• Title/Summary/Keyword: water oxidation

Search Result 1,776, Processing Time 0.027 seconds

Complete Decomposition of Chlorinated-Organic Compounds(PCB, 4-DCBz) with Improved Supercritical Water Oxidation Method (개량된 초임계수 산화법에 의한 염소계 유기물(PCB, 4-DCBz)의 완전분해반응)

  • Lee Sang-Hwan;Park Ki-Chul;Park Yoon-Yul;Yang Jong-Gyu;Kim Jung-Sung;Hiroshi Tomiyasu
    • Journal of Environmental Science International
    • /
    • v.14 no.5
    • /
    • pp.513-520
    • /
    • 2005
  • For the destruction of toxic chlorinated organic compounds, this study proposes improved supercritical water oxidation method (multistep oxidation) using sodium nitrate as an oxidizer. This method solves the problems involved in the existing supercritical water oxidation method. Multistep oxidation means that $NaNO_3$ is oxidized to $N_2\;via\;NaNO_2$ and NO. Toxic and hard to destroy organic substances like para-dichlorobenzen(4-DCBz), polychlorinate biphenyl(PCB) ware oxidized to non toxic substances in a condition, in which rapid pressure and temperature rise is restrained as much as possible. 4-dichlorobenzene(4-DCBz) and Polychlorinate biphenyl(PCB) in condition$(450^{\circ}C,\;p_w=0.25g/cm^3,\;30min)$ Was discomposed perfectly.

Development of Depot Encircled with Oxidation Canal for Water Quality Improvement (수질 개선을 위한 침전산화수로 개발)

  • 김원장;박상현
    • Magazine of the Korean Society of Agricultural Engineers
    • /
    • v.42 no.6
    • /
    • pp.83-89
    • /
    • 2000
  • A depot encircled with contact oxidation canal has been developed to improve water qualityr. The depot is aimed to settle suspended solid in the flow. The oxidation canal is to contact the pollutants and oxygen in the surface of gravel filter to purify the water. The deposit of the pollutant in the depot is released by the drainage culvert located at the bottom of it. Aeration nozzle is installed to supply enough oxygen to the gravel filter layers in the bottom of the detent the flow and improve oxidation efficiency. From the experiment it is founded that 91% of SS, 39% of TN, 63% of TP and 77% of COD were removed in the system. The treatment efficiency of total nitrogen is rather lower than any other components, however, it would be higher when some floating vegetation is added in the primary clarifier. The depot and oxidation canal system would be useful to purify the flows in the mouth of the reservoirs or at the outlet of the drainage canal.

  • PDF

Removal of Bisphenol-A using Rotating Photocatalytic Oxidation Drum Reactor (RPODR)

  • Son, Hee-Jong;Jung, Chul-Woo;Kim, Seung-Hyun
    • Environmental Engineering Research
    • /
    • v.13 no.4
    • /
    • pp.197-202
    • /
    • 2008
  • This study evaluated the photocatalytic oxidation of BPA using the RPOD reactor under various conditions. This study found that the RPOD was effective for BPA degradation. It could reduce 1 mg/L of BPA by half within 5 min under the optimum conditions. According to the study results, $TiO_2$ coating was important for the BPA oxidation. As the coating thickness increased, the removal efficiency improved. The light source, the light intensity and the drum rotating speed were important for the oxidation. The UV light was more effective for the BPA degradation than the visible light. The removal efficiency improved with increasing intensity. As the drum speed increased, the removal efficiency improved. The maximum speed was 240 rpm in this study. Addition of air and nitrogen was not beneficial for the BPA degradation in this study probably due to enough oxygen in the water.

A Study on Treatment of Livestock wastewater using Fenton Oxidation and Zeolite Adsorption Process (Fenton 산화공정과 Zeolite 흡착공정을 연계한 축산폐수처리에 관한 연구)

  • Cho, Chang-Woo;Kim, Youn-Jeong;Chung, Paul-Gene
    • Journal of Korean Society on Water Environment
    • /
    • v.21 no.5
    • /
    • pp.505-510
    • /
    • 2005
  • The objective of this study was to remove non-biodegradable matters and ammonia ion in livestock wastewater using Fenton oxidation and Zeolite adsorption process. After coagulation process as 1st treatment, non-biodegradable matters remained after 1st treatment were removed by using OH radical produced in Fenton oxidation process. Zeolite as cation adsoption process was used to remove ammonia ion in 2nd treatment water. As a result of treatment using these processes, NBDCOD removal efficiency was over 90% and ammonia ion was almost removed. Most aromatics or polynuclear aromatics like benzene, phenol and scatol in livestock wastewater wasn't detected after Fenton oxidation process.

