• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.783-787
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• 2013

The separation and capture process of carbon dioxide from power plants is garnering interest as a method to reduce greenhouse gas emissions. In this study, aqueous alkanolamine solutions were studied as absorbents for $CO_2$ capture. The solubility of $CO_2$ in aqueous alkanolamine solutions was investigated with a continuous stirred reactor at 313, 333 and 353 K. Also, the heat of absorption ($-{\Delta}H_{abs}$) between the absorbent and $CO_2$ molecules was measured with a differential reaction calorimeter (DRC) at 298 K. The solubility and heat of absorption were determined at slightly higher than atmospheric pressure. The enthalpies of $CO_2$ absorption in monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), and 2-amino-2-methyl-1-propanol (AMP) were 88.91, 70.44, 44.72, and 63.95, respectively. This investigation showed that the heat of absorption is directly related to the quantity of heat for absorbent regeneration, and is dependent on amine type and $CO_2$ loading.

• 한국환경보건학회:학술대회논문집
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• 한국환경보건학회 2003년도 Challenges and Achievements in Environmental Health
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• pp.213-216
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• 2003

This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) “A” can cause anti-microbial activity and health effect. Three water-based MWF products (“A”, “B”, and “C”) were studied every week for two months (from June 1, 2002 to July 30, 2002). Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF “A” was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF A were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF “A” are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically, To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

• 한국환경보건학회지
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• 제34권2호
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• pp.148-152
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• 2008

Coated filters were developed to replace the glass impinger methods that use reagent solutions. The purpose of this study was to simultaneously measure nitrogen dioxide ($NO_2$) and respirable suspended particles (RSP) by a filtration method with a cyclone connected to a pump. A first pre-filter for RSP and second filter for $NO_2$, which was soaked in a TEA (Triethanolamine) solution, were loaded into a filter cassette with a pump flow rate of 1.7 l/m. After sampling, the TEA soaked filter was removed from the cassette, placed in a large test tube (10 ml), mixed, and allowed time to develop. The absorbance (abs) of the diazo compound of the $NO_2$ and N-(1-Napthylethylenediamine dihydrochloride) in the color reagent was measured at 545 nm on a spectrophotometer. The collection efficiency(%) of $NO_2$ by each 3 filter soaked in TEA solution and used in the cyclone with a pump flow rate 1.7 l/m was $89{\pm}3%$ and the correlation coefficient between the true $NO_2$ concentration and that determined by the TEA soaked filters was 0.993(p<0.001).

• 한국세라믹학회지
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• 제31권11호
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• pp.1271-1282
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• 1994

The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${\gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${\gamma}$-LiAlO2 sol was completely transformed into the ${\gamma}$-LiAlO2 at $600^{\circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${\gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{\circ}C$.

• 콘크리트학회논문집
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• 제12권6호
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• pp.51-56
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• 2000

Fly ash used as a cement replacement material increases the long term strength and also improves the durability of concrete and mortar. However, the use of fly ash is a little in spite of great benefit. In order to increase the consumption of fly ash, it has to be used as a cement replacement materials in the production of mortar and concrete, and the reduction of early strength development due to the use of fly ash also has to be diminished. In this study, many chemical compounds which accelerate the early strength was investigated. The $Na_2$$SO_4$, $K_2$$SO_4$, Triethanolamine were selected and applied to the production of mortar. It was found that they enhance the early strength development of mortar(1, 3day) and decrease the amount of $Ca(OH)_2$, and also increase the production of ettringite. According to the results of mercury instruction test, the pores ranged from 0.01 $\mu\textrm{m}$ to 5$\mu\textrm{m}$ were decreased and it was also found in the analysis of X ray and SEM that fly ash increases the amount of ettringite at early ages.

• 한국응용과학기술학회지
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• 제29권1호
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• pp.54-62
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• 2012

본 실험에서는 투명비누를 만드는데 사용되는 폴리올의 최적 농도를 실험계획법을 이용하여 결정하였다. 짧은 사슬을 보유한 디프로필렌글리콜과 1,3 부틸렌글리콜은 비누의 투명도를 증가시켰으나 폴리에틸렌글리콜 400, 글리세린과 디글리세린은 비누를 불투명하게 하였다. 프로필렌글리콜, 디글리세린, 디프로필렌글리콜 및 폴리에틸렌글리콜의 농도를 증가시키면 비누의 경도는 증가하였다. 경도, 투명도, 물의 흡수성 및 마찰 용해도는 디프로필렌글리콜, 폴리에틸렌글리콜, 설탕과 트리에탄올아민의 농도를 조절하여 최적화할 수 있었다.

