서 생성되는 고령토광물들의 광물학적 특성 및 생성 환경)

  • 정기영
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.97-105
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    • 1998
  • Weathering of biotite in Palgonsan granite was studied by using X-ray diffraction, optical microscopy, scanning electron microscopy, and electron probe micro analysis. Biotite altered to biotite/vermiculite regular mixed layer mineral (B/V) in the early stage of weathering. Although partially replaced by kaolinite with the progress of weathering. B/V is the major weathering product of biotite throughout the profile. During the formation of B/V, Mg, Fe and K are removed from a biotite layer to form a vermiculite layer by about 28%, 44% and 88%, respectively, whereas the Ti content is not changed. Considerable volume increase after the kaolinitization of B/V suggests that Al and Si are largely introduced from the external weathering solution. The silicate lattice templet of a weathering biotite facilitated the nucleation and growth of kaolinite. In the Palgongsan granite weathering profile, plagioclase weathered mostly into halloysite whereas biotite greatly contributes to the kaolinite crystallization though its small content in fresh rock.

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The Effect of a Freeze-Thaw Cycle on Rock Weathering: Laboratory Experiments (동결-융해작용에 따른 암석풍화의 특성)

  • YANG, Jae-Hyuk
    • Journal of The Geomorphological Association of Korea
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    • v.18 no.3
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    • pp.21-36
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    • 2011
  • Rock Weathering is a basic of geomorphological evolution as a preparation of materials. Of those, frost shattering has traditionally been considered as the operative process causing rock breakdown in cold regions as well as temperate zone. Each Granite(fresh rock, semi-weathered), Gneiss, Limestone, Dolomite was prepared slab specimens in ten, repeated freeze-thaw cycles of 180 under the -25℃~+30℃, and the changes was observed in physical properties and weathering aspect. Rock shattering was more active in waterlogging conditions rather than atmospheric and soil conditions. Limestone and Dolomite that high porosity are most severely crushed. Gneiss, regardless surface of the crack, joint, fissure and has a lowest rock strength(SHV), was even though no physical changes and their weathering product do not generate, has a very high resistance to weathering.

Petrological Characteristics and Deterioration phenomena of the rocks consisting the Naju-Dongmunoi-Seogdanggan(Stone Stele) (나주동문외석당간 구성암석의 암석학적 특징과 훼손양상)

  • Lee, Sang-Hun
    • Journal of Conservation Science
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    • v.19
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    • pp.57-66
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    • 2006
  • The rock consisting the Naju-Dongmunoi-Seogdanggan (Stone Stele)(Treasure number 49) is biotite granite of medium to coarse grains which might be taken from nearby area. The rock is mainly composed of quartz, plagioclase, alkali feldspar and biotite. Due to strong weathering grail peel-off and surface exfoliation are well developed. The rock surface is changed into pale brown or pale black colors according to weathering, organism and weathering product of iron band. Major deterioration phenomena are grain peel-off, surface exfoliation, cracks and damage which may be originally classified into weathering, effect of weathering product of iron band, organisms, structural unstabilities and impact.

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A Study on the Indexes and Properties of Mechanical Weathering to Granite Distributed in Korea (화강암의 풍화산물에 대한 기계적 풍화지수의 특성에 관한 연구)

