DOI QR코드

DOI QR Code

Magnetic and Spectroscopic Studies of some Oxovanadium(IV) Complexes having O = V(O)$_4$ Chromophore

  • Published : 1989.04.20

Abstract

Three oxovanadium(IV) complexes with bidentate ligands having only oxygen donor atoms, benzohydroxamic acid (Hben), 8-hydroxyquinoline-N-oxide(Hhqno) and picolinic acid-N-oxide (Hpicn) are prepared and magnetic and spectroscopic properties are investigated for the complexes $VO(ben)_2,\;VO(hqno)_2\;and \;VO(picn)_2.$ Magnetic data together with IR results strongly indicate that dimeric intermolecular interaction is significant in $VO(ben)_2$ while the presence of polymeric V-O${\cdot}{\cdot}$V-O interaction is suggestive in $VO(picn)_2$. For all three complexes, three electronic d-d transitions were observed; extremely strong optical absorption of these bands of $VO(ben)_2$ in DMSO are supposed to be arised from a great metal-ligand covalency. Some fundamental vibration modes of oxovanadium(IV) complexes were empirically assigned from the differences in the spectrum of metal complexes with free ligand.

Keywords

References

  1. Chem. Rev. v.65 J. Selbin
  2. Coored. Chem. Rev. v.1 J. Selbin
  3. Angew. Chem. v.12 J. Selbin
  4. Inorg. Chem. v.12 B. J. McCermick;J. L. Featherstone;H. J. Stokkolosa;J. R. Wasson
  5. Inorg. Chem. v.7 L. J. Boucher;E. C. Tynan;T. F. Yen
  6. Inorg. Chem. v.8 L. J. Boucher;T. F. Yen
  7. Chem. Commun. R. J. Farmer;F. L. Urbach
  8. Inorg. Chem. Acta v.2 R. G. Ciarvey;R. O. Ragsdale
  9. J. Am. Chem. Soc. v.92 M. Mathew;A. J. Carty;G. J. Plenik
  10. Inorg. Chem. v.13 R. L. Farmer;F. L. Urbach
  11. Inorg. Chem. v.9 R. L. Farmer;F. L. Urbach
  12. Inorg. Chem. v.5 A. P. Ginsberg;E. Koubeck;H. J. Williams
  13. Bull. Chem. Soc. (Japan) v.43 Y. Kuge;S. Yamada
  14. Inorg. Chem. v.10 B. J. McCormick;R. A. Bozis
  15. J. Org. Chem. v.34 C. R. Houser;W. B. Renfrow, Jr.
  16. Rev. Scient. Instrum. v.30 S. Foner
  17. J. Chem. Soc. B. N. Figgis;R. S. Nyholm
  18. J. Phys. Chem. v.77 H-st. Rade
  19. Magnetochemistry P. Selwood
  20. Inorg. Nucl. Chem. Lett. v.9 G. D. Simpson;G. O. Carlisle
  21. Russ. J. Inorg. Chem. v.7 V. V. Zelentsov
  22. Coord. Chem. Rev. v.16 A. Symal
  23. J. Indian Chem. Soc. v.47 S. N. Poddar;K. Dey;J. Haldar;S. C. Nathsarkar
  24. Bull. Chem. Soc. (Japan) v.45 Y. Kuge;S. Yamada
  25. Aust. J. Chem. v.22 A. T. Casey;J. R. Thackeray
  26. Inorg. Chem. v.11 R. G. Cavell;E. D. Day;W. Byers;P. M. Watkins
  27. J. Indian Chem. Soc. v.40 R. L. Dutta;S. Lahiry
  28. J. Indian Chem. Soc. v.40 S. N. Poddar;K. Dey;S. C. Nathsarkar
  29. Theory and Applications of Molecular Paramagernatism E. A. Boudreaux;L. N. Mulay
  30. J. Am. Chem. Soc. v.79 Wiley;Slaymaker
  31. Physical Methods in Hetrocyclic Chemistry v.2;4 Katritzky;Ambler;Katritzty;Taylor
  32. Inorg. Chem. v.13 R. L. Farmer;F. L. Urbach
  33. J. Am. Chem. Soc. v.92 M. Mattew;A. J. Carty;G. J. Palenik
  34. Inorg. Chem. v.12 J. B. Milne;Moffett
  35. Inorg. Chem. v.11 K. O. Kriste;E. C. Carties
  36. J. Chem. Phys. v.42 G. M. Begun;W. H. Fletcher;D. F. Smith
  37. Inorg. Chem. v.13 R. T. Paine;R. S. DcDowell
  38. J. Mol. Struc. v.19 R. J. Collins;W. P. Griffith;D. Dawson
  39. Inorg. Chem. v.1 C. J. Ballhausen;H. B. Gray
  40. Inorg. Chem. v.13 H. A. Kuska;P. H. Yang
  41. J. Mol. Spectry. v.37 M. H. Valek;W. A. Yeranos;G. Basu;P. K. Hon;R. L. Belford
  42. Inorganic Electronic Spectroscopy A.B.P. Lever
  43. J. Inorg. Nucl. Chem. v.36 H. J. Stokolsa;J. R. Wasson
  44. Chem. Phys. Lett. v.19 Z. Jaeger;R. Englman