• Title/Summary/Keyword: water corrosion

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Fabrication and Characterization of Environmental Barrier Coatings by Spray Drying and Atmospheric Plasma Spraying for Protection of Silicon Carbide Ceramics (분무건조 및 대기 플라즈마 용사에 의한 탄화규소 세라믹스용 내환경 코팅재의 제조 및 평가)

  • Feng, Fan Jie;Moon, Heung Soo;Kwak, Chan Won;Park, Ji Yeon;Lee, Kee Sung
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.481-486
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    • 2014
  • Environmental barrier coatings (EBCs) are used to protect SiC-based ceramics or composites from oxidation and corrosion due to reaction with oxygen and water vapour at high temperatures above $1000^{\circ}C$. Mullite ceramics have been studied for environmental barrier coatings for Si-based ceramics. More recently, rare earth silicate ceramics have been identified as more water vapour-resistant materials than mullite for environmental barrier coatings. In this study, we fabricate mullite and yttrium silicate ceramics by an atmospheric plasma spray coating method using spherical granules fabricated by spray drying. As a result, EBCs with thicknesses in the range of $200-300{\mu}m$ are successfully fabricated without any macroscopic cracks or interfacial delamination. Phase and microstructure analysis are conducted, and the basic mechanical properties, such as hardness and indentation load-displacement curves are evaluated.

Influence of Safety Valve Pressure on Gelled Electrolyte Valve-Regulated Lead/Acid Batteries Under Deep Cycling Applications

  • Oh, Sang-Hyub;Kim, Myung-Soo;Lee, Jin-Bok;Lee, Heung-Lark;, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.75-80
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    • 2002
  • Cycle life tests have been carried out to evaluate the influence of safety valve pressure on valve regulated lead/acid batteries under deep cycling applications. Batteries were cycled at 5 hour rates at 100% DOD, and safety valve pressure was set to 1.08 and 2.00 bar, respectively. The batteries lost 248.3 g and 235.3 g of water for each case after about 1,200 cycles, but the cyclic performances of the batteries were comparable. Most of the gas of the battery during discharging was hydrogen, and the oxygen concentration increased to 18% after 3 hours of charging. The micro structure of the positive active materials was completely changed and the corrosion layer of the positive grid was less than $50{\mu}m$, regardless of the pressure of the safety valve after cycle life tests. The cause of discharge capacity decrease was found to be water loss and the shedding of the positive active materials. The pressure of safety valve does not give little effect to the cyclic performances and the failure modes of the gelled electrolyte valve-regulated lead acid batteries.

Fabrication and Characteristics of Parylene Coated Isolated Type Pressure Sensor (파릴렌 막이 증착된 봉입형 압력센서의 제작 및 그 특성)

  • 김우정;조용수;김홍균;최시영
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.40 no.2
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    • pp.81-86
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    • 2003
  • To measure the pressure using semiconductor type pressure sensor in water or chemical solution, the sensor must be protected from the solution using proper packaging materials. stainless steel isolated type pressure sensor packaged with SUS316 can be widely used to measure the pressure in water or chemical due to its high corrosion-resistance and good performance in tensility and welding. Even if the surface of SUS316 has a plenty of nickel and chromium, the SUS316 is highly corrosive in acidic or alkaline solution. We coated parylene and adhesion promoting copper layer are 5${\mu}{\textrm}{m}$ and 200nm, respectively. The parylene coated stainless steel pressure sensor showed good anti-corosive characteristics in various strong acids. The accuracy of pressure sensor wasn't varied after parylene coating with 0.5%FSO.