Manganese Removal in Water Treatment Processes (상수처리에서 망간 제거)

  • Kim, Jinkeun;Jeong, Sanggi;Kim, Jeongsook;Park, Sejin
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.19 no.5
    • /
    • pp.595-604
    • /
    • 2005
  • To determine the characteristics of manganese removal in Korea, 31 multi-regional water treatment plants (WTPs) were examined. The concentration of manganese in raw water was higher than the standards for drinking water at 2 WTPs. Manganese should be properly removed during water treatment processes to reduce the occurrence of black water in the distribution system because $Mn^{+2}$ can cause black deposits when it is oxidized. Manganese can effectively removed by oxidation, followed by sedimentation and filtration as well as absorption by greensand. Manganese absorption by greensand was the major mechanism for the removal of manganese, and it is effectively removed using this process. Regeneration of greensand using an oxidation agent was necessary for continuous and adequate removal of manganese.

Decomposition of PVC and Ion Exchange Resin in Supercritical Water

  • Kim Jung-Sung;Lee Sang-Hwan;Park Yoon-Yul;Yasuyo Hoshikawa;Hiroshi Tomiyasu
    • Journal of Environmental Science International
    • /
    • v.14 no.10
    • /
    • pp.919-928
    • /
    • 2005
  • This study introduces the development of new supercritical water oxidation(SCW)(multiple step oxidation) to destruct recalcitrant organic substances totally and safely by using sodium nitrate as an oxidant. This method has solved the problems of conventional SCW, such as precipitation of salt due to lowered permittivity, pressure increase following rapid rise of reaction temperature, and corrosion of reactor due to the generation of strong acid. Destruction condition and rate in the supercritical water were examined using Polyvinyl Chloride(PVC) and ion exchange resins as organic substances. The experiment was carried out at $450^{\circ}C$ for 30min, which is relatively lower than the temperature for supercritical water oxidation $(600-650^{\circ}C)$. The decomposition rates of various incombustible organic substances were very high [PVC$(87.5\%)$, Anion exchange resin$(98.6\%)$, Cationexchange resin$(98.0\%)$]. It was observed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium (salt formation). However, relatively large amount of sodium nitrate (4 equivalent) was required to raise the decomposition ratio. For complete oxidation of PCB was intended, the amount of oxidizer was an important parameter.

Pollutant Removal Efficiency in Oxidation Pond with Filamentous Algae Mat (사상성 조류매트 산화지의 수질정화효율)

  • Choi, Sun-Hwa;Jang, Jeong-Ryeol;Ahn, Yeul
    • Proceedings of the Korean Society of Agricultural Engineers Conference
    • /
    • 2005.10a
    • /
    • pp.655-660
    • /
    • 2005
  • This study was carried out to evaluate of water purification in oxidation pond with filamentous algae mat. It is the water treatment process in the small rural streams to remove the organic materials and nutrients. We used the filamentous algae mat(FAM) which selectively predominate the filamentous algae to prevent the additional contamination by algae outflow. The removal efficiencies of COD, SS, T-N and T-P in Oxidation Pond with Filamentous Algae Mat were -2.5%, 84.7%, 63.9% and 89.2%, respectively. The removal efficiencies of T-N and T-P which are nutrients index were high. Results of this study would help us to determine the possibility of using the water treatment on the contaminated small rural streams.

