• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.421-425
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• 2009

A study has been performed to investigate the thermo-mechanical effects of thermal barrier coating on liquid rocket regenerative cooling chamber using finite element analysis. Two kinds of thermal barrier coatings were studied on the same loading condition: first, NiCrAlY-$ZrO_2$, coating which is currently applied to the developing combustion chamber and second, Ni-Cr coating which might be applied in the future. Analysis results showed that NiCrAlY-$ZrO_2$ coating has better decreasing effect of temperature than the Ni-Cr coating. As a results, temperature and deformation of the cooling channel in the NiCrAlY-$ZrO_2$ coating were also less than those of the Ni-Cr coating. The Ni-Cr coating has no effect on a structural stability of the outer jacket but the NiCrAlY-$ZrO_2$ coating reduced the effective stress of the outer jacket and enhanced the structural stability of the chamber.

• Tunnel and Underground Space
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• v.33 no.1
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• pp.10-28
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• 2023

Long-term shear behavior of the rock discontinuities should be analyzed and its stability should be evaluated to ensure the long-term stability of a high-level radioactive waste disposal repository. The long-term shear behavior of the discontinuities can be modeled with creep and RSF models. The shear creep test, velocity step test, and slide-hold-slide test can be performed to determine their model parameters or analyze the shear behavior by experiments under various conditions. Testing apparatuses for direct shear, triaxial compression, and biaxial shear were mainly used and improved to reproduce the thermo-hydro-mechanical conditions of local bedrock, and it was confirmed that the shear behavior could vary. In order to design a high-level radioactive waste disposal site in Korea, the long-term behavior of rock discontinuities should be investigated in consideration of rock types, thermo-hydro-mechanical conditions, metamorphism, and restoration of shear resistance.

• Fire Science and Engineering
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• v.18 no.3
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• pp.45-50
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• 2004

Thermal degradation of PVC which used for insulator of 600V vinyl insulated wire has been studied by thermo gravimetry analysis and accelerated thermal aging test. The activation energy using thermo gravimetry analysis was determined by the kinetic methods, such as Kissinger and Flynn-Wall-Ozawa. The activation energy was determined to from 89.29 kJ/mol to 111.39 kJ/mol in 600V PVC insulated wire and from 97.80 kJ/mol to 119.25 kJ/mol in 600v heat-resistant PVC insulated wire. And also, the activation energy through a long-term thermal aging test was calculated by using Arrhenius equation In the low temperature of 8$0^{\circ}C$, 9$0^{\circ}C$, 10$0^{\circ}C$. The results showed that 600V PVC insulated wire was 92.16 kJ/mol, and 600v heat-resistant PVC insulated wire was 97.52 kJ/mol. Consequently, the activation energy of 600V heat-resistant PVC insulated wire is larger than 600V PVC insulated wire. Therefore, it can be predicted that 600V heat-resistant PVC insulated wire has a long-term stability relatively.

• Journal of Powder Materials
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• v.22 no.6
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• pp.420-425
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• 2015

Rare-earth zirconates, such as lanthanum zirconates and gadolinium zirconates, have been intensively investigated due to their excellent properties of low thermal conductivity as well as chemical stability at high temperature, which can make these materials ones of the most promising candidates for next-generation thermal barrier coating applications. In this study, three compositions, lanthanum/gadolinium zirconates with reduced rare-earth contents from stoichiometric $RE_2Zr_2O_7$ compositions, are fabricated via solid state reaction as well as sintering at $1600^{\circ}C$ for 4 hrs. The phase formation, microstructure, and thermo-physical properties of three oxide ceramics are examined. In particular, each oxide ceramics exhibits composite structures between pyrochlore and fluorite phases. The potential of lanthanum/gadolinium zirconate ceramics for TBC applications is also discussed.

• Journal of Powder Materials
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• v.17 no.2
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• pp.148-153
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• 2010

Thermal barrier systems have been widely investigated over the past decades, in order to enhance reliability and efficiency of gas turbines at higher temperatures. Yttria-stabilized zirconia (YSZ) is one of the most leading materials as the thermal barriers due to its low thermal conductivity, thermodynamic stability, and thermal compatibility with metal substrates. In this work, rare-earth oxides with pyrochlore phases for thermal barrier systems were investigated. Pyrochlore phases were successfully formed via solid-state reactions started from rare-earth oxide powders. For the heat-treated samples, thermo-physical properties were examined. These rare-oxide oxides showed thermal expansion of $9{\sim}12{\times}10^{-6}/K$ and thermal conductivity of 1.2~2.4 W/mK, which is comparable with the thermal properties of YSZ.

