• Bulletin of the Korean Chemical Society
• /
• 제22권2호
• /
• pp.219-227
• /
• 2001

The silver colloidal effects on the excited-state structure and intramolecular charge transfer (ICT) of p-N,N-dimethylaminobenzoic acid (DMABA) in aqueous cyclodextrin (CD) solutions have been investigated by UV-VIS absorption, steady-state and time-resolved fluorescence, and transient Raman spectroscopy. As the concentration of silver colloids increases, the ratio of the ICT emission to the normal emission (Ia /Ib) of DMABA in the aqueous $\alpha-CD$ solutions are greatly decreased while the Ia /Ib values in the aqueous B-CD solutions are significantly enhanced. It is also noteworthy that the ICT emission maxima are red-shifted by 15-40 nm upon addition of silver colloids, implying that DMABA encapsulated in $\alpha-CD$ or B-CD cavity is exposed to more polar environment. The transient resonance Raman spectra of DMABA in silver colloidal solutions demonstrate that DMABA in the excited-state is desorbed from silver colloidal surfaces as demonstrated by the disappearance of νs (CO2-)(1380 cm-1 ) with appearance of ν(C-OH)(1280 cm -1) band, respectively. Thus, in the aqueous B-CD solutions the carboxylic acid group of DMABA in the excited-state can be readily hydrogen-bonded with the secondary hydroxyl group of B-CD while in aqueous and $\alpha-CD$ solutions the carboxylic acid group of DMABA has the hydrogen-bonding interaction with water. Consequently, in the aqueous B-CD solutions the enhancement of the Ia /Ia value arises from the intermolecular hydrogen-bonding interaction between DMABA and the secondary hydroxyl group of B-CD as well as the lower polarity of the rim of the B-CD cavity compared to bulk water. This is also supported by the increase of the association constant for DMABA/ B-CD complex in the presence of silver colloids.

• 대한기계학회논문집A
• /
• 제25권11호
• /
• pp.1802-1812
• /
• 2001

The theoretical method is developed to investigate the effects of ring stiffeners on free vibration characteristics and transient response for the ring stiffened composite cylindrical shells subjected to the impulse pressure Loading. In the theoretical procedure, the Love's thin shell theory combined with the discrete stiffener theory to consider the ring stiffening effect is adopted to formulate the theoretical model. The concentric or eccentric ring stiffeners are laminated with composite and have the uniform rectangular cross section. The modal analysis technique is used to develop the analytical solutions of the transient problem. The analysis is based on an expansion of the loads, displacements in the double Fourier series that satisfy the boundary conditions. The effect of stiffener's eccentricity, number, size, and position on transient response of the shells is examined. The results are verified by comparison with FEM results.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 춘계학술대회논문집A
• /
• pp.883-888
• /
• 2001

The theoretical method is developed to investigate the effects of ring stiffeners on free vibration characteristics and transient response for the ring stiffened composite cylindrical shells subjected to the impulse pressure loading. In the theoretical procedure, the Love's thin shell theory combined with the discrete stiffener theory to consider the ring stiffening effect is adopted to formulate the theoretical model. The concentric or eccentric ring stiffeners are laminated with composite and have the uniform rectangular cross section. The modal analysis technique is used to develop the analytical solutions of the transient problem. The analysis is based on an expansion of the loads, displacements in the double Fourier series that satisfy the boundary conditions. The effect of stiffener's eccentricity, number, size, and position on transient response of the shells is examined. The theoretical results are verified by comparison with FEM results.

• 대한기계학회논문집
• /
• 제16권9호
• /
• pp.1700-1710
• /
• 1992

본 연구에서는 경계요소법에 의해 천이상태 열전도문제를 해석하는 프로그램 과 Sladek등이 제안한 열탄성 경계적분방정식을 기초로 하여 열탄성문제를 해석하는 프로그램을 개발하여, 유한체 내에 존재하는 Griffith 균열에 대해 정상 및 천이상태 에서 계산한 열응력세기계수와 유한체 내에 존재하는 대칭 입술형 커스프균열(symme- tric lip cusp crack)에 대해 정상상태에서 열응력세기계수를 계산한다. 그 결과를 기존의 해와 비교하여 프로그램의 타당성을 입증한다. 그후 대칭 입술형 커스프균열 에 대한 천이상태에서의 열응력세기계수를 계산하고자 한다.

