• Title/Summary/Keyword: vinyl

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Film Properties of Cold Blending Emulsion Between Poly(vinyl Acetate) and Poly(vinyl acetate-co-ethylene) Emulsion (Poly(vinyl acetate)와 Poly(vinyl acetate-co-ethylene) 에멀젼을 이용한 상온 블렌드 에멀젼의 Film 특성)

  • Kim, Ho-Young;Yoo, Sung-Hee;Choi, Yong-Hae
    • Journal of Adhesion and Interface
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    • v.12 no.4
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    • pp.117-124
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    • 2011
  • This study was made on the poly(vinyl acetate) (PVAc) and poly(vinyl acetate- ethylene) (VAE) emulsion polymer blend which used PVA as protective colloid, and the PVA used as protective colloid was existed in each emulsion film before blend and even in the film after the blend consecutively. It makes us expect excellent adhesive power among particles that form the blend. Emulsion blends with different Tg are important target of concerning, and PVAc/VAE emulsion blend suggested simple and excellent research method. As a result of blend, elongation was lowered by the increase of PVAc, and the plasticizer used in making PVAc affected on the Tg of blend and lowered Tg of VAE emulsion, and the synergy effect of two blends was seen for the tensile strength, thermal resistance, and adhesive strength.

Preparation of High Molecular Weight Atactic Poly(vinyl alcohol)/Dye Complex Film (고분자량 혼성배열 폴리비닐알코올/염료 복합체 필름의 제조)

  • Park, Joo-Min;Kim, Sam-Soo;Lyoo, Won-Seok
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.48-51
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    • 2003
  • Poly(vinyl alcohol) (PVA) obtained by the saponification of poly(vinyl ester) like poly(vinyl acetate) or poly(vinyl pivalate) is a linen. semicrystalline polymer, which have been widely used as fibers for clothes and industries, films, membranes, medicines for drug delivery system, and cancer cell-killing embolic materials[1-3]. PVA fibers and films have high tensile and compressive strengths, high tensile modulus, and good abrasion resistance due to its highest crystalline lattice modulus. (omitted)

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Interaction Analysis of Small Molecules with Polymers( I ) - Interaction between Poly(vinyl pyrrolidone) and Methylene Blue in Homogeneous Systems- (고분자와 저분자의 상호작용의 해석 ( I ) -균일수용액계에서의 Poly(vinyl pyrrolidone)과 Methylene Blue의 상호작용-)

  • 박수민;김문식;유정문
    • Textile Coloration and Finishing
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    • v.5 no.3
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    • pp.182-187
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    • 1993
  • The binding isotherms of Methylene Blue with Poly(vinyl pyrrolidone) (PVP) were determined in a Mcllvaine buffer of pH 8.0 at 3$0^{\circ}C$ by a dynamic dialysis methods. The isotherms showed a partition binding which was increase linearly with the increase of free dye concentration in solution. The Scatchard plots for Poly(vinyl pyrrolidone)-Methylene Blue gave a constant value. The results were interpreted by the McGhee and von Hippel theory considering non-cooperative binding. The intrinsic binding constant k, for Poly(vinyl pyrrolidone)-Methylene Blue was 6.02$\ell$/base mol.

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Studies on the Effect of Vinyl Mulching on Pleurotus Cultivation - Bunch Formation an Pleurotus sajor-caju(III) -

  • Oh, Se-Jong;Shin, Pyung-Gyun;Jang, Kab-Yeul;Kim, Hee-Kyu
    • Mycobiology
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    • v.31 no.1
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    • pp.54-56
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    • 2003
  • Perforated vinyl mulching technique was performed on Pleurotus sajor-caju beds to assess fruitbody formation. Individual fruitbody of P. sajor-caju was transformed into bunch type on vinyl mulching bed. It was effective to grow the mushroom without waterlogging and abortion of small pins on the beds as well as hygienical bed management. A bunch showed 79 fruitbodies and 225 g of weight. Available site for fruiting was reduced up to 20% in comparison of 100% for conventional bed. The color of fruitbody turned on brownish white from treated vinyl mulching bed.

Development of functional microsphere (I) - Formation and characteristics of poly(ethylene-co-vinyl acetate) microspheres via thermally induced phase separation - (기능성 마이크로스피어의 개발 (I) - 열유도 상분리에 의한 Poly(ethylene-co-vinyl acetate) 마이크로스피어의 제조와 특성 -)

  • 이신희;김효정;박수민
    • Textile Coloration and Finishing
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    • v.15 no.4
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    • pp.57-64
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    • 2003
  • Poly(ethylene-co-vinyl acetate)(EVA) microspheres were prepared by a thermally induced phase separation. The microsphere formation occurred by the nucleation and growth mechanism in the metastable region. The diluent used was toluene. The microsphere formation and growth was followed by the cloud point of the optical microscope measurement. The microsphere size distribution, which was obtained by SEM observation and particle size analyzer, became broader when the polymer concentration was higher, the content of vinyl acetate in EVA copolymer was higher, and the cooling rate of EVA copolymer solution was lower.

