• Journal of the Korean Ceramic Society
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• v.52 no.2
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• pp.128-132
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• 2015

In this study, we prepared cadmium phosphate glasses with various compositions, given by $xCdO-(100-x)P_2O_5$ (x = 10-55 mol%), and analyzed their Fourier transform infrared spectra, dissolution rate, thermal expansion coefficient, glass transition temperature, glass softening temperature, and optical band gap. We found that the thermal expansion coefficient and dissolution rate increased while the glass transition temperature and glass softening temperature decreased with increasing CdO content. These results suggest that CdO acts as a network modifier in binary phosphate glass and weakens its structure.

• Bulletin of the Korean Chemical Society
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• v.19 no.7
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• pp.776-779
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• 1998

Second-order rate constants have been measured spectrophotometrically for the addition reaction of a series of alicyclic amines to 3-butyn-2-one to yield their respective enamines at 25.0 'C. The reactivity of the amines increases with increasing the basicity of the amines. However, the Bronsted-type plot obtained exhibits a downward curvature as the basicity of the amines increases, i.e. βnuc decreases from 0.3 for low basic amines (pKa < 9) and to 0.1 for highly basic amines (pKa > 9). Such a curvature in the Bronsted-type plot is clearly indicative of a change in the reaction mechanism or transition state structure. From the corresponding reactions run in D2O, the magnitude of kinetic isotope effect (KIE) has been calculated to be about 0.8 for highly basic amines and 1.21 for weakly basic amines. The difference in the magnitude of KIE also supports a change in the reaction mechanism or transition state structure upon changing the basicity of the amines. Furthermore, the small KIE clearly suggests that H+ transfer is not involved in the rate-determining step, i.e. the addition reaction is considered to proceed via a stepwise mechanism in which the attack of the amines to the acetylene is the rate-determining step. The curvature in the Bronsted-type plot has been attributed to a change in the degree of bond formation between the amine and the acetylene.

• Bulletin of the Korean Chemical Society
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• v.19 no.9
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• pp.968-973
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• 1998

Solvolyses of para-substituted phenyl chloroformates in water, $D_2O,\;CH_3OD$, 50% $D_2O-CH_3OD$, and in aqueous binary mixtures of acetone, ethanol, methanol are investigated at 25.0 ℃. Product selectivities are reported for a wide range of ethanol-water and methanol-water solvent compositions. These data are interpreted using the Grunwald-Winstein relationship, Hammett equation, and quantum mechanical model. Grunwald-Winstein plots of the first-order rate constants for phenyl chloroformates with $Y_{Cl}$ (based on 1-adamantyl chloride) show marked dispersions into three separate curves for the three aqueous mixtures with a small m value and a rate maximum for aqueous alcohol solvents. To account for these results, third-order rate constants, $k_{ww},\;k_{aw},\;k_{wa}$, and $k_{aa}$ were calculated from the observed $k_{ww}\;and\;k_{aa}$ values together with $k_{aw}\;and\;k_{wa}$ calculated from the computer fit. The kinetic solvent isotope effects determined in water and methanol are consistent with the proposed mechanism of the general base catalyzed carbonyl addition-elimination for para-substituted phenyl chloroformates solvolyses based on mass law and stoichiometric salvation effect studies. This study has shown that the quantum mechanical model predicts transition state variation correctly for $S_N2\;like\;S_AN$ reaction mechanism of para-substituted phenyl chloroformates.

• Journal of Labour Economics
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• v.43 no.4
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• pp.117-141
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• 2020

The paper focuses on the question of whether and how the labor underutilization indicator supplements the unemployment rate. The research is based on the differences in the labor market behavior among three groups of the not-employed; the unemployed, potential labor force and the rest of outside the labor force. The annual transition rate among the labor market states shows that the potential labor force has the explicit unmet need for employment different from the rest of the outside the labor force. The multinomial logit regression controlling the effects of individual characteristics rejects the hypothesis that the potential labor forces are behaviorally identical to the unemployed. The evidence shows that the two indices should be interpreted distinctively.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.36 no.5
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• pp.407-419
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• 2008

In this study, the transition Reynolds number of compressible axi-symmetric sharp cone boundary layer is predicted by using a linear stability theory and the -method. The compressible linear stability equation for sharp cone boundary layer was derived from the governing equations on the body-intrinsic axi-symmetric coordinate system. The numerical analysis code for the stability equation was developed based on a second-order accurate finite-difference method. Stability characteristics and amplification rate of two-dimensional second mode disturbance for the sharp cone boundary layer were calculated from the analysis code and the numerical code was validated by comparing the results with experimental data. Transition prediction was performed by application of the -method with N=10. From comparison with wind tunnel experiments and flight tests data, capability of the transition prediction of this study is confirmed for the sharp cone boundary layers which have an edge Mach number between 4 and 8. In addition, effect of wall cooling on the stability of disturbance in the boundary layer and transition position is investigated.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.150-154
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• 2004

Gas explosion characteristics of hydrogen and liquefied petroleum gas(LPG) were measured in 6L cylindrical vessel, and experiment for explosion to fire transition phenomena of the gases were carried out using the 270L vessel. Explosion characteristics were measured using the stain type pressure transducer and explosion to fire transition phenomena was analyzed with the hish-speed camera. Base on the experiment, it was found that explosion pressure was most high slightly above the stoichiometric concentration, and explosion pressure rise rate and flame propagation velocity were proportional to the combustion velocity. And we find that those kind of explosion characteristics affect the explosion-to-fire transition, in addition, explosion flame temperature, flame residence time, are important parameters in explosion-to-fire transition.

