• Title/Summary/Keyword: transport and diffusion

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Effects of Aspect Ratio on Diffusive-Convection During Physical Vapor Transport of Hg2Cl2 with Impurity of NO (염화제일수은과 일산화질소의 물리적 승화법 공정에서의 확산-대류에 미치는 에스펙트 비율의 영향)

  • Kim, Geug-Tae
    • Applied Chemistry for Engineering
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    • v.26 no.6
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    • pp.746-752
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    • 2015
  • This study investigates the effects of aspect ratio (transport length-to-width) on diffusive-convection for physical vapor transport processes of $Hg_2Cl_2-NO$ system. For a system with the temperature difference of 20 K between an interface at the source material region and growing crystal interface, the linear temperature profiles at walls, the total molar fluxes at Ar = 2 are much greater than Ar = 5 as well as the corresponding nonuniformities in interfacial distributions due to the effect of convection. The maximum total molar flux at the gravitational acceleration of 1 $g_0$ is greater twice than at the level of 0.1 $g_0$, where g0 denotes the gravitational acceleration on earth. With increasing aspect ratio from 2 to 5, a diffusive-convection mode is transited into the diffusion mode, and then the strength of diffusion is predominant over the strength of diffusive-convection.

Reactor core analysis through the SP3-ACMFD approach Part II: Transient solution

  • Mirzaee, Morteza Khosravi;Zolfaghari, A.;Minuchehr, A.
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.230-237
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    • 2020
  • In this part, an implicit time dependent solution is presented for the Boltzmann transport equation discretized by the analytic coarse mesh finite difference method (ACMFD) over the spatial domain as well as the simplified P3 (SP3) for the angular variable. In the first part of this work we proposed a SP3-ACMFD approach to solve the static eigenvalue equations which provide the initial conditions for temp dependent equations. Having solved the 3D multi-group SP3-ACMFD static equations, an implicit approach is resorted to ensure stability of time steps. An exponential behavior is assumed in transverse integrated equations to establish a relationship between flux moments and currents. Also, analytic integration is benefited for the time-dependent solution of precursor concentration equations. Finally, a multi-channel one-phase thermal hydraulic model is coupled to the proposed methodology. Transient equations are then solved at each step using the GMRES technique. To show the sufficiency of proposed transient SP3-ACMFD approximation for a full core analysis, a comparison is made using transport peers as the reference. To further demonstrate superiority, results are compared with a 3D multi-group transient diffusion solver developed as a byproduct of this work. Outcomes confirm that the idea can be considered as an economic interim approach which is superior to the diffusion approximation, and comparable with transport in results.

Numerical simulation of advection-diffusion on flow in waste stabilization ponds (1-dimension) with finite difference method forward time central space scheme

  • Putri, Gitta Agnes;Sunarsih, Sunarsih;Hariyanto, Susilo
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.442-448
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    • 2018
  • This paper presents the numerical simulation of advection-diffusion mechanism of BOD concentration which was used as an indicator of waste only in one flow-direction of waste stabilization ponds (1-dimension (1-D)). This model was represented in partial differential equation order 2. The purpose of this paper was to determine the simulation of the model 1-D of wastewater transport phenomena based advection-diffusion mechanism and did validate the model. Numerical methods which was used for the solution of this model is finite difference method with Forward Time Central Space scheme. The simulation results which was obtained would be compared with field observation data as a validation model. Collection of field data was carried out in the Wastewater Treatment Plant Sewon, Bantul, D.I. Yogyakarta. The results of numerical simulations were indicate that the advection-diffusion mechanism takes place continuously over time. Then validation of the model was state that there was a difference between the calculation results with the field data, with a correlation value of 0.998.

Electrochemical model for the simulation of solid oxide fuel cells (고체산화물연료전지의 시뮬레이션을 위한 전기화학모델)

  • Park, Joon-Guen;Lee, Shin-Ku;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.63-66
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    • 2008
  • This study presents 0-dimensional model for solid oxide fuel cells(SOFCs). The physics of the cell and the simplifying assumptions are presented, and only hydrogen participates in the electrochemical reaction. The electrical potential is predicted using this model. The Butler-Volmer equation is used to describe the activation polarization and the exchange current density is changed according to the partial pressure of reactants and the temperature. The electrical conductivities of electrodes and an electrolyte are calculated for the ohmic polarization. Material characteristics and temperature affect those factors. Analysis of concentration polarization based on transport of gaseous species through porous electrodes is incorporated in this model. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results and numerical results by other researchers.

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The characteristics of laminar diffusion flame impinging on the wall (벽면 충돌 층류 확산화염의 특성)

  • Park,Yong-Yeol;Kim, Ho-Yeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.3
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    • pp.979-987
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    • 1996
  • A theoretical study for the laminar round jet diffusion flame impinging on the wall was carried out to predict the characteristics and structure of impinging jet flame and heat transfer to the wall. Finite chemistry via Arrhenius equation was adopted as the combustion model. All the transport properties were considered as the variable depending on the temperature and composition. For the parametric study, the distance from nozzle to perpendicular wall and Reynolds number at nozzle exit were chosen as the major parameters. As the results of the present study, the characteristics of flow field and the distributions of temperature, density and each chemical species were obtained. The heat transfer rate from flame to the wall and the effective heating area were calculated to investigate the influence of the major parameters on the heat transfer characteristics.