Formability of Non-Vinyl Pre-coated Metal Sheet (Non-Vinyl Pre-coated Metal재의 성형성에 관한 연구)

  • Kim, Dong-Hwan;Kim, Byung-Min
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.4
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    • pp.121-128
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    • 2001
  • This study has been performed to investigate formability of non-vinyl PCM(pre-coated metal)sheet. First, physical test of PCM sheets were tested to evaluate finish coating characteristic of PCM. And then, test equipment was made for friction test and three non-vinyl PCM sheets were tested by straight pulling method. This paper provides the results of the friction tests showing the influence of sheet surface texture and process conditions. It was found that the influence of contact pressure and speed had an effect upon the level of friction. Also using tests, the scratch resistance of a series of polyester coating has been investigated. This investigation aims to clarify the process conditions that prevent the scratch of PCM to form the good electrical appliances such as microwave oven, air conditioner and refrigerator etc.

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Photosensitive Effect of Poly(vinyl cinnamoyl acetate) by New Squarylium Dyes(I) (신규 Squarylium Dyes 증감제에 의한 Poly(vinyl cinnamoyl acetate)의 고감도화(I))

  • 손세모;박진화
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.1-13
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    • 1998
  • Some photopolymer, poly(vinyl cinnamoyl acetate)(PVCiA) was synthesized by esterification of polymer(vinyl alcohol(PVA) with monochloroacetic acid, followed by reaction poly(vinyl monochloroacetate)(PVChA) and potassium cinnamate. When esterification of PVA with monochloroacetic acid was reacted in the dimethyl sulfoxide(DMSO), in the synthesis of PVChA, it is very good yield and the successive cinnamoyl acetoxyl esterification of PVCiA can be successfully synthesized. But PVCiA is low photosensitive polymer if not added photosensitizing dyes. Here, we synthesized photosensitizing dyes. trifluoromethylindol squarylium dye derivatives(TFSQ). Indolization of 3-trifluoromethylphenyl-hydrazine formed 4- and 6-substituted indoles, the rate of 4- and 6-substituted indoles is close to unity. Absorption's coefficient of 1,3-bis(4-trifluoromethyl-1,3,3-trimethylindol) squarylium dye(TFSQ) is 7.57$\times$10\ulcorner, PVCiA added with TFSQ(3%) was highly sensitized six times than not added.

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Effect of Wire Bracing to Snow Load Acting on Vinyl House Frame (적설하중이 작용하는 비닐하우스 골조에 대한 강선보강효과)

  • Jung, Dong-Jo;Teng, Chhay
    • Journal of the Korean Institute of Rural Architecture
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    • v.12 no.3
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    • pp.27-34
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    • 2010
  • Unbraced vinyl house frame that is economically installed is certainly easy to collapse under the influence of excess snow load. To make it more cheaply in putting up as well as more efficiently in withstanding the applied snow load, it is essential to insert additional bracing into the existing unbraced vinyl house frame. On the other hand, there are varieties of possible bracing shapes that can be formed. However, their efficiencies are different. Therefore, it is important to identify the most effective bracing shape. In this study, 2 different kinds of bracing shapes, horizontal and inclined bracing, are used to additionally install in the ordinary single frames in order to show the effect of the bracing resisting the applied snow load and compare the bending moment, axial force, combined stress and vertical displacement of the vinyl house frame.

Effect of Wire Bracing to Wind Load Acting on Vinyl House Frame (비닐하우스 골조에 작용하는 풍하중에 대한 강선보강효과)

  • Jung, Dong-Jo;Teng, Chhay
    • Journal of the Korean Institute of Rural Architecture
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    • v.12 no.2
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    • pp.23-29
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    • 2010
  • Vinyl house is a simple agricultural structure that is installed economically and easily. In contrast, every year the farmers have spent a lot of money because of the collapse of this structure caused by the external forces such as strong wind and heavy snow. To prevent this damage due to frequent heavy snow and strong wind, it would be necessary to design it again. But getting rid of former vinyl house and reconstructing is unreasonable. It would be very economic if the former vinyl house is strengthened simply. This paper covers the investigation of the effect of the bracing systems that are additionally inserted inside the ordinary single frames as well as unbraced multiple frames that resisting only the strong wind load.