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Evaluation of Exposure Indicators for Plants by Silicon Tetrachloride Release (사염화규소 누출사고지점 주변 식물에 대한 노출지표 평가)

  • Park, Jae-Seon;Kim, Jee-Young;Kim, Myeong-Ock;Park, Hyun-Woo;Chung, Hyen-Mi;Choi, Jong-Woo
    • Korean Journal of Environmental Agriculture
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    • v.36 no.4
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    • pp.288-292
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    • 2017
  • BACKGROUND: Silicon tetrachloride reacts with moisture in the atmosphere to generate hydrogen chloride, which affects the environment. Since silicon tetrachloride and its by-products are dispersed in the atmosphere in a short time after the silicon tetrachloride release into the atmosphere, it is difficult to directly assess the extent of environmental impact. In the present study, the exposure test of silicon tetrachloride or hydrogen chloride was examined in order to establish the criterion of the range affected by the silicon tetrachloride release, and the actual crops in the area exposed to silicon tetrachloride leakage were analyzed. METHODS AND RESULTS: For the experiment of exposure to silicon tetrachloride or hydrogen chloride, the leaves of red-pepper and corn were used in glass sealed containers. In the actual accident area, 59 samples from 10 different kinds of crops were collected. The pretreatment of the sample was performed by freezing and grinding, and then extracted using distilled water. The pH and concentration of chloride ($Cl^-$) ion of the extracted solution were measured using pH meter and ion chromatograph, respectively. CONCLUSION: Exposure to silicon tetrachloride caused visible damage, increasing the concentration of chloride ion, and decreasing the pH as well as hydrochloric acid. In the actual crops of the affected area, the tendency was the same as the result of the laboratory test, and the range of influence could be estimated through the concentration of $Cl^-$ ion over 2,000 mg/kg, and the correlation evaluation between the concentration of $Cl^-$ and pH. Therefore, the concentration of $Cl^-$ ion and the correlation between $Cl^-$ and pH would be considered as the factors to estimate the influence range of silicon tetrachloride release.

The Effect of Dual-Task on Standing Postural Control in Persons With Chronic Stroke (만성 뇌졸중 환자의 기립 자세조절에 이중 과제가 미치는 영향)

  • Jeon, Hye-Won;Chung, Yi-Jung
    • Physical Therapy Korea
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    • v.17 no.3
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    • pp.20-30
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    • 2010
  • This study examined whether any changes by mental task types on postural control in chronic stroke persons. Sixteen chronic stroke persons (mean age=53.75 yr) and sixteen age-and gender-matched healthy controls (mean age=54.44 yr) took part in this study. Participants randomly performed three different tasks on the stable and unstable surfaces. The no mental task was to stand while holding a 100 g weight in each hand, the arithmetic task (mental task) was to perform a silent 1-backwards counting while standing and holding a 100 g weight in each hand, and the simple task (mental task) was to stand and hold with both hands a tray (200 g) on which a glass filled with water has been placed. Sway path and sway velocity of the center of pressure (COP) were measured to assess standing postural control by task performance using the force platform. According to the results, in stroke group, total sway path and total sway velocity of COP was significantly decreased during arithmetic and simple task compared to no mental task on the stable surface (p<.05), and sway path (anteroposterior AP, mediolateral ML) of COP, total and sway velocity (AP, ML, total) of COP was significantly decreased during arithmetic and simple task compared to no mental task on the unstable surface (p<.05). Especially, sway path (AP, total) of COP and sway velocity (AP, ML, total) of COP was significantly decreased under the simple task when compared to the arithmetic task on the unstable surface (p<.05). In healthy control group, sway path (AP, ML, total) of COP and sway velocity (AP, ML, total) of COP was significantly decreased during arithmetic and simple task compared to no mental task on the stable and unstable surface (p<.05), and sway path (AP, total) of COP and sway velocity (AP, ML, total) of COP was significantly decreased under the simple task when compared to the arithmetic task on the unstable surface (p<.05). In conclusion, the findings of this study showed that arithmetic and simple task improved standing postural control for chronic stroke patients and the type of arithmetic and simple tasks were critical factor that reduced standing postural sway in dual-task conditions. Future research should determine whether dual-task conditions, including simple task, would be effective as a training program for standing postural control of stroke patients.

