• Title/Summary/Keyword: volatile materials

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Characteristics of Volatile Organic Compounds Emitted from Wood-based Panels (목질제품에서 방출되는 휘발성 유기화합물 특성 연구)

  • Park, Hyun-Ju;Son, Youn-Suk;Lim, Bo-A;Kim, Jo-Chun;Park, Sang-Bum
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.6
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    • pp.616-623
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    • 2010
  • Recently, interests in indoor air quality (IAQ) have been increased; however, a number of researchers have mainly focused on anthropogenic volatile organic compounds (AVOC) emitted from building materials. Therefore, the properties of natural VOC (NVOC) and anthropogenic VOC (AVOC) emitted from wood-based panels was investigated in this work. VOCs emitted from these panels were sampled through Tenax TA/Cabotrap and analyzed by GC-MS and GC-FID. Comparisons were made concerning TVOC, NVOC, and composition ratios of NVOC. It was revealed that TVOC emission rates of midium density fiber (MDF) were the highest. Besides, it was found that emissions of NVOC from wood-based panels were much higher than those of anthropogenic AVOC except for plywood of Oceania timber. It was also observed that the composition ratio of NVOC emitted from plywood of Pinus radiata was the highest as 65% of TVOC. Major NVOC components were monoterpene compounds such as $\alpha$-pinene, $\beta$-pinene, d-limonene, camphene and $\alpha$-terpinene. It was concluded that the composition rates of VOCs emitted from building materials were clearly different according to the raw materials and manufacturing methods.

Preparation and Characterizations of Wood Plastic Composite Panel Fabricated with Chamaecyparis obtusa Wood Flour (편백나무 목분을 첨가한 합성목재 패널의 제조 및 특성 평가)

  • Kim, Soo-Jong
    • Journal of Convergence for Information Technology
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    • v.12 no.5
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    • pp.126-132
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    • 2022
  • Wood Plastic Composite(WPC) has been mostly used for outdoor purposes such as deck materials and trails so far. In this study, WPC panels with improved antibacterial properties, total volatile organic compound emissions (TVOC), and flame retardant were manufactured to use Wood Plastic Compound as interior materials for indoor use. WPC compound was prepared by mixing Chamaecyparis obtusa wood flour with high density polyethylene(HDPE). The prepared WPC compound exhibited excellent antibacterial and antifungal properties, and the total volatile organic compound emission(TVOC) was 0.062 mg/m2·h. The WPC panel(303mm×606mm×10mm) manufactured by a twin screw extruder with the manufactured compound achieved the flame retardant grade 2 standard of KS F 2271.

Ferroelectric Properties of Chiral Compound $SrBi_2Ta_2O_9$ Thin Films for Non-Volatile Memories (비 휘발성 기억소자 용 $SrBi_2Ta_2O_9$ 박막의 강유전체 특성)

  • Lee, Nam-Hee;Lee, Eun-Gu;Lee, Jong-Kook;Jang, Woo-Yang
    • Korean Journal of Crystallography
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    • v.11 no.2
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    • pp.95-101
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    • 2000
  • Ferroelectric SrBi2Ta2O9 (SBT) thin films of Pt/Ti/SiO2 electrode were fabricated using a sintered SBT target with various Bi2O3 content by rf magnetron sputtering. Good hysteresis loop characteristics were observed in the SBT thin films deposited with 50mol% excess Bi target. SBT thin films crystallized from 650℃ however, good hysteresis loop can be obtained in the film annealed above 700℃. pt/TiO2/SiO2 and Pt/SiO2 electrodes were also used to investigate the Pt electrode dependence of SBT thin films. SBT thin films showed random oriented polycrystalline structure and similar morphology regardless of electrodes with quite different surface morphology. A 0.2㎛ thick SBT film annealed at 750℃ exhibited the remanent polarization (2Pr) of μC/㎠ and coercive voltage(Vc) of 1V at an applied voltage of 5V.

