• Journal of the Korean Applied Science and Technology
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• v.27 no.3
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• pp.273-281
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• 2010

Nickel recovery method was studied by the wet process from the catalyst used in hydrogenation process. Nickel content in waste catalyst was about 16%. At the waste catalyst leaching system by the alkaline solution, selective leaching of nickel was possible by amine complex formation reaction from ammonia water and ammonium chloride mixed leachate. The best leaching condition of nickel from mixed leachate was acquired at the condition of pH 8. LIX65N as chelating solvent extractant was used to recover nickel from alkaline leachate. The purity of recovered nickel was higher than 99.5%, and the whole quantity of nickel was recovered from amine complex.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.2
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• pp.183-192
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• 2015

Response surface methodology (RSM) based on a Box-Behnken Design (BBD) was applied to optimize the thermal-alkaline pre-treatment operating conditions for anaerobic digestion of flotation scum in food waste leachate. Three independent variables such as thermal temperature, NaOH concentration and reaction time were evaluated. The maximum methane production of 369.2 mL $CH_4/g$ VS was estimated under the optimum conditions at $62.0^{\circ}C$, 10.1% NaOH and 35.4 min reaction time. A confirmation test of the predicted optimum conditions verified the validity of the BBD with RSM. The analysis of variance indicated that methane production was more sensitive to both NaOH concentration and thermal temperature than reaction time. Thermal-alkaline pretreatment enhanced the improvement of 40% in methane production compared to the control experiment due to the effective hydrolysis and/or solubilization of organic matters. The fractions with molecular weight cut-off of scum in food waste leachate were conducted before and after pre-treatment to estimate the behaviors of organic matters. The experiment results found that thermal-alkaline pre-treatment could reduce the organic matters more than 10kD with increase the organic matters less than 1kD.

• Journal of the Korean GEO-environmental Society
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• v.14 no.1
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• pp.61-68
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• 2013

This paper presents an experimental results on the environmental characteristics of waste tire. Experimental program includes a set of laboratory leaching tests and field pilot test for leachate analysis. Laboratory tests were conducted to illustrate how properties such as TOC, pH, turbidity and Zn change with tire sizes and drain conditions. In field pilot test, water samples were collected form a drainage system installed below the tire-reinforced retaining wall and analyzed for chemical quality. Laboratory leaching tests performed on various particle sizes of waste tire indicated that as tire size is increased, the concentration of leachate is decreased. In continuous flow column tests, the concentration of leachate decreased with the number of exposure periods or pore volumes flushed through the waste tire. However, during pause flow column tests, the concentration of leachates were increased with time. Field monitoring of effluent indicated that no significant adverse effects on ground water quality had occurred over a period of 12 months.

• Journal of Korean Society on Water Environment
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• v.18 no.2
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• pp.151-157
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• 2002

Landfill leachate is one of highly contaminated and heterogeneous wastewater. The leachate from initial landfill can be treated by anaerobic process because it contains biodegradable matters, particularly, volatile fatty acids (VFAs). However, the anaerobic treatment of leachate is generally required longer hydraulic retention time (HRT) than aerobic process and another treatment process to satisfy effluent concentration. Therefore the modification of conventional anaerobic treatment is needed. Two phase anaerobic membrane process (TPAMP) is an integrated membrane process to be able to separate anaerobic metabolism into two phase which are acidogenesis and methanogenesis for improvement of anaerobic treatment efficiency. In this study, the efficiency of TPAMP and conventional anaerobic treatment were compared in terms of HRT, effluent SCOD, VFAs Membrane used in TPAMP was the UF of capillary type with the surface area of $0.048m^2$. The average effluent SCOD of conventional anaerobic treatment was 1352 mg/L and the removal was 96 % at HRT 60 days, while in TPAMP, 927 mg/L and 98% at HRT 30 days.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.6
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• pp.307-312
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• 2005

Since alpine upland in Pyungchang-gun has been typically applied every two or three years with saprolite, agricultural by-products are inputted to raise soil properties. Therefore, the effect of saprolite application on water quality in runoff and leachate should be monitored. To investigate water quality in runoff and leachate with various treatments of agricultural by-product, lysimeter with dimension of $0.85m{\times}1.75m{\times}0.30m$ was installed in Kangwon National University. Control, mixed compost with cow, chicken and sawdust by-product (CCSC), chicken manure by-product compost (CC), food waste by-product compost (FWC), and beer sewage sludge by-product compost (BSSC) at the rate of $10Mg\;ha^{-1}$ were mixed with soil in 25 cm depth, and water qualities in runoff and leachate were monitored from Jun. 4, 2004 to Oct. 18, 2004. EC ($0.8-2.2dS\;m^{-1}$) and concentrations of total N ($25-75mg\;L^{-1}$) and total P ($0.12-0.43mg\;L^{-1}$) were highest in both runoff and leachate of CC treatment. EC values in CC and FWC treatments continuously increased during lysimeter experiment, while total N and total P concentrations continuously decreased. Average total N concentrations in runoff taken from CCSC, FWC and BSSC treatments were 41, 34 and $37mg\;L^{-1}$, and in leachate were 35, 28 and $34mg\;L^{-1}$, respectively. Average total P concentrations were not different with different treatments. EC values in leachate were higher than those in runoff, and total N concentrations in runoff were higher than those in leachate.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.182-186
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• 2001