• The Research Journal of the Costume Culture
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• v.25 no.6
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• pp.880-892
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• 2017

In this study, the appearance change and the heat moisture transfer properties of knitted fabric by yarn shrinkage were examined to obtain useful data on the development of thermo-sensitive functional materials. Eleven types of knitted fabric were knitted using highly bulky acrylic-blended yarn. After shrinking the specimens using dry heat treatment, the appearance change and thickness were measured. An HEC simulator was adopted for measuring the heat moisture transfer properties of specimens by yarn shrinkage. When holes were arranged vertically in the mesh structure, the specimens with 2,500 and 5,000 holes showed high percent change of hole area, appearance, and thickness. When holes were diagonally arranged in the mesh structure, the percent change of hole area in the specimen with 1,250 holes was larger than the one with 2,500 holes. However, the dimensional stability of the specimen with 2,500 holes was better because of its smaller appearance and thickness change. In the tuck structure, the percent change of hole area in the specimen with 625 and 416 holes was relatively large compared with the appearance and thickness change. Furthermore, the hole size in the tuck structure was smaller than that in the mesh structure but the percent change of hole area was larger. Therefore, it was proved that the tuck structure is more suitable than the mesh structure for developing thermo-sensitive functional materials. Heat moisture transfer property test verified that the change of hole area by yarn shrinkage enabled obtaining the thermal effect due to the distinct temperature difference in the inner layer.

• Polymer(Korea)
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• v.30 no.6
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• pp.545-549
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• 2006

Blends of poly(acrylic acid- co-maleic acid) (PAM) with poly (vinyl alcohol) (PVA) were pre -pared in distilled water PVA/PAM/saponite (PVA/PAM/SPT) nanocomposite films were prepared with various clay contents by using the solution intercalation method. The variations of the dispersion, morphology, and thermo-mechanical properties of the nanocomposites with clay content in the range 0 to 9 wt% were examined. Up to 3 wt% clay loading, the clay particles were homogeneously dispersed in the PVA/PAM blends. However, some agglomerated structures form in the polymer matrix above a clay content of 7 wt%. The thermal stability of the hybrids was increased linearly with increasing the clay loading up to 9 wt%. The maximum strength and modulus were obtained at a clay content of 7 wt%. Thus, the addition of small amounts of clay to the PVA/PAM blends produced PVA/PAM nano-composites with improved the thermo-mechanical properties.

• Journal of the Korean Ceramic Society
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• v.51 no.6
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• pp.554-559
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• 2014

Gadolinium zirconate, $Gd_2Zr_2O_7$, is one of the most promising candidates for replacing yttira-stabilized zirconia (YSZ) in thermal barrier coating (TBC) applications due to its low thermal conductivity and chemical stability at high temperature. In this study, rare-earth zirconate ceramics in the $GdO_{1.5}-ZrO_2$ system with reduced gadolinia contents were fabricated via solid-state reaction as well as hot-pressing at $1800^{\circ}C$. The phase formation, microstructure, and thermo-physical properties of these oxides were examined. The potential application of $GdO_{1.5}-ZrO_2$ ceramics for TBC was also discussed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.291-295
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• 2011

Thermo-structural analysis was performed for a radiation-cooled nozzle extension of thrust chamber. A Niobium alloy that is known to be a high-performance refractory alloy was used. Since area ratio of the nozzle extension is larger than that of nozzle divergence part, its size also becomes larger. For this reason, it is important to minimize the thickness of nozzle extension to reduce its weight. For the purpose of weight minimization, the thickness of nozzle extension was varied from 1.0 mm to 0.4 mm and structural stability was evaluated for each case. Analysis results showed that nozzle extension with thickness of 0.4 mm is structurally stable for the operation condition. The effect of combustion-included vibration will be additionally considered in the future.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.3
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• pp.47-57
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• 2011

All solid rocket propellants are divided in two basic classes according to chemical state: homogeneous(double base) and heterogeneous (composite). Today, composite propellants are extensively used as power sources covering the range from gas generators and small rocket systems to large launch vehicles in space programs. The development of composite rocket propellants in the past was mainly directed to thermoset polymers. But, the thermoset composite propellants have the complication in formulation and fabricating process to adapt to rocket system requirements. In contrast to the thermoset propellant, the PVC plastisols composite propellants have the advantages in the view of loss in manufacturing process, low cost of raw material, and stability of the handling process even though moderate ballistic and mechanical properties. It is predicted that the application field of this class will be used more widely than any other classes.