• Title/Summary/Keyword: three-electrode cell

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Experimental Validation of a Direct Methanol Fuel Cells(DMFCs) model with a Operating Temperatures and Methanol Feed Concentrations (직접메탄올 연료전지의 농도 및 온도변화에 따른 실험적 검증)

  • Kang, Kyungmun;Ko, Johan;Lee, Giyong;Ju, Hyunchul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.125.2-125.2
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    • 2010
  • In this paper, both theoretical and experimental investigations have been performed to examine the effects of key operating parameters on the cell performance of a DMFCs (i.e., methanol feed concentration and operating temperature). For experiment, the membrane electrode assemblies (MEAs) were prepared using a conventional MEA fabrication method based on a catalyst coated electrode (CCE) and tested under various cell temperatures and methanol feed concentrations. The polarization curve measurements were conducted using in-house-made $25cm^2$ MEAs. The voltage-current density data were collected under three different cell temperatures ($50^{\circ}C$, $60^{\circ}C$, and $70^{\circ}C$) and four different methanol feed concentrations (1 M, 2 M, 3 M, and 4 M). The experimental data indicate that the measured I-V curves are significantly altered, depending on these conditions. On the other hand, previously developed one-dimensional, two-phase DMFC model is simulated under the same operating conditions used in the experiments. The model predictions compare well with the experimental data over a wide range of these operating conditions, which demonstrates the validity and accuracy of the present DMFC model. Furthermore, both simulation and experimental results exhibit the strong influences of methanol and water crossover rates through the membrane on DMFC performance and I-V curve characteristics.

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Electrode Surface Analysis of Delithiated $LiCoO_2$ using Ion Chromatograph (이온 크로마토그래피를 이용한 충전전압에 따른 $LiCoO_2$ 전극의 표면 특성)

  • Kim, Dong-Hun;Shin, Hye-Min;Chung, Young-Dong;Veluchamy, A.;Doh, Chil-Hoon;Jin, Bong-Soo;Moon, Seong-In;Kim, Hyun-Soo;Oh, Dae-Hui;Kim, Ki-Won
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.498-499
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    • 2007
  • In this paper, we report on a study of the electrode/electrolyte interfaces of MCMB/$LiCoO_2$ cell using Ion-chromatography. The cells for the experiments were preconditioned by cycling three times and stabilized at OCV of 3.0V 4.35V and 4.5V. The stabilized cathode electrode was used for surface characterization investigations. Concerning the $LiCoO_2$/electrolyte interfaces, the result obtained have shown the presence of $F^-\;and\;CO_3^{2-}$ on the surface of cathode electrode as well as increasing the concentration of ions as cell voltage increase.

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Electrochemical Detection of Pesticide in Living Plant and Fish Brain Cell

  • Lee, Chang-Hyun;Ly, Suw-Young
    • Journal of Environmental Science International
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    • v.19 no.8
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    • pp.941-949
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    • 2010
  • The three electrode system was used to detect the pesticide fenitrothion ($C_9H_{12}NO_5PS$. MW=277.24) using cyclic voltammetry (CV) and square wave anodic stripping voltammetry (SWASV). The working electrode was mercury immobilized on a carbon nanotube paste electrode (Hg-CNTPE). At the optimized condition, the limit of detection (LoD) was 0.6 ppt ($2.16{\times}10^{-12}\;M$), and the relative standard deviation was 0.035% (n=15). And there is more sensitive in detecting fenitrothion than common type carbon nanotube paste electrode. When it was implanted into the brain of live fish (carp), the existence of fenitrothion was measured without any destruction or damage of tissue.

Preparation of WO3 by using sol-gel method for photoelectrode and its application for PEC cell (물분해로부터 수소 제조를 위한 광촉매용 텅스텐 산화물 박막 제조)

  • Hong, Eun-Mi;Im, Dong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.101-101
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    • 2015
  • Photoelectrochemical water splitting is considered as a promising method of transforming solar energy into chemical energy stored in the type of hydrogen. An n-type $WO_3$ semiconductor is one of the most promising photoanodes for hydrogen production from water splitting. Films annealed at lower temperatures consisted of amorphous, whereas films annealed above $500^{\circ}C$ comprised solely of monoclinic $WO_3$. In this study, we observed photoactivity of $WO_3$ as increasing thickness of $WO_3$. And it shows good photoacivity as thickness increases. Also we tried to improve photoactivity through surface modification and bulk modification by using hydrogen treatment and conducting polymer. The photocurrent was measured in potentiostatic method with the three electrode system. A Pt wire and Ag / AgCl electrode were used as the counter electrode and the reference electrode, respectively. photocurrent-time (I-T) curve was measured at a bias potential of 0.79 V.

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Suggestion of Multi-Electrode Type Electronic Paper Film to Can be Used as a Transparent Display (투명 디스플레이로써 활용 가능한 다수전극형 전자종이 필름 제안)

  • Lee, Sang-il;Hong, Youn-Chan;Kim, Young-cho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.4
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    • pp.296-301
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    • 2019
  • A multiple-electrode-type electronic paper film can implement a single color and control the transparency, as it has multiple electrodes in one cell. Therefore, it can be used as a transparent display. In this paper, we explain the structure and driving method of a transparent electronic paper display, and then propose a control method of transmittance. Subsequently, we verify the theory by measuring the transmittance via experiment. Thus, by changing the manner of applying the voltage to three lower electrodes and one upper electrode, transmittance in eight cases could be realized. It was confirmed that the transmittance derived from the experiment could be controlled from a minimum of 6.75% to a maximum of 71.18%.

