• Carbon letters
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• v.16 no.3
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• pp.219-221
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• 2015

In order to study the impact of atmosphere during electron beam irradiation (EBI) of polyacrylonitrile (PAN) precursor fibers, the latter were stabilized by EBI in both air and oxygen atmospheres. Gel-fraction determination indicated that EBI-stabilization under an oxygen atmosphere leads to an enhanced cyclization in the PAN fibers. In the Fourier-transform infrared spectroscopy analysis, the PAN fibers stabilized by EBI under an oxygen atmosphere exhibited a greater decrease in the peak intensity at 2244 cm⁻¹ (C≡N vibration) and a greater increase in the peak intensity at 1628 cm⁻¹ (C=N absorption) than the corresponding PAN fibers stabilized under an air atmosphere. From the X-ray diffraction analysis it was found that oxygen uptake in PAN fibers leads to an increase in the amorphous region, produced by cyclization.

• Journal of Magnetics
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• v.17 no.1
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• pp.6-8
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• 2012

M$\ddot{o}$ssbauer spectra of hexagonal $BaFe_{12}O_{19}$ single crystals were studied at various temperatures (4-300 K). It was found that the spin states in Fe atoms were parallel to the ${\gamma}$-ray's direction into a single crystal along the caxis. The location of the Fe ion in the 2b site is unusual in an oxide structure and has strong anisotropic lattice vibrations. Moreover, at room temperature, the zero absorption lines of the Fe ions at the 2b site were observed due to fast diffusion motion in a double well atomic potential. The two Fe ions of the single crystal mainly enter into the sites in the mirror plane of the trigonalbipyramidal structure.

• Journal of the Korean Society of Safety
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• v.13 no.1
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• pp.85-91
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• 1998

Sol-gel derived silica films were prepared by dip-coating onto polymethylmethacylate with Tetraethoxysilane(TEOS) as starting materials. Film properties such as viscosity and thickness were investigated as a function of dip speed, waterprecursor ratio, sol aging time. IR spectra of the gel films prepared from TEOS at various R are given. At small values of R the absorption peaks assignable to C-H vibration in $-OC_2H_5$ groups are observed around 3000 and 1500-1300 $cm^{-1}$. These bands indicate that the -$-OC_2H_5$ groups are retained in the gel at small values of R because of incomplete hydrolysis of TEOS. Film behaviour was interpreted in terms of the dependence of hydrolysis and condensation rates on the interplay between sol pH and waterprecursor ratio. Film thickness was found to increase by approximately a factor of two as waterprecursor ratio increased from two to six. Film thickness also increased with sol prepolymerization time. Surface quality was correlated with processing conditions.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.11 no.3
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• pp.33-38
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• 2002

This paper deals with pressure ripple attenuation far separated-type Hydrostatic Transmission (HST) consisting ova variable axial piston pump connected in an open loop to a fried displacement axial piston motor. Pressure ripples in HST is major source of vibration which can lead to fatigue failure of components and cause noise. In order to reduce the pressure ripple, an annular tube tripe hydraulic filter is proposed to attenuate pressure ripples with the high frequencies components to achieve better noise reduction in HST. The basic principle of a hydraulic filter is allied to propagation of pressure wave, reflection, absorption in cross section of discontinuity and resonance in the hydraulic pipeline. It is experimentally shown that the hydraulic filter attenuates about 30∼40dB of pressure ripple with high frequencies. These results will assist in modeling and design of noise reduction in hydraulic control systems, and provide a means of designing a quieter HST.

• Journal of KSNVE
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• v.9 no.6
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• pp.1218-1226
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• 1999

In this paper, the extended Biot's semilinear model was developed. Combining the extended Biot model with the dynamic equation yields the nonlinear wave equation in poproelastic sound absorbing materials. Both perturbation and matching techniques are used to find solutions for nonlinear wave equations. By comparing results between linear and nonlinear wave solutions, characteristics of nonlinear waves in poroelastic sound abosrbing materials have been studied. Nonlinear waves were found to be attenuated faster than the linear ones. A maximum amplitude of the nonlinear wave occurred near its surface boundaries and decay quickly with distance from the surface. It has also been found that, if the amplitudes of linear waves are known at the surface boundaries, those of nonlinear ones can be determined. This will be the basis of finding effects of nonlinearity on the absorption coefficient and the transmission loss.

