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New Iron-Containing Electrode Materials for Lithium Secondary Batteries

  • Hong, Young-Sik;Ryu, Kwang-Sun;Chang, Soon-Ho
    • ETRI Journal
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    • v.25 no.5
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    • pp.412-417
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    • 2003
  • Using a galvanostatic charge/discharge cycler and cyclic voltammetry, we investigated for the first time the electrochemical properties of iron-containing minerals, such as chalcophanite, diadochite, schwertmannite, laihuite, and tinticite, as electrode materials for lithium secondary batteries. Lithium insertion into the mineral diadochite showed a first discharge capacity of about 126 mAh/g at an average voltage of 3.0 V vs. $Li/Li^+$, accompanied by a reversible capacity of 110 mAh/g at the 60th cycle. When the cutoff potential was down to 1.25 V, the iron was further reduced, giving rise to a new plateau at 1.3 V. Although the others showed discharge plateaus at low potentials of less than 1.6 V, these results give an important clue for the development of new electrode materials.

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Kinetic Theory for Chemical Reactions in Liquids (용액중에서의 화학반응에 관한 동역학적 이론)

  • Kook Joe Shin
    • Journal of the Korean Chemical Society
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    • v.25 no.5
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    • pp.291-299
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    • 1981
  • A test particle kinetic theory for reaction dynamics in liquids is presented at the repeated ring collision level for the hard sphere model. A kinetic equation for the equilibrium time correlation function of the reactive test particle phase space density is derived and the rate kernel expression for the reversible chemical reaction of the type A +B ${\rightleftharpoons$ C + D in the presence of inert solvent S is obtained by the projection operator method.

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Mechanochemical Synthesis of ZnMn2O4 and its Electrochemical Properties as an Anode Material for Lithium-ion Batteries

  • Park, Yoon-Soo;Oh, Hoon;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3333-3337
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    • 2011
  • $ZnMn_2O_4$ has been prepared by a mechanochemical process using a mixture of $Mn_2O_3$ and ZnO as starting materials, and investigated as a possible anode material for lithium-ion batteries. The phase evolution and morphologies of the ball-milled and annealed powders are characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive microanalysis (EDX), respectively. The solid-state reaction for the formation of $ZnMn_2O_4$, under the given experimental conditions, is achieved in a short time (30 min), and the prepared samples exhibit excellent electrochemical performances including an enhanced initial coulombic efficiency, high reversible capacity, and stable capacity retention with cycling.

Electrochemical Characteristics of Si/Mo Multilayer Anode for Lithium-Ion Batteries (리튬 이온 전지용 Si/Mo 다층박막 음극의 전기화학적 특성)

  • Park, Jong-Wan;Ascencio Jorge A.
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.297-301
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    • 2006
  • Si/Mo multilayer anode consisting of active/inactive material was prepared using rf/dc magnetron sputtering. Molybdenum acts as a buffer against the volume change of the Silicon. Multilayer deposited on RT (reversible treatment) copper foil current collector to enhance adhesion between Silicon and copper foil. Deposited Silicon was identified as an amorphous. Amorphous has a relatively open structure than crystal structure, thus prevents the lattice expansion and has many diffusion paths of Li ion. When deposited time of Silicon and Molybdenum is 30 second and 2 second respectably, electrode has more capacity and good cycle stability. A 3000 nm thick multilayer was maintained 99% of the initial capacity (1624 $mAhg^{-1}$) after 100 cycles. As the increase of the multilayer thickness (4500 nm, 6000 nm), Si/Mo mutilayer anodes show aggravation cycle stability.

Understanding the Conception of Stress regard in the Oriental Medicine (스트레스의 개념에 대한 한의학적 해석)

  • Ahn, Sang-Woo
    • Korean Journal of Oriental Medicine
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    • v.3 no.1
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    • pp.119-151
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    • 1997
  • Conclusions for the relationship between a conceptional model of stress theory and its examination based on the Oriental medicine; 1. It was considered that a general conception of stress is included into the meaning of Ki in the Oriental medicine. 2. The response-based model to stress could be comparable to a conception of Ki-pathogens interchange In the Onental medicine. 3. The stimulus-based model may be explained as a modern conception of immoderation feeling related with an internal etiological factor, specially injury of seven emotions, among three groups of etiological factors for disease. 4. The feedback conception based on the interaction model could explain the principal of reversible emotion therapy in the nine Ki. 5. In the Oriental medicine, a study to clarify a emotional etiologic factor and its pathophysiologlcal mechanism has been continued for long time before establishment of stress theory.