  • Rheem, Chong-Ho
    • Journal of the Korean Geographical Society
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    • v.28 no.2
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    • pp.99-111
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    • 1993
  • The transformation of rocks into unconsoli-dated debris is the prime geomorphic processes including weathering and soil forming process. In these processes, rocks tend to be unconsol-idated debris with small particles. Particularly, typical granite is more likely affected by weathering, since the rock consists of quartz, feldspar and mica that can be easily coarse-grained and well jointed without bedding. The purposes of this study are to clarify the index and properties of mechanical weathering that contributed to transformation of granite distributed in Korea. A total of seventy-three samples of weathering products of granite in Korea were collected during the three-year period, March 30, 1989 to February 21, 1992. The prticle analysis was performed for clay, silt and sand using Sieve and Hydrometer. The results of the analysis are as the followings: First, soil textures in the study area are included seven categories of textures as C, CL, SCL, Sil, SL, LS, and S. Among these textures, the most frequent soil texture were SL, S and SCL in order. Second, the weathering products of granite are crumbled by weathering and hydrothermal. Clay texture consisted of fine materials seems to be influenced by hydrothermal, while Sand texture composed of coarse materials, seems to be significantly influenced by weathering. Third, the index of mechanical weathering by region indicates that Hawngdeung(1) is the lowest as 2.37 and the index by soil texture shows that Clay texture is the lowest as 2.46. Forth, the regression analysis of MW showes that sand/clay variable is the most significant variable. Finally, pedochemical weathering is prevailed on the clayey gruss and geochemical weathering is on the gruss and shattering is on the weathered rock, strongly, but the fine materials in some sites were formed by argillation of hydrothermal.

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Mineralogical and Chemical Variation in Weathering Profile on Ultramafic Rocks During Vermiculitization (질석화가 진행된 풍화단면에서의 광물조성과 주원소의 변화)

  • Moon, Hi-Soo;Song, Yungoo;Sin, Sang Eun
    • Economic and Environmental Geology
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    • v.26 no.1
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    • pp.29-40
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    • 1993
  • Several vermiculite deposits occur as the alteration product from phlogopite in ultramafic rock, in the Hongseong and Cheongyang area, South Korea. Some quarries show well-defined weathering profile. Samples collected from those quarries were examined by XRD and chemistry to define a vertical variations in mineralogy and chemistry of the weathering profile developed on ultramafic rocks. The analysis by X-ray diffractometry showed that mineral compositions changed continuously as depth of profile increasing, the vermiculite-the phlogopite/vermiculite interstratified-the phlogopite. Chemical analysis of bulk samples in altered zone revealed that regardless of composition and kinds of mineral in the rock, there are significant increase of MgO, CaO and $H_2O$, and decrease of K as depth of profile decrease reflecting the characteristics in vermiculitization. Also, there was a tendency that weathering indicies of each sample horizon change gradually with increasing depth. This tendency can be explained as variations of degree of vermiculitization. The regular changes of mineralogical and chemical composition in vertical profile suggest that weathering is the most important process in vermiculitization in this area.

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Oxidized Biotite in the Weathering Profile of Andong Cranite (안동화강암의 풍화단면에서 산출되는 산화흑운모)

  • 정기영;김혜빈
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.3
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    • pp.183-194
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    • 2002
  • Biotite and its weathering Products in the weathering Profile of Andong granite were examined using X-ray diffraction, chemical analysis, and electron microscopy. Major weathering product of biotite was oxidized biotite, which is decomposed into kaolinite in the upper part. Discrete vermiculite or hydrobiotite was not detected although minor vermiculite (5%) was randomly interstratified with oxidized biotite. Excess positive charge induced by iron oxidation was balanced by release of Fe (16%) and Mg (12%) from octahedral site and K (13%) from interlayer site. After slight chemical and structural modification induced by iron oxidation, oxidized biotite persists through the weathering profiles with partial decomposition in the upper part of the profile. Formation environments and dissolution experiments of oxidized biotite highly resistant to weathering are required to understand the elemental behavior in the surface environments on the biotite-bearing bedrocks.