Studies on Genetic Toxicity of Epoxidized Soy Bean Oil (에폭시화 대두유의 유전독성 연구)

  • 한의식;정해관;김종원;박미선;엄미옥;강혁준;민수진;오혜영
    • Journal of Food Hygiene and Safety
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    • v.16 no.2
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    • pp.145-151
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    • 2001
  • EpoxidiBed soy bean oil (ESBO) is a plasticizer of PVC which is being widely used as a gaskets for the lid of glass jars including baby food. Using reverse mutation assay, chromosome aberration test and micronucleus test, ESBO were evaluated the mutagenicity. In the reverse mutation test, ESBO did not induced mutagenicity in Salmonella typhimurium TA98, TA100, TA1535, TA1537, TA102 with and without metabolic activation. In the chromosome aberration test using CHL cells, the results showed no increased structural and numerical aberrations in the concentration of sample producing cytotoxicity with and without metabolic activation. The in vivo induction of micronuclei was measured in polychromatic erythrocytes of bone marrow of young (3weeks old) and adult (6 weeks old) ddY mice of both sex. At 24 hours after treatment with ESBO 20, 10, 5, 2.5 g/B.W. kg/corn oil 10 ml by oral route animals were sacrificed and bone marrow cells were prepared for smear slides. The results showed no increased micronucleated polychromatic erythrocytes regardless of sex and age. It was concluded that water soluble ESBO did not show certain genotoxicity within our studies conducted.

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Eggs Development ana Larvae of the Horn Fish, Hemiramphus sajori TEMMINCK et SCHLEGEL (학공치의 난발생과 부화자어)

  • KIM Yong-Uk;MYOUNG Jung-Goo;CHOI Sang-Oong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.2
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    • pp.125-131
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    • 1984
  • The horn fish, Hemiramphus sajori TEMMINCK et SCHLEGEL, is widely distributed in the coastal waters of Korea, Japan and Taiwan. On April 13, 1983, mature adults of the horn fish were collected from Changson channel, Namhae. The authors carried out artificial insemination on the field, and incubated the eggs and reared larvae in the laboratory. And these larvae were reared for about two weeks in glass jars, fed brine shrimp nauplii. The eggs of this species are demersal and adhesive, with 4 to 6 filaments at the animal pole and a filament at the vegetal pole. The diameter of these eggs varies 1.80 to 2.00 mm. The hatching took place in ca. 376 hours after fertilization. During the incubation period water temperature fluctuated between $13.5^{\circ}C\;and\;20.0^{\circ}C$. The newly hatched larvae were elongate in shape $7.40{\sim}8.00$ mm in total length with $40+16{\sim}17=56{\sim}57$ myomers. Many melanophore were distributed on the head, both sides of dorsal body contour, peritoneum and ventral line of the tail part. Four days after hatching, the larvae were from 9.00 to 9.65 mm in total length, at this tims the larvae absorbed the yolk completely, and became postlarvae. Fourteen days after hatching, the larvae attained 13.25 mm in total length, with 14 rays of the dorsal fin, 13 rays of the anal fin, and 4 rays of pectoral fin. The lower jaw has somewhat projected.

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Phototaxis of Fish (2) - Response of Rook bream and Grass puffer to the white lights - (어류의 주광성에 관한 연구 (2) - 백색광에 대한 돌돔과 복섬의 반응 -)

  • 양용림
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.16 no.1
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    • pp.27-35
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    • 1980
  • The purpose of the present study is to find the light intensity which induces maximum gathering rate and to observe the variation of the gathering rate both in' daytime and at night by using two species of commercial fishes: rock bream, Oplegnathus fasciatus(Temminet et Schlegel) and glass-puffer,\ulcorner Fugu.niphobles (Jordan \ulcorneret. Snyder). An experimental tank($360L{\times}50W{\times}55H cm$) was set up in a dark room. An illumination system was attached to one end of the tank to control horizontal light intensity. Six artificial light sources were prepared by combination of two light bulbs (5W, 150W) and seven filters. During the. experiment water depth was maintained 50 em level in the tank. The tank was marked into six longitudinal sections each, being 60 cm long to observe the distribution of fish. The fish were acclimatized in dark condition for 40 minutes prior to the main experiment. Upon turning on the light, the number of fish in each section was counted40 times every 30 seconds, and the gathering rates were obtain from th~ average number of. fish' in each section. The light intensity inducing maximum gathering rate is as follows: rock bream: 162.0 lux (104,3--238, 1 lux) (day), 162.0 lux (104.3--238.1 lux) (night). grass puffer: 16.6 lux (10.6--24.5 lux) (day), 1. 9 lux (1. 2-2. 9 lUX) (night). Trend .of the gathering rate in illumination time revealed different results in two fish species. Gathering rate of rock bream showed the increasing trend fluctuately with the lapse of ' illumination time. However, that of grass puffer showed the increasing trend gradually at the early period of the illumination time and the uniform trend at the latter period with little distictive fluctuation.