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Deposition Pressure Dependent Electric Properties of (Hf,Zr)O2 Thin Films Made by RF Sputtering Deposition Method

  • Moon, S.E.;Kim, J.H.;Im, J.P.;Lee, J.;Im, S.Y.;Hong, S.H.;Kang, S.Y.;Yoon, S.M.
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1712-1715
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    • 2018
  • To study the applications for ferroelectric non-volatile memory and ferroelectric memristor, etc., deposition pressure dependent electric the properties of $(Hf,\;Zr)O_2$ thin films by RF sputtering deposition method were investigated. The bottom electrode was TiN thin film to produce stress effect on the formation of orthorhombic phase and top electrode was Pt thin film by DC sputtering deposition. Deposition pressure was varied along with the same other deposition conditions, for example, sputtering power, target to substrate distance, post-annealing temperature, annealing gas, annealing time, etc. The structural and electric properties of the above thin films were investigated. As a result, it is confirmed that the electric properties of the $(Hf,\;Zr)O_2$ thin films depend on the deposition pressure which affects structural properties of the thin films, such as, structural phase, ratio of the constituents, etc.

Response of Burley Tobacco (Nicotiana tabacum L.) to Application of Lime Materials (석회물질 시용이 Burley종 연초의 수량과 화학성분에 미치는 영향)

  • 이철환;김용옥;박수준
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.34 no.2
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    • pp.198-203
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    • 1989
  • Field experiment was conducted to find out the effect of lime materials application on yield, and chemical composition of Burley 21 in 1986. Lime materials and application rate were CaSO$_4$ : Ca 35kg/l0a. CaCO$_3$ : Ca 35kg/l0a and Liming: pH6.5. Contents of Ca and Mg in fresh or cured leaves were increased, but AI, Fe and Mn were decreased by applying lime materials. Yield were increased by applying lime materials. Among lime materials treatment, yield of limed and CaCO$_3$ plot were higher than that of CaSO$_4$ plot. Value per kg of cured leaves was not affected by applying lime materials. Cured leaves of CaSO$_4$ plot contained higher NH$_3$-nitrogen and alkalinity number of water insoluble ash than those of unlimed plot. Cured leaves of CaCO$_3$, plot contained higher alkalinity number of water soluble ash, insoluble ash and volatile neutral constituent, but lower protein-nitrogen and petroleum ether extracts than those of unlimed plot. Cured leaves of limed plot contained higher alkalinity number of water soluble and insoluble ash, NO$_3$-nitrogen and volatile neutral constituents, but lower protein -nitrogen, nicotine and petroleum ether extracts than those unlimed plot. Yield was increased, however leaf Quality in respect to chemical and organoleptic characteristics were not affected considerably by applying lime materials. Therefore, it suggests that controlling the soil pH about 6.5 by liming might be necessary for tobacco cultivation.

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Characteristics of Volatile Organic Compounds and Aldehydes Emission from Yellow poplar (Liriodendron tulipifera L.) (백합나무 판재의 VOCs 및 Aldehydes 방출특성)

  • Lee, Min;Park, Sang-Bum;Lee, Sang-Min;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.357-366
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    • 2014
  • Based on fundamental properties and machining characteristics of Yellow poplar (Liriodendron tulipifera L.), it has well performance on machinability or workability, drying, and fine surface. Additionally, yellow poplar is light weight and has bright color with high performance of bending processing, so it could be used for furniture or artworks materials and wood-based panel materials. Recently, public attention has been focused on indoor air quality, and Ministry of environment drift more tight regulation on indoor air quality for an apartment house and public facility with the times. Construction materials has been assessed emission of volatile organic compounds (VOCs) and formaldehyde according to law (No.10789), so yellow poplar is also needed to assess these emission characteristics. Emission of VOC and aldehyde compounds from dry and green wood condition of yellow poplar were investigated with KS M 1998:2009. Based on results, more than 30 compounds were detected from yellow poplar, and lower NVOC (natural VOC) were emitted than AVOC (Anthropogenic VOC) and OVOC (other VOC). Formaldehyde emission was lower than $5{\mu}g/m^3$ and acetaldehyde, ketone, and propionaldehyde were detected from yellow poplar. From dry yellow poplar, m-Tolualdehyde ($33.6{\mu}g/m^3$) was additionally detected while no detection of propionaldehyde. After drying process, amount of ketone emission increased significantly. The unique smell of yellow poplar may not only come from emission of acetaldehyde and propionaldehyde.