• Fire Science and Engineering
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• v.28 no.1
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• pp.26-30
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• 2014

A Compensation-type fire detector (CFD) is operated with two functions of a differential-temperature detector and as a fixed-temperature detector. The differential-temperature detector observes a rate of temperature increase, and the fixed-temperature detector measures a given fixed temperature. The differential-temperature detector does not observe the outbreak of fire in slowly increasing temperature conditions, whereas the fixed-temperature detector is not able to observe the outbreak of fire in conditions under predetermined temperature level. We developed a CFD to compensate for weaknesses of both detectors. To compensate for the disadvantages, a sensor of the sensor metal-insulator-transition critical-temperature sensor was used. Temperature coefficient of resistance is the sensitivity for sensor. At $55^{\circ}C$, temperature coefficient of resistance of metal-insulator-transition critical-temperature sensor was 14.15%. Temperature coefficient of resistance of thermistor was about 0.5%. This CFD was operated as two ways that fixed-temperature detector and differential-temperature detector in one sensor.

• Nuclear Engineering and Technology
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• v.27 no.4
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• pp.503-517
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• 1995

A mechanistic model for forced convective transition boiling has been developed to predict transition boiling heat flux realistically. This model is based on a postulated multi­stage boiling process occurring during the passage time of an elongated vapor blanket specified at a critical heat flux condition. Between the departure from nucleate boiling (DNB) and the departure from film boiling (DFB) points, the boiling heat transfer is established through three boiling stages, namely, the macrolayer evaporation and dryout governed by nucleate boiling in a thin liquid film and the unstable film boiling. The total heat transfer rate during the transition boiling is the sum of the heat transfer rates after the DNB weighted by the time fractions of each stage, which are defined as the ratio of each stage duration to the vapor blanket passage time. The model predictions are compared with some available experimental transition boiling data. From these comparisons, it can be seen that the transition boiling heat fluxes including the maximum heat flux and the minimum film boiling heat flux are nil predicted at low qualities/high pressures near 10 bar.

• Journal of the Korean association of regional geographers
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• v.17 no.6
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• pp.710-725
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• 2011

The purpose of this study is to analyze both residential conditions and the resident impressions of the transition zone of central Daegu. The results drawn from a questionnaire survey of the residents are summarized as follows: 1) The proportion of people over the age of 60 living on a low income is high and consists mostly of retired citizens who have lived in the transition zone, in their own homes, for an extended length of time 2) The condition of infrastructure in the transition zone is very poor, however, despite the housing deterioration, the internal repair and maintenance of houses is more satisfactory than their external appearance. 3) Residential satisfaction received high ratings in every category except pollution and housing price. This response appears to stem from the easy commute of residents as well as the ready availability of facilities in the city center. 4) In terms of residential satisfaction, the residents can be divided into two groups. The first, with a high satisfaction rate, consists mainly of senior citizens who possess both personal homes and a stable living, having resided in the city center for most of their lives. The second, with a lower satisfaction rate, is composed mostly of younger residents who have lived temporarily in inexpensive rental homes. As a results, the residential area in the transition zone of central Daegu does not appear to be a problematic area like the slum of the West, but instead a stable settlement for its residents.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.8 no.3
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• pp.13-22
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• 2012

According to recent research on leak-rate estimates to assess rupture probabilities of nuclear piping which contains a circumferential surface/through-wall cracks due to PWSCC, i.e., xLPR (Extremely Low Probability of Rupture) program, it has been revealed that the use of crack shape with an idealized circumferential through-wall crack during actual crack growth can lead to overestimate of the leak-rate. Thus, for accurate estimation of the leak-rate during crack growth, the more realistic crack shape that can simulate the crack shape transition from surface crack to through-wall crack should be used. In this context, in the present study, the elastic crack opening displacement of slanted circumferential through-wall crack in thick-walled cylinder was proposed based on 3-dimensional elastic finite element fracture mechanics analyses. To propose the elastic crack opening displacement of slanted circumferential through-wall crack in thick-walled cylinder, the geometric variables affecting crack opening displacement, i.e., thickness of cylinder, reference inner crack length and slant crack ratio were systematically varied. In terms of loading conditions, axial tension, global bending moment and internal pressure were considered. The present results can be applied to calculate the leak-rate considering more realistic crack shape transition from surface crack to idealized through-wall crack, and can be expected to enhance current leak-rate estimation scheme, for instance, in xLPR program etc.