A Monte-Carlo method and Boltzmann Equation analysis on the electron swarm parameter in SiH$_4$+Ar mixtures gas. ($SiH_4+Ar$ 혼합기체의 전자군 파라미터에 대한 볼츠만 방정식 및 몬테 칼로법 해석)

  • 김대연;하성철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.387-390
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    • 1999
  • Electron swarm parameterdthe drift velocity and longitudinal diffusion coefficienthn $SiH_4-Ar$ mixtures containing 0.5% and 5% monosilane were measured using over the range of E/N from 0.01 to 300 Td at room temperature. Electron swarm parameters in argon were drastically changed by adding a small amount of monosilane. The electron drift velocity in both mixtures showed unusual behaviour against E/N. It had negative slope in the medium range of E/N, yet the slope was not smooth but contained a small hump. The longitudinal diffusion coefficient also showed a corresponding feature in its dependence on E/N. A two-tern approximation of the Boltzmann equation analysis and Monte Carlo simulation have been used to study electron transport coefficients.

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3-D Numerical Prediction Modeling of Air Pollution in Coastal Urban Region - II. Movement and Diffusion Prediction of Air Pollutants - (연안도시지역에서 대기오염의 3차원 수치예측모델링 -II. 대기오염물질의 이동과 화산예측-)

  • gyeong-Mee Won;Hwa-Woon Lee
    • Journal of Environmental Science International
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    • v.10 no.5
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    • pp.343-350
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    • 2001
  • To investigate air quality away from the coastal urban source region, we used a hybrid Eulerian - Lagrangian method which can describe the formation, transport, transform and deposition processes in complex terrain, with inclusion of shipping sources that were considered to be important emission in the coastal urban region. The result of the Eulerian advection - diffusion prediction was quite similar to that of the Lagrangian particle diffusion prediction. It showed that pollutants emitted from Sasang and Janglim industrial complexes can affect Hwamyeong and the coastal, respectively. During the daytime the concentration was low due to large deposition flux and terrain effect.

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Investigation of Reducing Characteristics for the Spreading of Dredging Soil and the Diffusion of Contaminant by Silt Protector Curtain through Three Dimensional Numerical Model Experiment (3차원 수치모형실험을 통한 오탁방지막의 오염물질 및 준설토 확산 저감특성 조사)

  • Hong, Nam-Seeg
    • Journal of Ocean Engineering and Technology
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    • v.24 no.4
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    • pp.78-85
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    • 2010
  • This study investigates reducing characteristics for the spreading of dredged soil and the diffusion of contaminant by silt protector curtain through three dimensional numerical experiment. The numerical medel is modified by combining the sediment transport characteristics for cohesive sediment into the previously developed model. Several numerical experiments have been given in order to investigate the reducing effect of silt protector using two dimensional numerical channel model under various parameters such as upstream flow velocity, depth of silt curtain and the position of dumped materials. Through the evaluation of several simulation results, we knew that the careful design has to be given in the determination of depth and position of silt protector.

Unsteady Analysis of Acoustic-Pressure Responses of $N_{2}$ Diluted $H_{2}$ and Air Diffusion Flames (희석된 수소/공기 확산화염의 비정상 음향파 응답특성 해석)

  • Sohn, Chae-Hoon
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.320-325
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    • 2003
  • Acoustic-Pressure Response of diluted hydrogen-air diffusion flames is investigated numerically by adopting a fully unsteady analysis of flame structures. In the low-pressure regime, the amplification index remains low and constant at low frequencies. As acoustic frequency increases, finite-rate chemistry is enhanced through a nonlinear accumulation of heat release rate, leading to a high amplification index. Finally, the flame responses decrease at high frequency due to the response lag of the transport zone. For a medium-pressure operation and low-frequency excitation, the amplification index is low and constant. It then decreases at moderate frequencies. As frequency increases further, the amplification index increases appreciably due to an intense accumulation effect.

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Organic Pollutant Transport in Unsaturated Porous Media by Atmospheric Breathing Process(II) Dispersion Coefficient (불포화토양에서 확산에 의한 유기오염물질의 이동)

  • 구자공;황종혁
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1997.05a
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    • pp.79-82
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    • 1997
  • 토양내에서 오염유기물질이 불포화토양내에 유입될 때의 dispersion coefficient를 adsorption과 desorption과정에 대해 알아보았다. apparent dispersion coefficient를 측정하기 위해 일상적인 상대습도(46%)조건에서 parametric analysis를 행하였다. 실험에 사용된 토양은 fine sand와 silt-clay혼합시료였고, 흐름방향은 상향과 하향으로 하였다. 그리고, Freon gas를adsorbing solute로 사용하였다. 오염물질로는 DCM, TCE, DCB를 사용하였다. 분석을 위해서 linear와 probability scale의 breakthrough curve를 사용하였다. 공기에서의 diffusion coefficient의 예측을 위하여 Graham's law를 계산에 사용하였고, DCM diffusion coefficient는 0.098$\textrm{cm}^2$/s로 계산되었다. 연구결과, adsorption과 desorption의 속도는 차이가 있는 것으로 나타났으며, diffusion이 flow regime을 좌우하는 것으로 나타났다. 그리고, desorption에서의 D$^{a}$ D$^{o}$ 는 1보다 클수도 있다. 또한, dispersion은 silt-clay혼합시료에서의 속도와 함께 증가한다. dispersion은 Freon의 sorption방향에 크게 의존한다.

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