• 한국전기전자재료학회논문지
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• 제14권5호
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• pp.423-429
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• 2001

PbS, CuS and (Pb,Cu)S thin films were chemically deposited on glass from alkaline baths containing lead acetate, copper chloride, thiourea and triethanolamine. The deposition, optical, resistivity and thermal electric properties of these films were studied. PbS thin films showed a hexagonal structure and CuS thin films showed amorphous. The crystalline of (Pb,Cu)S thin films was obtained by heat treatment at 200$\^{C}$ and the deposition ratio of Pb to Cu showed 7:3. The energy gap of PbS, CuS and (Pb,Cu)S thin films were 1.7, 2.1 and 2.4 eV, respectively. Sheet resistance of PbS thin films was less affected on thermal annealing, but hose of (Pb,Cu)S and CuS thin films were more reduced about 3 orders of magnitude. All of those thin films indicated p type semiconductor in temperature ranging 30$\^{C}$ to 150$\^{C}$.

• 한국정밀공학회지
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• 제18권2호
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• pp.161-170
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• 2001

Synthetic water-based metal-cutting fluids are increasingly popular in the metal-working industry because of its environmental friendliness. The propose of this study is to investigate the synergistic effect of combining polyethylene glycol and common fatty acid in formulating a metal-cutting fluid. The tested metals were aluminum, copper and steel, and the test was performed with a modified drilling machine. From the study, it was found that there existed some synergistic effects on the drilling efficiency of the metals to decrease of cutting time, cutting energy, torque as well as the smoothness of surface depended on the formulation ratio of the two fluids.

• Journal of the Optical Society of Korea
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• 제10권1호
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• pp.1-10
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• 2006

Optical transparency and high diffraction efficiency are two essential factors for high performance of the photopolymer. Optical transparency mainly depends on the miscibility between polymer binder and photopolymerized polymer, while diffraction efficiency depends on the refractive index modulation between polymer binder and photopolymerized polymer. For most of organic materials, the large refractive index difference between two polymers accompanies large structural difference that leads to the poor miscibility and thus poor optical quality via light scattering. Therefore, it is difficult to design a high-performance photopolymer satisfying both requirements. In this work, first, we prepared a new phase-stable photopolymer (PMMA) with large refractive index modulation and investigated the optical properties. Our photopolymer is based on modified poly (methyl methacrylate) as a polymer binder, acryl amide as a photopolymerizable monomer, triethanolamine as initiator, and yellow eosin as a photosensitizer at 532 nm. Diffraction efficiency over 85% and optical transmittance over 90% were obtained for the photopolymer. Second, Organic-inorganic nanocomposite films were prepared by dispersing an aromatic methacrylic monomer and a photo- initiator in organic-inorganic hybrid sol-gel matrices. The film properties could be controlled by optimizing the content of an organically modified silica precursor (TSPEG) in the sol-gel matrices. The photopolymer film modified with the organic chain (TSPEG) showed high diffraction efficiency (> 90%) under an optimized condition. High diffraction efficiency could be ascribed to the fast diffusion and efficient polymerization of monomers under interference light to generate refractive index modulation. The TSPEG modified photopolymer film could be successfully used for holographic memory.

• Archives of Pharmacal Research
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• 제24권6호
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• pp.578-583
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• 2001

To investigate the feasibility of developing a new tenoxicam plaster, the effects of vehicles and penetration enhancers on the in vitro permeation of tenoxicam from a pressure-sensititre adhesive (PSA) matrices across the dorsal hairless mouse skin were studied. Vehicles employed in this study were propylene glycol (PC)-oleyl alcohol (OAI), PG-oleic acid (OA), and diethylene glycol monoethyl ether (DCMI)-propylene glycol monolaurate (PCML) cosolvents with/without fatty acids. In this studys amines such as triethanolamine (TEA) and tromethamine (TM) were additionally used as a solubilized. Among PSAs used, $Duro-Tak^{\circledR}$87-2510 showed much higher release rate than either $Duro-Tak^{\circledR}$ 87-2100 or $Duro-Tak^{\circledR}$87-2196. The relatively high flux rate was obtained with the formulation of DCMI-PCML (40:60, v/v) with 3% OA and 5% TM, and the flux increased as a function of the dose;the initial flux up to 12 h was $4.98{\pm}1.38{\;}{\mu\textrm{g}}/{\textrm{cm}^2}/h$ at the tenoxicam dose of $50{\;} mg/70{\;}{\textrm{cm}^2}$. This flux was much higher than that of a commercial piroxicam patch ($Trast^{\circledR}$) ($1.24{\pm}0.73{\;}{\mu\textrm{g}}/$\textrm{cm}^2/hr$) with almost only one-third that of the commercial patch. Therefore, these observations indicated that these composition of tenoxicam plaster may be practically applicable.