Performance Evaluation of a Portable GC for Real-time Monitoring of Volatile Organic Compounds (휘발성 유기화합물의 실시간 모니터링을 위한 휴대형 GC의 성능 평가)

  • You, Dong-Wook;Seon, Yeong-Sik;Oh, Jun-Sik;Yi, Bongyoon;Kim, Hyun Sik;Jung, Kwang-Woo
    • Journal of the Korean Chemical Society
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    • v.64 no.6
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    • pp.327-333
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    • 2020
  • Performance of a portable GC that can be utilized for the real time determination of volatile organic compounds in air was evaluated. It employs purified/compressed ambient air as the carrier gas eliminating the need for high pressure gas tanks. The compact system with dimensions of 35 × 26 × 15 ㎤ and weight of 5 kg is powered by either a 24 V DC external adapter or battery pack. Chromatograms of the mixture sample including benzene, toluene, ethylbenzene, and oxylene at concentrations of 1 ppmv and 20 ppmv represent a good reproducibility: 3.79% and 0.48% relative standard deviations (RSDs) for peak area variations; 0.40% and 0.08% RSDs for retention times. The method detection limit was 0.09 ppmv. A 30 m long, 0.28 mm I.D. column operated at an optimal condition yielded a peak capacity of 61 with good resolution for a 10 min isothermal analysis. The relative standard deviations (RSD) of the peak area variations and retention times during consecutive measurements over 27 h were less than 2.4%RSD and 0.5%RSD, respectively. Thus, this instrument makes it suitable for continuous and field analysis of low-concentration VOC mixtures in the indoor/outdoor environment as well as the spillage accident of hazardous chemicals.

A Study on the Indoor Air Pollutants Emission Characteristics by Composed Building Materials (건축자재 마감구성에 따른 실내공기오염물질 방출특성에 관한 연구)

  • Park, Jin-Chul;Rhee, Eon-Ku;Yu, Hyung-Ku
    • Proceedings of the SAREK Conference
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    • 2005.11a
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    • pp.3-8
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    • 2005
  • Building parts of Multi-Family Houses are consisted of several building material assembly. Therefore, after selecting building materials with test result of emission intensity and their feature, composed building materials are made equally with actual construction methods, and experimented emission intensity. 7 days after experiment, formaldehyde emission intensity appeared low in an order of Tile Wall, Wood Flooring, Wallpaper, Reum Flooring, Silk Wallpaper, and 20 days after experiment, TVOC emission intensity appeared low in an order of Tile Wall, Reum Flooring, Silk Wallpaper, Wood Flooring, Wallpaper. There was a clear difference in TVOC emission intensity according to kind of building materials. Composed building materials that weight per unit area is big and omission intensity is high, they effect continuously to indoor air because decrement is small.

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Manufacture of High Density Graphite Using Coal Tar Pitch (석탄계 피치를 이용한 고밀도 흑연 제조)

  • Cho, Kwang-Youn;Kim, Kyung-Ja;Riu, Doh-Hyung;Lim, Kwang-Hyun;Kim, Jung-Il;Shin, In-Cheol;Lim, Yun-Soo;Joo, Heyok-Jong
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.839-845
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    • 2006
  • Graphite has hexagonal closed packing structure with two bonding characteristics; (1) van der waals bonding between c axis, and (2) covalent bonding in the a and b axis. The weak van der waals bonds cause self-lubricant property, and the strong covalent bonds cause excellent electric and thermal conductivity. Furthermore, graphite is chemically very inert because of the material composed of only carbon elements. Thus, graphite is very useful for mechanical sealing materials. However, Graphite have porous microstructure because starting materials of graphite produce many volatile during the manufacturing processes. This causes low density of graphite, which is unsuitable for the mechanical sealing materials. Thus, further impregnation process is generally needed to enhance the graphite density. In this work, high density graphite is prepared with the principle of densification when coke and pitch binder, prepared from thermal treatment of coal tar pitch, become dehydrogenation during graphitization or carbonization.

The State of the Art and Architectural Environmental Property Evaluation of Earth Construction Material (주요 흙 건축재료 현황 및 건축환경 관련 물성 평가에 관한 연구)

  • Song, Seol-Young;Koo, Bo-Kyoung;Song, Seung-Yeong
    • Journal of the Korean Solar Energy Society
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    • v.26 no.4
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    • pp.83-91
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    • 2006
  • As a demand for sustainable development rises, the preference for earth house (earth construction) increases gradually. However, there are few data for predicting and evaluating the thermal environment and indoor air quality of earth house. Thus, this study aims to measure thermal properties(thermal conductivity, density and specific heat) and pollutants emission intensities(formaldehyde and volatile organic compounds) of current main earth construction materials and make a comparison between earth and cement construction materials. As results, quantitative thermal properties and pollutants emission intensities of current main earth construction materials are shown.