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Forced Flow Dryout Heat Flux in Heat Generating Debris Bed (열을 발생하는 Debris층에서의 강제대류 Dryout 열유속)

  • Cha, Jong-Hee;Chung, Moon-Ki
    • Nuclear Engineering and Technology
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    • v.18 no.4
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    • pp.273-280
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    • 1986
  • The purpose of this study is to obtain the experimental data of the forced flow dryout heat flux in a heat generating debris bed which simulates the degraded nuclear reactor core after severe accident. An experimental investigation has been conducted of dryout heat flux in an inductively heated bed of steel particles with upward forced flow rising coolant circulation system under atmospheric pressure. The present observations were mainly focused on the effects of coolant mass flux, particle size, bed height, and coolant subcooling on the dryout heat flux The data were obtained when carbon steel particles in the size distribution 1.5, 2.5, 3.0 and 4.0 mm were placed in a 55 mm ID Pyrex glass column and inductively heated by passing radio frequency current through a multiturn work coil encircling the column. Distilled water was supplied with variation of mass flux from 0 to 3.5 kg/$\textrm{cm}^2$ s as a coolant in the tests, while the bed height was selected as 55 mm and 110 mm. Inlet temperature of coolant varied by 2$0^{\circ}C$ and 8$0^{\circ}C$. The principal results of the tests are: (1) Dryout heat flux increases with increase of upward forcing mass flux and particle size; (2) The dryout heat flux at the zero mass flux obviously depends on the Particle size as Previous studies; (3) The forced flow dryout heat flux in the shallow bed is somewhat higher than that in the deep bed,

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Air Sampling and Isotope Analyses of Water Vapor and CO2 using Multi-Level Profile System (다중연직농도시스템(Multi-Level Profile System)을 이용한 수증기와 이산화탄소 시료채취 및 안정동위원소 조성 분석)

  • Lee, Dong-Ho;Kim, Su-Jin;Cheon, Jung-Hwa;Kim, Joon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.12 no.4
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    • pp.277-288
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    • 2010
  • The multi-level $H_2O/CO_2$ profile system has been widely used to quantify the storage and advection effects on energy and mass fluxes measured by eddy covariance systems. In this study, we expanded the utility of the profile system by accommodating air sampling devices for isotope analyses of water vapor and $CO_2$. A pre-evacuated 2L glass flask was connected to the discharge of an Infrared Gas Analyzer (IRGA) of the profile system so that airs with known concentration of $H_2O$ and $CO_2$ can be sampled. To test the performance of this sampling system, we sampled airs from 8 levels (from 0.1 to 40 m) at the KoFlux tower of Gwangneung deciduous forest, Korea. Air samples in the 2L flask were separated into its component gases and pure $H_2O$ and $CO_2$ were extracted by using a vacuum extraction line. This novel technique successfully produced vertical profiles of ${\delta}D$ of $H_2O$ and ${\delta}^{13}C$ of $CO_2$ in a mature forest, and estimated ${\delta}D$ of evapotranspiration (${\delta}D_{ET}$) and ${\delta}^{13}C$ of $CO_2$ from ecosystem respiration (${\delta}^{13}C_{resp}$) by using Keeling plots. While technical improvement is still required in various aspects, our sampling system has two major advantages over other proposed techniques. First, it is cost effective since our system uses the existing structure of the profile system. Second, both $CO_2$ and $H_2O$ can be sampled simultaneously so that net ecosystem exchange of $H_2O$ and $CO_2$ can be partitioned at the same temporal resolution, which will improve our understanding of the coupling between water and carbon cycles in terrestrial ecosystems.

