• Title/Summary/Keyword: trace analysis

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Trace Element Analysis by Neutron Activastion Analysis in the Human Cancer Tissue (폐암조직에서 중성자 방사화 분석법을 이용한 미량 원소 분석)

  • Lim, Sang-Moo;Zo, Jae-Il;Shim, Young-Mog;Chung, Young-Ju;Cho, Seung-Yeon;Chung, Yong-Sam
    • The Korean Journal of Nuclear Medicine
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    • v.27 no.1
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    • pp.104-111
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    • 1993
  • Trace elements are important components in the biological system, as a structural material and metabolic controller. Neutron activation analysis (NAA) with high neutron flux and high energy resolution Ge (Li) detector coupled to multichannel analyzer (MCA) has been one of the most accurate method for the determination of ultra-trace level components, and is applicable to biological material. In human body, the NAA can be used for quantitation of trace elements in various organs and tissue with endocrinological and metabolic disease and industrial metal poisoning. In this study, Triga Mark III nuclear reactor in Korea Atomic Research Institute was used for quantitation of trace eleement in human lung cancer tissues by neutron activation analysis. In the squamous cell carcinoma tissues, Br, Hg, La, Sb, Sc, Cl, Fe and I content were lower than normal lung tissues, and K, Rb and Se content were higher. In the adenocarcinoma tissues, Fe, Au, La, Sc and Zn content were lower than normal lung tissues, and Rb, Co and Se content were higher. Rb content was higher in the adenocarcinoma tissues than in the squamous cell carcinoma tissues. Fe and Na content were higher in the squamous cell carcinoma tissues than in the adenocarcinoma tissues.

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ON DIFFERENTIABILITY OF THE MATRIX TRACE OPERATOR AND ITS APPLICATIONS

  • Dulov, E.V.;Andrianova, N.A.
    • Journal of applied mathematics & informatics
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    • v.8 no.1
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    • pp.97-109
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    • 2001
  • This article is devoted to “forgotten” and rarely used technique of matrix analysis, introduced in 60-70th and enhanced by authors. We will study the matrix trace operator and it’s differentiability. This idea generalizes the notion of scalar derivative for matrix computations. The list of the most common derivatives is given at the end of the article. Additionally we point out a close connection of this technique with a least square problem in it’s classical and generalized case.

Determination of trace impurities of HFC-134a by gas chromatograph with atomic emission detector (GC/AED) (GC/AED를 이용한 HFC-134a의 미량 불순물 분석)

  • Kim, Myeongja;Lim, Jeongsik;Lee, Jinbok;Lee, Jeongsoon
    • Analytical Science and Technology
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    • v.30 no.5
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    • pp.240-251
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    • 2017
  • 1,1,1,2-Tetrafluoroethane (HFC-134a), which is used as refrigerant in air conditioners, has been recently regulated as a greenhouse gas and is recommended for reuse by refining. It is very important to quantitatively analyze trace impurities present in the refrigerant to evaluate the criteria for reuse. In this study, trace impurities including C, H, Cl, and F, which are difficult to quantify because there are no reference materials, were quantitatively analyzed by a gas chromatograph-atomic emission detector (GC/AED); for this analysis, this was preceded by a qualitative analysis with a GC-mass selective detector (GC/MSD). In addition, the AED response was investigated using a hydrocarbon mixed reference material, which was proportional to the number of atoms in the component. Fifteen refrigerant components were detected as trace impurities in HFC-134a by qualitative analysis of trace impurities including C, H, Cl, and F in the samples. Based on the results of the qualitative analysis, quantitative analysis of trace impurities using AED showed that the highest mole fractions were for the $CHClF_2$ component ($45438.38{\mu}mol/mol$) in one sample and for the $C_2H_2ClF_3$ component ($1311.47{\mu}mol/mol$) in another sample. From this study, it has been shown that it is possible for this analytical method to be applied to the qualitative and quantitative analysis of trace compounds in refrigerants, which are difficult to quantify because of the absence of reference materials.

Analysis of Resonant Characteristics for a Metallic Shielding Enclosure with a PCB Source (PCB 파원이 내장된 금속 함체의 공진 특성 해석)

  • Cho, Byung-Doo;Kim, Ki-Chai
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.23 no.4
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    • pp.507-514
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    • 2012
  • This paper proposed the analysis method of the cavity resonance characteristics for a metallic enclosure with a PCB trace source. In order to calculation the electromagnetic fields inside the cavity, coupled integral equations for a current distribution on the PCB trace and an aperture electric field distribution on the boundary of the PCB dielectric are derived and solved by applying Galerkin's method of moments. The result show that the resonant characteristics of the metallic enclosure are fairly good agreement with the simulation(HFSS) and the measured results. The resonant frequencies of the metallic enclosure with the PCB trace are changed by the PCB trace location inside of the cavity. In order to check the validity of the theoretical analysis, the calculated return losses are compared with the measured results.

Comparative study of constitutive relations implemented in RELAP5 and TRACE - Part I: Methodology & wall friction

  • Shin, Sung Gil;Lee, Jeong Ik
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3526-3539
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    • 2022
  • Nuclear thermal-hydraulic system analysis codes have been developed to simulate nuclear reactor systems, which solve simplified governing equations by replacing source terms with constitutive relations for simulating entire reactor systems with low computational resources. For half a century, many efforts have been made for wider versatility and higher accuracy of system codes, but various factors can affect the code analysis results, and it was difficult to isolate these factors and interpret them individually. In this study, two system codes, RELAP5 and TRACE, which have many users and are highly reliable, are selected to analyze only the effects of constitutive relations. The influence of constitutive relations is analyzed using in-house platforms that replicate constitute relations of RELAP5 and TRACE equally to exclude factors that may affect analysis results, such as governing equation solvers and user effects. Among the various constitutive relations, the analysis is performed on the wall variables expected to have the most influence on the analysis results. Part 1 paper presents the methodology and wall friction model comparison, while Part 2 paper shows wall heat transfer comparison of the two selected codes.