  • PDF

Effects of Clove Extracts on the Autoxidation and Thermal Oxidation of Soybean Oil (대두유의 자동산화 및 가열산화에 미치는 정향추출물의 항산화 효과)

  • 박상일;손종연
    • Korean journal of food and cookery science
    • /
    • v.20 no.1
    • /
    • pp.81-85
    • /
    • 2004
  • This study was conducted to investigate the antioxidant activities of clove extracts in water, methanol and ether. The clove extracts, BHA and ${\alpha}$-tocopherol were added to each oil at a level of 200 ppm. The activities of the substrate oils and controls were tested under autoxidation and thermal oxidation conditions. The degree of the effects of the antioxidant activities under autoxidation condition were in the following order; ether extract 〉 methanol extract 〉BHA 〉 ${\alpha}$-tocopherol 〉 water extract = control group. The induction periods of the control, water, methanol and ether extracts, and BHA and ${\alpha}$-tocopherol were 9.5, 9.6, 10.7 11.8, 10.4 and 9.7 days, respectively. Under thermal oxidation condition, the methanol extract showed stronger antioxidant activity than those of the water and ether extracts. The antioxidant activity of the methanol extract was attributed to ${\alpha}$-tocopherol and BHA.

Inhibition of lipid and protein oxidation in raw ground pork by Terminalia arjuna fruit extract during refrigerated storage

  • Chauhan, Pranav;Pradhan, Soubhagya Ranjan;Das, Annada;Nanda, Pramod Kumar;Bandyopadhyay, Samiran;Das, Arun K.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.32 no.2
    • /
    • pp.265-273
    • /
    • 2019
  • Objective: Terminalia arjuna plant, specially its leaves, bark, and roots, are widely used in traditional herbal medicine due to presence of bioactive components and being a rich source of natural antioxidants. But its fruit has not been used for any such purposes despite its potential to retard oxidation. Hence, the antioxidant potential of Arjuna fruit extract (AFE) in retarding lipid and protein oxidation of raw ground pork was evaluated during refrigerated storage for 9 days. Methods: The AFEs were prepared using different solvents viz. ethanol (EH), water, ethanol: water (60:40) and methanol:hot water (60:40). The AFEs were analysed for total phenolic content (TPC), 2, 2-diphenyl-1-picrylhydrazyl radical scavenging activity and reducing power. Water extract (WE) and ethanol-water extract (EH-WE) were selected and incorporated at 1.0% into freshly minced pork meat and compared with a synthetic antioxidant, in retarding lipid and protein oxidation during storage. Results: The TPC in AFEs using different solvents ranged from 11.04 to 16.53 mg gallic acid equivalents/g and extracts exhibited appreciable scavenging activity ranging from 50.02% to 58.62%. Arjuna extracts significantly (p<0.05) improved the colour score of meat samples by reducing the formation of metmyoglobin during storage. Both the AFEs (WE and EH-WE) significantly (p<0.05) lowered the thiobarbituric acid reactive substances value, peroxide formation and formation of protein carbonyls in raw pork than control sample during storage. Upon sensory evaluation of all samples, it was found that AFE treatment could prolong the storage period of meat samples, without influencing the colour and odour score, up to 6 days. Conclusion: AFEs used at 1% improved the oxidative stability, colour and odour score and prolonged the refrigerated shelf life of ground pork up 6 days. Therefore, AFE could be explored as an alternative natural antioxidant in retarding lipid and protein oxidation in meat products.

Study of optimal reduction plan for wastewater sludge generated from oil refinery (정유 공장에서 발생된 폐수 슬러지의 최적 감량화 방안 연구)

  • Choi, Jae-Woo;Jung, Jong-Min;Shim, Natalia;Lee, Sang-Hyup;Park, Cheol-Hee
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.24 no.4
    • /
    • pp.395-406
    • /
    • 2010
  • In this study, anaerobic digestion, electro-oxidation and electro-fenton oxidation processes were investigated to reduce oily refinery sludge. Anaerobic digestion process was not suitable for oily activated sludge reduction because of characteristics itself and, as experimental results revealed, reduction efficiency was low for electro-oxidation process. However, 40% total suspended solid reduction of oily activated sludge was obtained by electro-fenton oxidation process, operating at pH=1, 0.5 A and $Fe^{2+}$:$H_2O_2$ ratio = 1:30. In addition, higher reduction efficiency was obtained as reaction time was increased (30, 60, 90, 120 min) despite of low $H_2O_2$ concentration. From the results, it has been investigated that electro-fenton oxidation is efficient process for oily activated sludge reduction.