Effect of Total Resistance of Electrochemical Cell on Electrochemical Impedance of Reinforced Concrete Using a Three-Electrode System (3전극방식을 활용한 철근 콘크리트의 교류임피던스 측정 시 전기화학 셀저항의 영향)

  • Khan, Md. Al-Masrur;Kim, Je-Kyoung;Yee, Jurng-Jae;Kee, Seong-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.82-92
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    • 2022
  • This study aims to investigate the effect of total electrochemical cell resistance (TECR) on electrochemical impedance (EI) measurements of reinforced concrete (RC) by electrochemical impedance spectroscopy (EIS) using a three-electrode system. A series of experimental study is performed to measure electrochemical behavior of a steel bar embedded in a concrete cube specimen, with a side length of 200 mm, in various experimental conditions. Main variables include concrete dry conditions, coupling resistance between sensing electrodes and concrete surface, and area of the counter electrode. It is demonstrated that EI values remains stable when the compliant voltage of a measuring device is sufficiently great compared to the potential drop caused by TECR of concrete specimens. It is confirmed that the effect of the coupling resistance of TECR is far more influential than other two factors (concrete dry conditions and area of the counter electrode). The results in this study can be used as a fundamental basis for development of a surface-mount sensor for corrosion monitoring of reinforced concrete structures exposed to wet-and-dry cycles under marine environment.

The effect of the cell size on the discharge characteristics of a plasma display panel

  • Moon, Cheol-Hee
    • Journal of Information Display
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    • v.12 no.1
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    • pp.29-35
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    • 2011
  • In this study, plasma display panels with three different cell volumes were prepared by changing the spaces between the vertical barrier ribs into two and three times the reference structure. The discharge gap and area of the segmented ITO electrode were the same for the three cases, and Ne.20%Xe gas was used. The luminance and luminance efficiency were measured using applied voltage variations. The time evolution and intensity distribution of the infrared, which are related to the vacuum ultraviolet, were observed via intensified, charged, coupled device, and the visible-light intensity profiles were observed using PR-900 to analyze the discharge phenomena in the discharge cell.

Fabrication and Characteristics of Supported Type Planar Solid Oxide Fuel Cell By Co-firing Process (공소결법에 의해 제조된 지지체식 평판형 고체산화물 연료전지 성능 특성)

  • Song, Rak-Hyun
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.160-168
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    • 2003
  • The co-firing processes for the supported type planar solid oxide fuel cell were investigated. A flat cell of $7.7${\times}$10.8\textrm{cm}^2$ was fabricated successfully by the co-firing process, in which green films were co-sintered in the forms of two layers of anode/electrolyte or of three layers of anode/electrolyte/cathode with gas distributor. A co-fired cell of two layers yielded a power of 200 ㎽/$\textrm{cm}^2$ at 608 ㎷. Its performance loss was mainly due to iR drop in the anodic gas distributor, which was attributed to poor contact between anodic gas distributor and current collector. The performance in the co-fired cell of three layers was much lower than that of two layers, which resulted from the large iR drop and activation overvoltage at the cathodic side. In the co-fired cell of two layers, the impedance analysis indicated that the performance decay during cell operation is due to both anode overvoltage and iR drop at anode side. Also the electrode reaction of the co-fired two layers' cell is considered to be controlled by activation overvoltage within the low current of 50 ㎃.

New PDP cell designs for high luminous efficiency and radiation transport model in PDP

  • Yang, Sung-Soo;Shin, Seung-Won;Kim, Hyun-Chul;Lee, Jae-Koo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.590-593
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    • 2002
  • Using two- and three-dimensional fluid simulation codes, we have suggested several new plasma display panel (PDP) cell structures that have high luminous efficiency compared with conventional structure. To improve the luminance and discharge efficiency, we utilize long discharge path, lower electric field region, and reduction of power consumption by adding one auxiliary electrode or reducing the electrode area. Consequently, luminous efficiency increases about 1.8 times. Furthermore for the resonance radiation trapping effect in PDP system, we have described a self-consistent radiation transport model coupled with fluid simulation using modified Holstein's equation.

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Analysis of the luminous efficacy improvement in Full HD ac Plasma Display Panel

  • Bae, Hyun-Sook;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.29-32
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    • 2007
  • We analyzed the effect of cell resolution on the luminous efficacy through three-dimensional numerical simulation to understand the inherent discharge mechanism change in the plasma display panel. As the resolution increases from VGA to Full HD, the luminous efficacy decreases. With higher Xe content, VUV generation efficacy of Full HD becomes much lower than those of VGA or XGA cells, due to the increased plasma loss and lower electron heating. However a long electrode gap $140{\mu}m$ in Full HD cell with Ne-Xe [20%] results in the high luminous efficacy comparable to that of the XGA cell with $60{\mu}m$ gap. When comparing the effects of Xe content variation on the luminous efficacy of two different subpixel types, i. e., SDE (Segmented electrode in Delta color arrayed, Enclosed subpixel) [1] and conventional stripe barrier type in the XGA and Full HD cells, the luminous efficacy of SDE structure shows higher improvement in Full HD resolution compared with that of conventional type XGA cell, whose cause is identified as the reduced plasma loss.

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