• Nuclear Engineering and Technology
• /
• 제45권2호
• /
• pp.191-202
• /
• 2013

A numerical analysis of thermal stratification in the upper plenum of the MONJU fast breeder reactor was performed. Calculations were performed for a 1/6 simplified model of the MONJU reactor using the commercial code, CFX-13. To better resolve the geometrically complex upper core structure of the MONJU reactor, the porous media approach was adopted for the simulation. First, a steady state solution was obtained and the transient solutions were then obtained for the turbine trip test conducted in December 1995. The time dependent inlet conditions for the mass flow rate and temperature were provided by JAEA. Good agreement with the experimental data was observed for steady state solution. The numerical solution of the transient analysis shows the formation of thermal stratification within the upper plenum of the reactor vessel during the turbine trip test. The temporal variations of temperature were predicted accurately by the present method in the initial rapid coastdown period (~300 seconds). However, transient numerical solutions show a faster thermal mixing than that observed in the experiment after the initial coastdown period. A nearly homogenization of the temperature field in the upper plenum is predicted after about 900 seconds, which is a much shorter-term thermal stratification than the experimental data indicates. This discrepancy may be due to the shortcoming of the turbulence models available in the CFX-13 code for a natural convection flow with thermal stratification.

• Journal of Mechanical Science and Technology
• /
• 제18권9호
• /
• pp.1500-1511
• /
• 2004

In this paper, the anti-plane transient response of a central crack normal to the interface between a piezoelectric ceramics and two same elastic materials is considered. The assumed crack surfaces are permeable. By virtue of integral transform methods, the electro elastic mixed boundary problems are formulated as two set of dual integral equations, which, in turn, are reduced to a Fredholm integral equation of the second kind in the Laplace transform domain. Time domain solutions are obtained by inverting Laplace domain solutions using a numerical scheme. Numerical values on the quasi-static stress intensity factor and the dynamic energy release rate are presented to show the dependences upon the geometry, material combination, electromechanical coupling coefficient and electric field.

• 오토저널
• /
• 제15권3호
• /
• pp.111-119
• /
• 1993

In this study, the transient impact structural stress analysis of tracked vehicle structures under recoil impact load is investigated. ANSYS, ABAQUS Code are used for modelling and analytical procedures. The highest maximum Tresca stress occurs on race ring portion and its stress level is (.sigma.$_{T}$)$_{max}$ =20-40kgf/m $m^{2}$. The second highest stress occurs on upper plate of chassis and down plate of turret. The maximum stress level increases with loading direction and elevation angle. The results from liner static load analysis are very much different with impact analysis. Therefore, the practical solutions of structures under impact load can be obtained by only nonlinear transient impact analysis. The impact stress analysis of the steel vehicle structures is conducted. The maximum stress level is less than (.sigma.$_T/)$_{max}$m $m^{2}$. So, the design concept of steel structures can be adapted for new alternatives.s.s.s..s.

• Interaction and multiscale mechanics
• /
• 제6권1호
• /
• pp.15-29
• /
• 2013

Phononic system composed of periodical elastic structures exhibit band gap phenomenon, and all elastic wave cannot propagate within the band gap. In this article, we consider one-dimensional binary materials which are periodically arranged as a 20-layered medium instead of infinite layered system for phononic system. The layered medium with finite dimension is subjected to a uniformly distributed sinusoidal loading at the upper surface, and the bottom surface is assumed to be traction free. The transient wave propagation in the 20-layered medium is analyzed by Laplace transform technique. The analytical solutions are presented in the transform domain and the numerical Laplace inversion (Durbin's formula) is performed to obtain the transient response in time domain. The numerical results show that when a sinusoidal loading with a specific frequency within band gap is applied, stress response will be significantly decayed if the receiver is away from the source. However, when a sinusoidal force with frequency is out of band gap, the attenuation of the stress response is not obvious as that in the band gap.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2001년도 하계학술대회 논문집 A
• /
• pp.10-12
• /
• 2001

This paper presents a study of transient overvoltages caused by capacitor switching on the utility distribution system. Capacitor banks used for power factor correction and voltage regulation can improve efficiency of the power system. But transient voltages due to capacitor switching on the utility system affect the sensitive customer load equipments. If Distributed Generation System (DGS) is involved in the system, the problems become more serious. In this paper, effect of transient voltages at the customer load created by utility capacitor switching is analyzed by simulations Solutions to this problem are presented.

• 대한기계학회논문집B
• /
• 제30권1호
• /
• pp.67-73
• /
• 2006

This investigation deals with the spin-up flows in a circular container of aspect ratio, 2.0. Shear front is generated in the transient spin-up process and propagating from the side wall to the central axis in a rotating container. Propagation of the shear front to the axis in a rotating container means the region acquires an angular momentum transfer from the solid walls. Propagating speed of the shear front depends on the apparent viscosity of polymer solution. Two kinds of polymer solutions are considered as a working fluid: one is CMC and the other is CTAB solution. CMC solution has larger apparent viscosity than that of water, and CTAB shows varying apparent viscosities depending on the applied shear rates. Transient and spatial variations of the apparent viscosities of the present polymer solutions (CTAB and CMC) cause different speeds of the propagating shear front. In practice, CMC solution that has larger values of apparent viscosity than that of water always shows rapid approach to the steady state in comparison of the behavior of the flows with water. However, for the CTAB solution, the speed of the propagating of the shear front changes with the local magnitude of its apparent viscosity. Consequently, the prediction of Wedemeyer's model quantitatively agrees with the present experimental results.