A Study on the Behavior of Non-Metallic Anchoring System for FRP Tendons (고성능 팽창재를 이용한 FRP 긴장재의 정착에 관한 연구)

  • 김덕현;조병완;이계삼;김영진
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.23-28
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    • 2001
  • Since non-corrosive Fiber Reinforced Polymer(FRP) tendons have been in increasing use for underground and coastal structures constantly contacted with fresh water or sea water because of their superiority to metallic ones in corrosion-resistance, new non-metallic anchoring system for FRP tendons has been developed and investigated to verify the effectiveness of tendon force, which consist of mainly FRP pipes and Highly Expansive Mortar(HEM). The major factors considered in this experiment were expansive pressures of HEM during its hydration, sleeve lengths and types, and anchoring methods of tendon. New anchoring system were investigated from the pull-out tests. The pull-out procedures of the FRP tendons in the various pipe filled with HEM were analyzed and improved ideas were suggested to develop novel non-metallic anchoring system for FRP tendons The pull-out tests for the FRP tendon and new non-metallic anchoring system were conducted. The results show that non-metallic anchoring system for the FRP tendon has been more stablized due to the gradual expansive pressrure of HEM, as tims goes. Since tile lower stiffness of FRP pipes causes the weakness of anchoring force, it requires the increase of stiffness using a carbon fiber or an increased section area.

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Prediction of Long-Term behavior of polyethylene pipe buried underground (지중매설 폴리에틸렌 관의 장기거동 예측)

  • Lee, Jae-Ho;Kim, Bin;Yoon, Soo-Hyun;Kim, Eung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.1
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    • pp.7-12
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    • 2017
  • Most of existing buried pipes are composed of reinforced concrete. Reinforced concrete pipes have many problems such as aging, corrosion, leaking, etc. The polyethylene (PE) pipes have advantages to solve these problems. The plastic pipes buried underground are classified into a flexible pipe. National standard that has limited the long-term vertical deformation of the pipe to 5% for flexible pipes including PE pipe. This study presents a prediction for the long-term behavior of the polyethylene pipe based on ASTM D 5365. This prediction method is presented to estimate by using the statistical method from the initial deflection measurement data. We predict the behavior of long-term performance on the double-wall pipe and multi-wall pipe. As a result, it was found that the PE pipe will be sound enough more than 50 years if the compaction of soil around the pipe is more than 95% of the standard soil compaction density.

Strength Estimation of Ready-Mixed Concrete Using Crushed Sand (부순모래를 사용한 레디믹스트 콘크리트의 배합설계 및 강도추정방법)

  • Suh, Jin-Kook
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.1
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    • pp.45-52
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    • 1999
  • It is difficult to keep the balance of supply and demand for natural aggregates in recent years, because natural resources have become to be almost exhausted. Crushed stone is already used for coarse aggregate instead of river gravel at present. Now, crushed sand or sea sand should be used for fine aggregate, because natural sand also has been exhausted with a few exceptions around Nakdong River. The sea sand has a lot of problems which are the corrosion of reinforcement bars, the investment of facility for cleansing salt and the cost increase due to the insufficiency of industrial water. Therefore, it is necessary to produce and to utilize the crushed sand very actively, but some material properties which are related to water absorption, strength and chemical durability, prevent from determining the generalized criteria because its rocks make much differences in its physical and chemical characteristics. In this paper, fundamental physical properties of crushed sand, which comes from Daegu Subway construction fields, have been investigated for the usability on basic material of concrete. The optimum replacement ratio and the strength estimation method of crushed sand replacing natural sand also have been presented here through the compressive strength test of ready-mixed concrete cylinders.

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PWSCC and System Engineering Development of Internal Inspection and Maintenance Methodology for RCS