Supergene Alteration of Amphibole in Suryun Kaolin Deposits: Mineralogical and morphological Studies (수륜 고령토광산에서 산출되는 각섬석의 표성 변질작용: 광물학적 및 형태적 연구)

  • 김수진;아비드무타자칸;이동진
    • Journal of the Mineralogical Society of Korea
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    • v.2 no.1
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    • pp.37-46
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    • 1989
  • X-ray, optical and electron microscope studies exhibit that the amphiboles in anorthositic saprolite from kaolin deposits, located in Suryun-myeon, Seongju-gun, Kyungsangbuk-do, have altered under weathering conditions to smectite, mixed-layer mineral, vermiculite and goethite. In early supergene alteration stage when rock structure is still preserved, smectite occurs as initial weathering product of amphibole. Further weathering leads to the formation of mixed-layer mineral, vermiculite and goethite as indicated by XRD and SEM studies. Scanning electron microscopy studies of amphibole show that the dissolution of amphibole proceeds by selective etching at the surface along weaker zones producing distinct etch pattern, The calcic amphiboles according to electron microprobe analyses, show leaching of the most mobile elements (Mg, Ca and Fe) during alteration.

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Mineralogical Changes in the Weathering Profiles of Carnin Gneiss in the Yoogoo Area, Korea (유구지역 화강암질 편마암의 풍화작용에 의한 광물 조성의 변화)

  • 이석훈;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.3
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    • pp.121-137
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    • 2000
  • Weathering profiles which were developed under a temperate, humid environment and relatively steep geography, show a thick saprolite and soil horiaon in the Precambrian granitic gneiss of the Yoogoo area. In the weathering profiles, secondary minerals such as interstratified biotite/vermiculite, tri- or di-octahedral vermiculite, halloysite, kaolinite, illite, smectite, gibsite and geothite were observed. Kaolinization of biotite is the most prevalent mechanism but vermiculitization is a minor from all ofweathering profiles. Biotite altered to B/V mixed layer-vermiculite, to illite and to halloysite, kaolinite and gibbsite. Halloysite is the most frequently observed weathering product of biotite in these profiles. Goethite is observed at the around or opened fissures of altered biotite. Tubular halloysite aggregates was fDrmed from dissolution-precipitation of plagioclase. The occurrence of halloysite aggregates is divided into a preferentially oriented type and a wrinkled one which were resulted from the dissolved type of plagioclase. Fe-bearing minerals have also been subjected to dissolution leaving the precipitation of geothite along dissolution voids. The profile of granitic gneiss is a typical weathering pattern showing a clay minerals increase toward the surface. Weathering of minerals were controlled by locally acidic and good-drainage environment, and formed a various and complicated secondary minerals in this study area.

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Mineralogical Changes Caused by the Weathering of Tailings Deposited on the Riverside of the Nakdong River, Bonghwa, Korea (봉화군 일대 낙동강변에 퇴적된 광미의 풍화에 따른 광물학적 변화)

  • Kim, Min-Jung;Kim, Yeong-Kyoo;Park, Hyoung-Sim;Jeon, Sang-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.4
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    • pp.331-339
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    • 2008
  • In the upstream of Nakdong river in Bonghwa-gun, Gyeongsangbuk-do, certain areas of riverside were found to be covered by weathered mine tailings which were assumed to be migrated and deposited by flood. This study was conducted to investigate the formation and characteristics of the secondary minerals from tailings and related leaching behavior of heavy metals in the severely weathered tailing deposits by river waters. Quartz, feldspar, micas, chlorite, hornblende, talc, pyroxene (johannsenite), pyrite, and calcite were identified as primary minerals by XRD. Kaolinite can be formed by the weathering of tailings, but considering the short period of weathering time, kaolinite in the deposits is considered to be from unweathered tailings or moved from soils. The secondary minerals such as goethite, gypsum, basanite, and jarosite were also identified. The formation of the secondary minerals was affected by the species of primary minerals and pH conditions. The weathering of pyrite produced sulfate minerals such as gypsum, basanite, jarosite, and also goethite. Mn oxide was also identified by SEM, coated on the primary minerals such as quartz. This Mn oxide was poorly crystalline and thought to be the weathering product of johannsenite (Mn-pyroxene). The Fe and Mn oxides are the main minerals determining the brown/red and black colors of weathered tailings. EDS results showed that those oxides contain high concentrations of Pb, Zn, and As, indicating that, in the river, the formation of Fe and Mn oxides can control the behavior and leaching of heavy metals by co-precipitation or adsorption.