Journal of Powder Materials (한국분말재료학회지)

The Korean Powder Metallurgy & Materials Institute (한국분말재료학회 (*구 분말야금학회))
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Phase Formation and Thermo-physical Properties of Lanthanum/Gadolinium Zirconate with Reduced Rare-earth Contents for Thermal Barrier Coatings

열차폐코팅을 위한 희토류가 저감된 란타눔/가돌리늄 지르코네이트의 상형성 및 열물성

  • Lee, Sujin (Engineering Ceramic Team, Korea Institute of Ceramic Engineering and Technology) ;
  • Kwon, Chang-Sup (Engineering Ceramic Team, Korea Institute of Ceramic Engineering and Technology) ;
  • Lee, Sung-Min (Engineering Ceramic Team, Korea Institute of Ceramic Engineering and Technology) ;
  • Oh, Yoon-Suk (Engineering Ceramic Team, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Hyung-Tae (Engineering Ceramic Team, Korea Institute of Ceramic Engineering and Technology) ;
  • Nahm, Sahn (Department of Materials Science and Engineering, Korea University) ;
  • Kim, Seongwon (Engineering Ceramic Team, Korea Institute of Ceramic Engineering and Technology)
  • 이수진 (한국세라믹기술원 이천분원 엔지니어링세라믹팀) ;
  • 권창섭 (한국세라믹기술원 이천분원 엔지니어링세라믹팀) ;
  • 이성민 (한국세라믹기술원 이천분원 엔지니어링세라믹팀) ;
  • 오윤석 (한국세라믹기술원 이천분원 엔지니어링세라믹팀) ;
  • 김형태 (한국세라믹기술원 이천분원 엔지니어링세라믹팀) ;
  • 남산 (고려대학교 신소재공학과) ;
  • 김성원 (한국세라믹기술원 이천분원 엔지니어링세라믹팀)
  • Received : 2015.10.26
  • Accepted : 2015.12.12
  • Published : 2015.12.28
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Abstract

Rare-earth zirconates, such as lanthanum zirconates and gadolinium zirconates, have been intensively investigated due to their excellent properties of low thermal conductivity as well as chemical stability at high temperature, which can make these materials ones of the most promising candidates for next-generation thermal barrier coating applications. In this study, three compositions, lanthanum/gadolinium zirconates with reduced rare-earth contents from stoichiometric $RE_2Zr_2O_7$ compositions, are fabricated via solid state reaction as well as sintering at $1600^{\circ}C$ for 4 hrs. The phase formation, microstructure, and thermo-physical properties of three oxide ceramics are examined. In particular, each oxide ceramics exhibits composite structures between pyrochlore and fluorite phases. The potential of lanthanum/gadolinium zirconate ceramics for TBC applications is also discussed.

Keywords

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