  • Abdallah, Khaled Atya Ahmed;Mesquita, Patricia Alves Franca de;Yusoff, Norashila;Nam, GungIhn;Jung, JaeCheon;Lee, YoungKwan
    • Journal of the Korean Society of Systems Engineering
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    • v.12 no.1
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    • pp.89-103
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    • 2016
  • Due to safety of the plant, it became very clear the importance of study occurrence reactor coolant system (RCS) issues specially the primary water stress corrosion cracking (PWSCC). The Systems Engineering (SE) approach is characterized by the application of a structured engineering methodology for the design of a complex system or component. Robotic devices have been used for internal inspection, maintenance and performing remote welding and inspection in high-radiation areas. In this paper, PWSCC overview and inlay and over lay welding methodology introduced, concept of robotic device that can be inserted into the piping via Steam Generator (SG) main way to access to primary piping of pressurized water reactor (PWR) is developed based on SE methodology. A 3D model of the inspection system was developed along with the APR1400 (Advanced Power Reactor)reactor coolant systems (RCS) and internals with virtual 3D simulation of the operation for visualization to prove the validity of the concept.

Vibration Analysis for Failure Diagnosis of Cylinder Liner of Large Ship Engine (선박엔진의 실린더 라이너의 손상 진단을 위한 진동 분석법)

  • Koo, Hyunho;Cho, Yonsang;Park, Junhong;Park, Heungsik
    • Tribology and Lubricants
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    • v.30 no.1
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    • pp.21-28
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    • 2014
  • Damage to the cylinder liner of large ship engines, such as scuffing on the surface, can occur very easily because it is operated in a corrosive environment. This scuffing may be due to oil film destruction and corrosive wear caused by water and sulfur included in the fuel, abrasive impurities, and poor lubricants. Thus, a method for monitoring the condition and diagnosing the failure of the cylinder liner and piston ring is needed. In this study, a reciprocating friction and wear test was carried out with a cast iron specimen, which simulated an engine cylinder in a corrosive atmosphere. The lubricants used were base oil, stirred oil with distilled water, a NaCl solution, and dilute sulfuric acid. The friction coefficient and frequency spectrum were measured using a load cell and acceleration sense in each experimental condition. We then used these results to diagnose the failure of the cylinder liner.

Development of Low Permeable Concrete for the Control of Deterioration in Underground Structures (지하구조물의 열화방지를 위한 수밀성 콘크리트의 개발)

  • Paik, S.H.;Park, S.S.;Park, J.Y.;Paik, W.J.;Um, T.S.;Choi, L.
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.191-196
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    • 1999
  • In underground reinforced concrete structures, such as drainage structure, water and chloride ion penetrated into concrete through the cracks of concrete and its permeable property, cause the corrosion of reinforcing steel bar, which accelerates the expansive cracks and deterioration of concrete. It is necessary to control those deterioration of underground structure by improving its permeability and durability through the reasonable solutions in design, construction and materials. In the present study, fly ash concrete, which has good material properties in long-term period, is compared and studied with plain concrete using ordinary portland cement in terms of fundamental mechanical properties, permeability, drying shrinkage and durability. Also, the mix design and its properties of low permeable concrete using fly ash are reviewed. From this study, fly ash concrete can conctrol the penetration of water and chloride ion effectively by forming dense microstructure of concrete. Therefore, fly ash concrete may increase the long-term function, performance and serviceability of underground structures.

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A Study on the Temperature Uniformity for the Anti-Corrosion Coating Process of Large-Sized Water Pipes (대형배관 내부식 코팅공정의 온도 균일성 향상을 위한 와류날개 형상 연구)

  • Park, Jaehyun;Park, Heesung;Kim, Sootae;Kang, Gyuongmoo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.15 no.6
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    • pp.35-40
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    • 2016
  • In this study, the thermal and fluid dynamic characteristics for the coating process of large-sized water pipes was studied by heating the inside of a pipe directly with a gas burner. Heat and flow analyses were performed on large pipes with various inlet shapes. Using large pipes for coating was shown to be the proper shape for heating large pipes uniformly. This type has a screw with a diameter of 200 mm installed at the inlet to provide a rotational motion to the heating air. The rotational motion resulted in a uniform temperature distribution that ranged from $289.1^{\circ}C$ to $352.1^{\circ}C$ The optimized geometric configuration of the inlet of the pipe successfully and uniformly enhanced the thermal characteristics of the devised temperature limit.