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Dynamic change of frequency after a generator outage in an Interconnection considering the primary control (연계계통에서 발전기 정지에 따른 주파수의 동적 변화)

  • Stanojevic, Vladimir;Moon, Y.H.;Yoon, J.Y.
    • Proceedings of the KIEE Conference
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    • 2001.05a
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    • pp.95-99
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    • 2001
  • Frequency is the unique physical value for all the interconnected systems. Therefore. the load frequency control is in the responsibility of all members in the interconnection power unbalance in one of the interconnected system can cause the problems in others. In the following text a brief description and the role of frequency in an interconnected system will be presented. Following is the short description of the Balkan Interconnection (UCTE Second Synchronous Zone) with schematic diagram. A Power-Frequency (P-f) dynamic model of a control area wil1 be shown. Model gives the analytical solution for frequency change versus a time after outage of a generator in the power system. This model will be applied to the Balkan Interconnection and compared with numerical approach. Advantages and drawbacks of the analytical method will be discussed Purpose of using this model is to investigate if the pumps in reversible hydropower plant will be underfrequency shed after the outage of the biggest generator unit in the interconnection, according %o (n-1) security postulate.

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The physical properties and switching characteristics of amorphous $Ge_2Sb_2Te_5$ thin film (비정질 $Ge_2Sb_2Te_5$ 박막의 물리적 성질 및 스위칭 특성)

  • Lee, Jae-Min;Yang, Sung-Jun;Shin, Kyung;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.268-271
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    • 2004
  • The phase transition from amorphous to crystalline states, and vice versa, of $Ge_2Sb_2Te_5$ films by applying electrical pulses have been studied. This material can be used as nonvolatile memory. The reversible phase transition between the amorphous and crystalline states, which is accompanied by a considerable change in electrical resistivity, is exploited as means to store bits of information. The nonvolatile memory cells are composed of a simple sandwich (metal/chalcogenide/metal). It was formed that the threshold voltage depends on thickness, electrode distance, annealing time and temperature, respectively.

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Abnormal behaviors in electrical conductions of SOI substrate by thermal annealing temperature (열처리에 따른 SOI 기판에서의 전기전도특성의 이상 거동)

  • Cho, Won-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.126-127
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    • 2008
  • The effects annealing conditions on the electrical conductions of SOI substrate were studied. The reversible change of resistance and carrier concentration in accordance with the annealing temperature were observed for the first time in SOI substrate. The thermal donors due to interstitial oxygen atoms contribute the change of resistance and carrier concentration. Final1y, we show that the furnace annelaing at $500^{\circ}C$ at final heat treatment stage is effective for eliminate the thermal donor effects in SOI substrate.

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Small Molecular Organic Nonvolatile Memory Cells Fabricated with in Situ O2 Plasma Oxidation

  • Seo, Sung-Ho;Nam, Woo-Sik;Park, Jea-Gun
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.8 no.1
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    • pp.40-45
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    • 2008
  • We developed small molecular organic nonvolatile $4F^2$ memory cells using metal layer evaporation followed by $O_2$ plasma oxidation. Our memory cells sandwich an upper ${\alpha}$-NPD layer, Al nanocrystals surrounded by $Al_2O_3$, and a bottom ${\alpha}$-NPD layer between top and bottom electrodes. Their nonvolatile memory characteristics are excellent: the $V_{th},\;V_p$ (program), $V_e$ (erase), memory margin ($I_{on}/I_{off}$), data retention time, and erase and program endurance were 2.6 V, 5.3 V, 8.5 V, ${\approx}1.5{\times}10^2,\;1{\times}10^5s$, and $1{\times}10^3$ cycles, respectively. They also demonstrated symmetrical current versus voltage characteristics and a reversible erase and program process, indicating potential for terabit-level nonvolatile memory.

An Experimental Study on the Vibrating Characteristics in Conveyor using the Linear Motor (수평가진식 진동 컨베이어의 진동특성에 관한 실험적 연구)

  • 윤영식;박철우
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.820-823
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    • 2003
  • Recently, the linear motors have been widely used in the industry, owing to various advantages in comparison with conventional feed mechanism; high speed, high acceleration and high stiffness. In addition, the linear motors have the merits of a good velocity control, reversible movement and long lifetime. For the application of the linear motors to vibrating conveyor, the study of vibrating characteristics is required. In this paper, we developed the linear vibrating conveyor using the linear motor that has the 410N thrust and the 7.2m/min maximum moving velocity. To accomplish this system, we had some experiments that included the influence of deceleration time, vibrating amplitude and additional weight.

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