• Title/Summary/Keyword: three-electrode system

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Production of Hydrogen from Methane by 3phase AC GlidArc Plasma (3상 교류 부채꼴 방전을 이용한 메탄으로부터 수소 생산)

  • Chun, Young-Nam;Kim, Seong-Cheon;Lim, Mun-Seup
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2232-2237
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    • 2007
  • Steam reforming and catalytic reforming of $CH_4$ conversion to produce synthesis gas require both high temperatures and high pressure. Non-thermal plasma is considered to be a promising technology for the hydrogen rich gas production from methane. In this study, three phase AC GlidArc plasma system was employed to investigate the effects of gas composition, gas flow rate, catalyst reactor temperature and applied electric power on the $CH_4$ and $H_2$ yield and the product distribution. The studied system consisted of three electrode and it connected AC generate power system different voltages. In this study, air was used for the partial oxidation of methane. The results showed that increasing gas flow rate, catalyst reactor temperature, or electric power enhanced $CH_4$ conversion and $H_2$ concentration. The reference conditions were found at a $O_2$/C molar ratio of 0.45, a feed flow rate of 4.9 ${\ell}$/min, and input power of 1kW for the maximum conversions of $CH_4$ with a high selectivity of $H_2$ and a low reactor energy density.

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Study on Automatic Mixing of Nutrient Solution Using ion Electrodes for Closed-Loop Hydroponics (이온전극을 이용한 순환식 양액 자동 조제에 관한 연구)

  • 김민규;류관희;장유섭;김기영
    • Journal of Biosystems Engineering
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    • v.27 no.5
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    • pp.425-432
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    • 2002
  • This study was carried out to develop an automatic mixing system of nutrient solution for closed-loop hydroponics using ion electrodes. The results of the study are summarized as follows: 1. It appeared that ion-electrodes had not to be soaked into nutrient solution for a long time since it was much less durable than EC or PH sensors. Once ion-electrodes were soaked into real nutrient solution for a long time, they became unstable. 2. ion measurement modules, which were able to sample recirculated nutrient solution and easily wash and dry ion-electrodes, were developed in order to use ion-electrodes continuously. 3. The results of calibration tests on three kinds of ion electrodes presented that the time required to read measurement data was over 30 seconds. Using the calibration data the regression equations for the ion electrodes were developed. 4. An automatic nutrient-solution mixing system using the three kinds of ion electrodes was developed and then its accuracy was examined. The control errors of the mixing system using ion electrodes were in the range of 9.8 to 12%.

DENTAL ELECTRONIC ANESTHESIA IN CHILDREN : A CASE REPORT (소아에서의 치과전기마취 : 증례보고)

  • Lee, Eun-Young;Lee, Chang-Seop;Lee, Sang-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.21 no.2
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    • pp.525-532
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    • 1994
  • The purpose of this report was to evaluate the effect of Dental Electronic Anesthesia on pain inhibition for clinical use. The subject for this study were 30 children whose Frankl behavioral rate is positive. The subjects was divided into two groups, the first group described by control group and the second group described by experimental group anesthetized with Dental Electronic Anesthetic device. And then three kind of treatments were done : extraction of deciduous teeth, application of rubber dam, cavity preparation for preventive resin restoration. 3M Dental Electronic Anesthesia System was used for this study : its electric impulse stimulate the skin surface by external electrode pads. The results were as follows. 1. Degree of the pain & the apprehension decreased in experimental group. 2. Degree of the pain & the apprehension showed statistical differences among three treatments procedures in the control group but, not showed statistical differences in the experimental group.

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Characteristics of Surface Flashover of spacer in Liquid Nitrogen (액체 질소중에서 고체 Spacer에 의한 연면 방전특성)

  • Kim, Y.S.;Back, S.M.;Lee, B.S.;Jang, H.M.;Kim, S.H.
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.912-914
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    • 1999
  • Composite insulation system of liquid nitrogen and solid spacer is widely applied in high temperature superconducting power machine. This study has three step procedure. As follow, first step is composition of parallel deposited electrode and vertically deposited electrode along the direction of immersion in liquid nitrogen($LN_2$). Second step is investigation into surface flashover voltage of solid spacer under partially immersed in $LN_2$, and last step is comparison the result of this research with that of fully immersed in $LN_2$ and at cryogenic temperature gaseous nitrogen($GN_2$). This result presented that surface flashover voltage along solid spacer half immersed in $LN_2$ was almost the same as that of fully immersed spacer when the thickness of spacer(t) was t<10 mm. In the case of t>10 mm, however, spacer flashover voltage was equal to that obtained in $GN_2$ at cryogenic temperature.