An acid forest surface soil as a land farming medium was treated with a water plant alum sludge at 0 to 18%. Indian mustard was grown in the treated soil in a greenhouse for 5 weeks and watered with pH 4 tap water adjusted with a mixed acid (1HNO$_3$: 2H$_2$SO$_4$) during plant growth. Changes in soil property, leachate chemistry, plant growth, and plant uptake of elements by the sludge treatment were determined. The alum sludge treatment increased buffer capacity to acidity, hydraulic conductivity, water holding capacity, and phosphate adsorption of the soil and decreased bulk density and mobility of small particles. The sludge treatment reduced leaching of Al, Mg, K, Na, and root elongation. Plant did uptake less amount of the cations and P but more Ca with the sludge treatment.

• The Korean Journal of Pesticide Science
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• v.9 no.4
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• pp.330-337
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• 2005

This study was investigated to elucidate the pesticide mobility in three different soil textures(Heongseong sandy loam; Chuncheon, loam; Taeback, silty clay loam) and four different gravel contents(0, 20, 40, 60%) of Taebaek soil using soil column. Carbofuran, which ranks the highest water solubility among 7 pesticides(carbendazim, carbofuran, chlorpyrifos, cypermethrin, dimethomorph, diniconazole and endosulfan) was defected over 87% in leachate samples within all soil types from early sampling time. Amount of 5 residual pesticides excluding carbendazim and carbofuran were ordered silty clay loam > loam > sandy loam, indicating pesticide residues are related to percentage of clay contents in soils. Comparing the amount of residual pesticides in soil column(upper, middle and lower layer), 6 pesticides apart from carbofuran were found in the range of $50{\sim}92%$ on the upper layer of silty clay loam and loam. Mobility of pesticides either in soil or leachate samples is dependant on water solubility of pesticide and clay content of soil. The results obtained from four different gravel contents of Tacback soil were similar to the results of three different soil textures. Also it was found that more the gravel contents, faster the flow velocity of leachate water. These results possibly provide an idea to select proper pesticides and to reduce soil and water contamination at alpine and sloped-land.

• Journal of the Korean Geotechnical Society
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• v.17 no.6
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• pp.215-224
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• 2001

The concept that the electrical properties of subsurface material can be affected by the introduction of contaminants might be applicable fur developing the leakage detection system for petroleum hydrocarbons of underground storage tanks and leachate coming from landfill. Investigations were conducted with diesel, NaCl solution, and leachate by laboratory tests. Simulation test was performed leaking at a certain point in the field. The measured resistance was exponentially decreased as the water content of uncontaminated unsaturated sand was increased. The resistance of soil was increased by diesel but decreased by NaCl solution or leachate. The optimum electrode spacings were found for NaCl solution, leachate and diesel. Electrolytic solutions were better detected by wider spacing than non electrolytic solution.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.3
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• pp.55-60
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• 1987

Impacts on ground water quality, growth of crops, and degree of corrosion due to the leachate produced from the contact of rain water with blast furnace slag as an aggragate used for roadway pavement were evaluated. Results from slag and soil leaching tests indicated pH, $SO_4$, $Ca^{{+}{+}}$ and $Mg^{{+}{+}}$ concentrations of ground water could be increased due to the use of slag, and pot test suggested slag would not adversely affect growth of Raphanus Satius L niger. Accelerated corrosion test revealed that slag leachate had a tendency to increase corrosion on cast iron at the beginning, however the degree of corrosion became similar to that experienced in soil after about 50 days at 50 degrees in centigrade.

• Journal of the Korean Geosynthetics Society
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• v.12 no.4
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• pp.67-76
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• 2013

Landfill require special care due to the dangers of nearby surface water and underground water pollution caused by leakage of leachate. The leachate does not leak due to the installation of the geomembrane but sharp wastes or landfill equipment can damage the geomembrane and therefore a means of protecting the geomembrane is required. In Korea, in accordance with the waste control act being modified in 1999, protecting the geosynthetics liner on top of the slope of landfill and installing a drainage layer to fluently drain leachate became mandatory, and technologies are being researched to both protect the geomembrane and quickly drain leachate simultaneously. Therefore, this research has its purpose in studying the drainage functions of leachate and protection functions of the geomembrane in order to examine the application possibilities of Geo-Multicell-Composite (GMC) as a Leachate Collection Removal and Protection System (LCRPs) at the slope on top of the geomembrane of landfill by observing methods of inserting filler with high-quality water permeability at the drainage net. GMC's horizontal permeability coefficient is $8.0{\times}10^{-4}m^2/s$ to legal standards satisfeid. Also crash gravel used as filler respected by vertical permeability is 5.0 cm/s, embroidering puncture strength 140.2 kgf. A result of storm drain using artificial rain in GMC model facility, maxinum flow rate of 1,120 L/hr even spray without surface runoff was about 92~97% penetration. Further study, instead of crash gravel used as a filler, such as using recycled aggregate utilization increases and the resulting construction cost is expected to savings.