Ideal Leaf Type on Leaf Shape and $\textrm{CO}_2$ Use Efficiency of Different Seed Size Cultivar in Soybean (엽형 및 $\textrm{CO}_2$ 이용효율에 따른 콩 입중별 이상초형 연구)

  • 이강세;전병무;김영진;국용인;박호기;박문수
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.3
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    • pp.243-247
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    • 2003
  • To examine ideal leaf types with higher $\textrm{CO}_2$ assimilates and different seed sizes, 12 soybean varieties were planted on the pot in a plastic house covered with glass. Leaf function based on stomatal conductance and $\textrm{CO}_2$ assimilation in soybean is different in seed size and leaflet shape. Mean $\textrm{CO}_2$ assimilation of a single leaf was 19.66 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$ and showed higher in small seed cultivars with narrow leaflet than that of small seeds with wide leaflet (18.29 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$), but within large seed groups, it was higher in wide leaflets (19.17 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$) than narrow leaflet cultivars (17.45 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$). In small seed and narrow leaflet cultivars, stomatal conductance ranged from 0.14 to 0.15 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$, while $\textrm{CO}_2$ assimilation ranged from 19 to 20 $\mu\textrm{molm}^{-2}\textrm{s}^{-1}$. The Photosynthetic rate was closely related to stomatal conductance, transpiration and water use efficiency.

Preparation of Copoly(styrene/butyl methacrylate) Beads and Composite Particles containing Carbon Black with Hydrophobic Silica as a Stabilizer in Aqueous Solution (수용액에서의 소수성실리카를 이용한 스티렌/부틸메타크릴레이트 입자 및 카본블랙을 함유한 복합체 입자의 합성)

  • Chung, Kyung-Ho;Park, Moon-Soo
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.43-53
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    • 2012
  • A suspension copolymerization of styrene and butyl methacrylate (BMA) in the aqueous phase was conducted at a selected temperature between 65 and $95^{\circ}C$. Hydrophobic silica was selected as a stabilizer and azobisisobutyronitrile (AIBN) as an initiator. Optimum dispersion of silica in water was obtained at pH 10 while polymerization reaction was run at pH 7. TGA and EDS measurements revealed that 90% of silica functioned as a stabilizer and 10% were incorporated into polymeric particles. Average particle diameter decreased with increasing amounts of stabilizer. Molecular weights displayed an increase when the stabilizer concentration reached 1.67 wt%. An increase in the initiator concentration and/or reaction temperature raised the reaction rate but decreased molecular weights. Particle diameter was nearly independent of the initiator concentration and reaction temperature. An increase in the BMA proportion decreased the glass transition temperature and increased the particle diameter with irregularity in shape. Incorporation of carbon black into the particles composed of styrene and BMA prolonged the reaction time before reaching completion. We have confirmed that a suspension copolymerization of styrene and BMA with hydrophobic silica as a stabilizer can produce spherical composite particles with $1-30{\mu}m$ in diameter containing carbon black.

Residual Patterns of Strobilurin Fungicides in Korean Melon under Plastic Film House Condition (Strobilurin계 살균제의 시설재배 참외 중 잔류 양상)

  • Park, Eun-Jeong;Lee, Ju-Hee;Kim, Tae-Hwa;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.28 no.3
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    • pp.281-288
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    • 2009
  • The strobilurin fungicides, azoxystrobin and kresoxim-methyl, were investigated to know the biological half-lives and dissipation patterns in Korean melon under plastic film house condition. Used pesticides for field application were 20% azoxystrobin of suspension concentrate and 47% kresoxim-methyl of water dispersible granule. Two pesticides were sprayed at recommended and double dose rate. Pesticide residues in Korean melon were analyzed until 14 days after application. The azoxystrobin was analyzed by HPLC equipped with UV detector after cleanup with florisil glass column. Initial residue concentrations of azoxystrobin in Korean melon at recommended and double dose rate were 0.09 mg/kg and 0.14 mg/kg, respectively. Those were less than 0.2 mg/kg maximum residue limit of Korean melon established by KFDA. The biological half-lives of azoxystrobin in Korean melon were 4.7 days at recommended dose rate and 7.8 days at double dose rate. Initial concentrations of kresoxim-methyl which was analyzed by GLC-ECD in Korean melon at recommended and double dose rate were 0.10 mg/kg and 0.23 mg/kg, respectively. Those were less than 1.0 mg/kg, MRL. The biological half-lives of kresoxim-methyl in Korean melon were 4.1 days at recommended dose rate and 4.8 days at double dose rate. The residue amounts of both pesticide was lower than MRL and biological half-lives were not so long. Because the weight of Korean melon under plastic film house condition was fast increased during cultivation.