Chemical Speciation of Trace Metals in Natural Water by Ultrafiltration/Size Exclusion Chromatography/UV Absorption/ICP-MS

  • Haraguchi, Hiroki;Itoh, Akihide;Kimata, Chisen
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.405-410
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    • 1995
  • A study on elemental speciation of trace metals in lake water (Lake Biwa in Japan) has been carried out by a size exclusion chromatography (SEC) / inductively coupled plasma mass spectrometry (ICP-MS) system. Before analysis, the water sample was preconcentrated with a ultrafiltration technique, where the large molecules with molecular weight larger than 10,000 were concentrated. Then the preconcentrated water samples (500-1000 fold) were analyzed by a SEC/ICP-MS system. Most trace metals were found at the UV absorption peaks corresponding to the molecular weights of ca. 300,000 and 10,000-50,000, where trace metals were on-line detected by ICP-MS. The results suggest that many of trace metals exist as the large organic molecules-metal complexes in natural water.

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Investigation of trace element contamination in steam sediments in the Chungnam coal mine area using geostatistical approach (지구 통계학적 방법에 의한 충남 탄전 지역 하상퇴적물의 미량원소 오염조사)

  • 황춘길
    • Economic and Environmental Geology
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    • v.32 no.1
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    • pp.63-72
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    • 1999
  • In order to examine the contamination levels of trace elements in stream sediments in the Chungnam coal mine area, stream sediment and water samples were collected and analyzed for trace elements. The pH of stream water was neutral or weak-alkaline and the mobility of metal in stream sediments was supposed to be low. From the result of cluster analysis, non-polluted sampling stations can be distinguished from polluted sampling stations influenced by mining activities. The trace element concentrations in sediments from non-polluted zone were considered to be the natural backround concentrations of this area. The trace element concentrations in sediment samples from the mining area were higher than those from non-polluted area, and contaminated area of enriched trace element levels need to be properly managed. From the results of discriminant and regression analyses, concentrations of Cd, Cu, Pb AND zN and predicted values of Be, Mo, and Ni in Chungnam coal mine area were found to be lower than those in metal mining areas in Korea.

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Simulation of the Operation of the Control Element Drive Mechanism (제어봉구동장치의 동작 시뮬레이션)

  • Kim, Hyun-Min;Kim, In-Yong;Kim, Il-Kon
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.468-473
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    • 2004
  • The magnetic jack type Control Element Drive Mechanism (CEDM) had been developed and verified through electromechanical testing including the testing of the magnetic force required to lift the control element assembly. It would become inefficient in view of cost and time for parametric studies to be performed by test to improve the CEDM system. So it becomes necessary to develop a computational model to simulate the electromagnetic characteristics of the CEDM in order to improve the CEDM design efficiently. In this paper it is presented that the electromagnetic analysis using a 2D axisymmetric FEM model has been carried out to simulate the operation of the latch magnet of the CEDM to generate a current trace for latch coil. The results show the calculated current trace is very similar to the real current trace taken from the CEDM.

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A Study on Trace Metal Contents in Rice, Soybean and Soils in the Vicinity of Ulsan Area (울산지역 주변의 토양 및 곡류(쌀,콩)중의 미량금속 함량에 관한 조사연구)

  • 김종욱;이용욱
    • Journal of Environmental Health Sciences
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    • v.22 no.2
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    • pp.69-82
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    • 1996
  • The samples for testing have been collected from Kangdong-myon, Nongso-myon, Beomseo-my on, and Cheongryang-myon in Ulju-Ku, Ulsan-city from July 1994 to March 1995 in order to grasp status of trace metals contained in some rice, soybean and soils, and to provide references in establishing their standard 96 collected samples(48 for cereals and 48 for soils) have been tested to measure levels of Hg, Pb, Cd, Cu, and Zn through methods of trace metal containing analysis and heavy metal analysis. moisture content was also analyzed. And at the same time 0.1N-HCl soluble heavy metal content of soil was measured. The average Hg containing level of samples is 0.006 ppm for cereal and 0.062 ppm for soil, Pb is 0.302 ppm for cereal and 1.137 ppm for soil, Cd is 0.012 ppm for cereal and 0.027 ppm for soil, Cu is 2.01 ppm for cereal and 0.885 ppm for soil, and Zn is 7.853 ppm for cereal and 2.366 ppm for soil.

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Walking load model for single footfall trace in three dimensions based on gait experiment

  • Peng, Yixin;Chen, Jun;Ding, Guo
    • Structural Engineering and Mechanics
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    • v.54 no.5
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    • pp.937-953
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    • 2015
  • This paper investigates the load model for single footfall trace of human walking. A large amount of single person walking load tests were conducted using the three-dimensional gait analysis system. Based on the experimental data, Fourier series functions were adopted to model single footfall trace in three directions, i.e. along walking direction, direction perpendicular to the walking path and vertical direction. Function parameters such as trace duration time, number of Fourier series orders, dynamic load factors (DLFs) and phase angles were determined from the experimental records. Stochastic models were then suggested by treating walking rates, duration time and DLFs as independent random variables, whose probability density functions were obtained from experimental data. Simulation procedures using the stochastic models are presented with examples. The simulated single footfall traces are similar to the experimental records.