• Journal of KSNVE
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• v.9 no.6
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• pp.1123-1130
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• 1999

A system which is composed of a membrane and an air cavity is studied. To analyze the low frequency characteristics of a single membrane-cavity system, a plane wave model is derived. The relations among system variables, such as tension, density and stiffness, are investigated. Absorption coefficient has a maximum value at a peak frequency. In addition, a membrane-cavity system absorbs the low frequency noise with a band around peak frequency. This band is primarily determined by damping effect of the system. Furthermore, a multiple membrane-cavity system is investigated by using the transfer matrix method. To show the practical applicability of the proposed model, extensive experiments were conducted. Results show that a multiple membrane-cavity system can have broader noise reduction in the low frequency range than single.

• Journal of KSNVE
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• v.10 no.6
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• pp.963-970
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• 2000

The turbo chiller uses centrifugal compressor, which operates at about 14,500 rpm. Due to the high rpm of the impeller, the noise of chiller males one of the serious problems. The possibility of the sound reduction by using absorbing material is studied in this paper. The generated sound propagates through the duct and then radiates to the outer field. So, the use of sound absorption material inside the duct is one of the effective methods. To study the effect of location of the material, we use Boundary Element Method to analyze the sound field inside the duct system. Numerical study shows the highest sound pressure region is near the elbow of curved duct. From the numerical study, it is also shown that appropriate use of sound absorbing material at this region makes 8dB reduction of the highest noise level.

• Current Optics and Photonics
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• v.1 no.4
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• pp.278-283
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• 2017

We theoretically study the dynamics of water tetramer in intense femtosecond laser pulses with different frequencies. The simulations are carried out by incorporating the molecular dynamics method non-adiabatically into the time-dependent local-density approximation (TDLDA-MD). Three typical scenarios of water tetramer including the normal vibration with enlarged OH bonds, free OH bonds breaking and the pure Coulomb explosion are presented by investigating the electronic and ionic dynamics. The result indicates that the ionization is enhanced and the corresponding fragmentation effect as well as the damping of the dipole moment are found more notably when increasing the laser frequency especially when the frequency falls in the resonant region of the absorption spectra. The study of the level depletion reveals that the ratio of the emission amount from different levels can be controlled by changing the laser frequency referring to the Keldysh parameter.

• Current Photovoltaic Research
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• v.2 no.3
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• pp.84-87
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• 2014

Protection of solar cell surface is important to prevent from dust, pollen, sand, etc. Therefore, development of large area antifouling film is urgent for high performance of solar cells. The surface of silica spheres was modified to fabricate large area antifouling film. The surface of monodisperse silica spheres has been modified with 3-(trimethoxysilyl) propylmethacrylate (TMSPM) to fabricate large area photonic crystal. Although the surface modification of silica spheres with TMSPM has been failed for the base catalyst, the second trial using acid catalyst showed the following results. The FTIR absorption peak at $1721cm^{-1}$ representing C=O stretching vibration indicates that the TMSPM was attached on the surface of silica spheres. The methanol solution comprised of the surface modified silica spheres (average diameter of 380 nm) and a photoinitiator was poured in the patterned silicon wafer with the dimension of 10 cm x 10 cm and irradiated UV-light during the self-assembly process. The result showed large area crack and defect free nanostructures.

• Bulletin of the Korean Chemical Society
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• v.10 no.2
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• pp.138-142
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• 1989

Three oxovanadium(IV) complexes with bidentate ligands having only oxygen donor atoms, benzohydroxamic acid (Hben), 8-hydroxyquinoline-N-oxide(Hhqno) and picolinic acid-N-oxide (Hpicn) are prepared and magnetic and spectroscopic properties are investigated for the complexes $VO(ben)_2,\;VO(hqno)_2\;and \;VO(picn)_2.$ Magnetic data together with IR results strongly indicate that dimeric intermolecular interaction is significant in $VO(ben)_2$ while the presence of polymeric V-O${\cdot}{\cdot}$V-O interaction is suggestive in $VO(picn)_2$. For all three complexes, three electronic d-d transitions were observed; extremely strong optical absorption of these bands of $VO(ben)_2$ in DMSO are supposed to be arised from a great metal-ligand covalency. Some fundamental vibration modes of oxovanadium(IV) complexes were empirically assigned from the differences in the spectrum of metal complexes with free ligand.