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Highly Durable Pt catalyst Supported on the Hybrid Carbon Materials for Polymer Electrolyte Membrane Fuel Cell (탄소계 복합담지체에 담지된 고내구성 고분자전해질 연료전지용 백금촉매)

  • Park, Hyang Jin;Hur, Seung Hyun
    • Journal of the Korean Electrochemical Society
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    • v.17 no.3
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    • pp.201-208
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    • 2014
  • A Pt catalyst ($Pt/G_xC_y$) supported on the hybrid supporting materials composed of graphene oxide (GO) and carbon black (C) was fabricated using polyol method to improve the durability of electrocatalysts. The electrochemical performances measured by cyclic voltammograms using three-electrode system revealed that the properly designed $Pt/G_xC_y$ catalyst exhibited higher durability than that of Pt/C catalyst without sacrificing an electrocatalytic acivity. In the oxygen reduction reaction (ORR) performed in acid solution with the rotating disk electrode, the $Pt/G_xC_y$ catalyst showed greater mass and area-specific activity than those of Pt/C catalyst.

The Measurement of Three-Dimensional Temporal Behavior According to the Pressure in the Plasma Display Panel (플라즈마 디스플레이 패널에서 압력에 3차원 시간 분해 측정)

  • 최훈영;이석현;이승걸
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.10
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    • pp.476-480
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    • 2003
  • In this paper, we have performed 3-dimensional time-resolving measurement of the Ne light emitted from the cell of plasma display panel(PDP) as a function of the pressure using the scanned point detecting system. From the temporal behavior results, we could analyze the discharge behavior of panel with Ne-Xe(4%) mixing gas and 300 torr, 400 torr and 500 torr pressure. At the top view of panel, the discharge of 300 torr panel starts at the 634 ns and ends at the 722 ns. The emission duration time is about 90 ns. The discharge of 400 torr panel starts at the 682 ns and ends at the 786 ns. the emission duration time is about 100 ns. Also, the discharge of 500 torr panel starts at the 770 ns and ends at the 826 ns. the emission duration time is about 56 ns. The discharge moves from inner edge of cathode electrode to outer cathode electrode forming arc type. In the side view of 300 torr, 400 torr and 500 torr an emission shows that the light is detected up to 180${\mu}{\textrm}{m}$, 150${\mu}{\textrm}{m}$ and 70${\mu}{\textrm}{m}$ height of barrier rib and the emission distribution of the 300 torr is wider than 400 torr, 500 torr.

Positional correction of a 3D position-sensitive virtual Frisch-grid CZT detector for gamma spectroscopy and imaging based on a theoretical assumption

  • Younghak Kim ;Kichang Shin ;Aleksey Bolotnikov;Wonho Lee
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1718-1733
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    • 2023
  • The virtual Frisch-grid method for room-temperature radiation detectors has been widely used because of its simplicity and high performance. Recently, side electrodes were separately attached to each surface of the detectors instead of covering the entire detector surface with a single electrode. The side-electrode structure enables the measurement of the three-dimensional (3D) gamma-ray interaction in the detector. The positional information of the interaction can then be utilized to precisely calibrate the response of the detector for gamma-ray spectroscopy and imaging. In this study, we developed a 3D position-sensitive 5 × 5 × 12 mm3 cadmium-zinc-telluride (CZT) detector and applied a flattening method to correct detector responses. Collimated gamma-rays incident on the surface of the detector were scanned to evaluate the positional accuracy of the detection system. Positional distributions of the radiation interactions with the detector were imaged for quantitative and qualitative evaluation. The energy spectra of various radioisotopes were measured and improved by the detector response calibration according to the calculated positional information. The energy spectra ranged from 59.5 keV (emitted by 241Am) to 1332 keV (emitted by 60Co). The best energy resolution was 1.06% at 662 keV when the CZT detector was voxelized to 20 × 20 × 10.

Development of PC-based and portable high speed impedance analyzer for biosensor (바이오센서를 위한 PC 기반의 휴대용 고속 임피던스 분석기 개발)

  • Kim, Gi-Ryon;Kim, Gwang-Nyeon;Heo, Seung-Deok;Lee, Seung-Hoon;Choi, Byeong-Cheol;Kim, Cheol-Han;Jeon, Gye-Rok;Jung, Dong-Keun
    • Journal of Sensor Science and Technology
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    • v.14 no.1
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    • pp.33-41
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    • 2005
  • For more convenient electrode-electrolyte interface impedance analysis in biosensor, a stand-alone impedance measurement system is required. In our study, we developed a PC-based portable system to analyze impedance of the electrochemical cell using microprocessor. The devised system consists of signal generator, programmable amplifiers, A/D converter, low pass filter, potentiostat, I/V converter, microprocessor, and PC interface. As a microprocessor, PIC16F877 which has the processing speed of 5 MIPS was used. For data acquisition, the sampling rate at 40 k samples/sec, resolution of 12 bit is used. RS-232 with 115.2 kbps speed is used for the PC communication. The square wave was used as stimuli signal for impedance analysis and voltage-controlled current measurement method of three-electrode-method were adopted. Acquired voltage and current data are calculated to multifrequency impedance signal after Fourier transform. To evaluate the implemented system, we set up the dummy cell as equivalent circuit of which was composed of resistor, parallel circuit of capacitor and resistor connected in parallel and measured the impedance of the dummy cell; the result showed that there exist accuracy within 5 % errors and reproduction within 1 % errors compared to output of Hioki LCR tester and HP impedance analyzer as a standard product. These results imply that it is possible to analyze electrode-electrolyte interface impedance quantitatively in biosensor and to implement the more portable high speed impedance analysis system compared to existing systems.

Development of High-performance Supercapacitors Based on MnO2/Functionalized Graphene Nanocomposites (망간산화물/기능화된 그래핀 나노복합체에 기반한 고성능 슈퍼커패시터 개발)

  • Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.439-443
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    • 2016
  • In this report, $MnO_2$ nanoparticle-deposited functionalized graphene sheets were prepared and their superior electrochemical performances were demonstrated by cyclic voltammetry, galvanostatic charge-discharge, and impedance analysis. Ionic liquids were employed to functionalize the surface of reduced graphene oxides (RGOs), leading to prevention of the aggregation of RGO sheets and abundant growth sites for deposition of $MnO_2$ nanoparticles. As-prepared $MnO_2/RGO$ nanocomposites were characterized using scanning electron microscope, transition electron microscope, X-ray photoelectron spectroscopy, and X-ray diffraction. Electrochemical properties of $MnO_2/RGO$ electrode were evaluated using $Na_2SO_4$ electrolyte under a three-electrode system. The $MnO_2/RGO$ electrode showed a high specific capacitance (251 F/g), a high rate capability (80.5% retention), and long-term stability (93.6% retention).

Synthesis, chemically and electrochemically polymerization of N-substituted pyrrole containing azo chromophore and its copolymerization with pyrrole

  • Hosseini, Seyed Hossein
    • Advances in materials Research
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    • v.1 no.4
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    • pp.299-310
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    • 2012
  • This article describes the synthesis of a novel N-substituted pyrrole monomer containing an azobenzene group. The 2-[N-ethyl-N-[4-[(4-nitrophenyl) azo]-phenyl] amino] ethyl-3-chloropropionate (RedII) compound was synthesized via reaction of 4-nitro-4'-[N-ethyl-N-(2-hydroxyethyl)-amino] azobenzene (RedI) and 3-chloropropionic acid. RedII was reacted with the potassium salt of pyrrole then 2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate (Py-RedII) was prepared. Chemical polymerization of Py-RedII and copolymerization of Py-RedII with pyrrole carried out using $FeCl_3$. Poly (2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate) (PPy-RedII) was characterized by UV, IR, $^1HNMR$, $^{13}CNMR$ spectroscopies. Electropolymerization of Py-RedII and electroco-polymerization of Py-RedII and pyrrole were studied using conventional three electrodes system, Ag/AgCl reference electrode, platinum counter electrode and GC disk working electrode. Scanning electron microscopy (SEM), thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC) were used for thermal and rheological studies. The TGA curve of PPy-RedII demonstrated a high thermal stability up to 200°C and its DSC thermogram showed two endothermic peaks at 88 and $122^{\circ}C$. The glass transition temperature of the polymer was found to be above the room temperature. Electrical conductivities of PPy-RedII and it's copolymer with pyrrole (PPy-RedII-co-Py) were studied by the four-probe method and produced conductivities of $7.5{\times}10^{-4}$ and $6.5{\times}10^{-3}Scm^{-1}$, respectively.