• Textile Coloration and Finishing
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• v.30 no.1
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• pp.29-37
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• 2018

Cotton has no adsorption ability for the cationic dye and heavy metal but, if anionized cotton can be made, it will be possible. In this study, to enable the anionisation of cotton fabric, it was modified using sodium vinylsolfonate(SV) as the anionisation reagent, employing a pad-dry-cure(PDC) technique. The effects of curing time, treatment concentrations of urea, sodium hydroxide and SV on the weight increase were experimented and then, the physical characterizations of sulfoethyl cotton(SEC) depending on the finishing conditions were estimated, thus the application possibility of SV as anionisation reagent was investigated. It was not much changed by anionisation except wrinkle recovery. And the structure of SEC was elucidated by Raman and NMR spectoscopy. The feasibility of using Raman and NMR spectroscopy with the band at $1,043cm^{-1}$, and 50.5ppm, respectively as marker band to determine sulfoethyl group of SEC was reported. The total degree of SV substitution(DSV) was determined via elemental analysis. SEC with diverse total DSV up to 0.066 was obtained. In the thermal decomposition(pyrolysis) by DSC, it can be found that the pyrolysis temperature was about $30^{\circ}C$ lower than that of non-treated cotton fabric.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.8
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• pp.711-718
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• 2011

The thermoelastic behavior of the porous carbon/phenolic composites is studied using the thermomechanical response model of chemically decomposing composites. The model includes thermal dependence of the porous composites, porosity in the pyrolysis process, pore pressure due to decomposing gases, and shrinkage. The poroelastic coefficients are calculated based on representative volume element model and finite element analysis. The internal stress distribution caused by pores and pore pressure, and the overall deformation are verified. The effects of the poroelastic coefficients on the thermoelastic behavior are examined through numerical experiments.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.566-569
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• 1999

The blue emitting BAM Phosphor Particles with various compositions were Prepared by the spray Pyrolysis. The effect of composition on the morphology of BAM particles was Investigated. In the case of BaMgAl$_{10}$ /O$_{22}$ : Eu$^{2+}$, the morphology of particles with sphericity and non-aggregation characteristics disappeared after post-treatment at 1400 $^{\circ}C$ for 3 hrs. On the other hand, the ocher composition particles except BaMgAl$_{10}$ /O$_{22}$ : Eu$^{2+}$ maintained their original morphology after post-treatment, even if the particles were prepared at low temperatures in the spray pryrolysis. The BAM particles with MgAl$_{2}$/O$_4$as intermediate material at low post-treatment temperature had high thermal stability and maintained sphericity of particles after post-treatment. All the samples had main omission peak at 450 nm, which corresponds to blue emission. The optimum post-treatment temperature of BAM:Eu$^{2+}$ particles for the maximum PL(photoluminescence) intensity in the spray pylolysis was 1200 $^{\circ}C$ because of high crystallinity, Phase-Purity, and good morphology.ology.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.6
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• pp.596-602
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• 2006

The effects of resin additives and inorganic compounds addition on the thermal decomposition of low density polyethylene(LDPE) resin have been studied in a thermal analyzer(TGA, DSC) and a small batch reactor. The silica-alumina type compounds tested were kaolinite, bentonite, perlite, diatomaceous earth, activated clay and clay. The resin additives were antiforgging-agent and longevity-agent. As the results of TGA experiments, addition of antifogging-agent, longevity-agent and clay increased the temperature of the maximum reaction rate($T_{max}$). The silica-alumina type inorganic materials increased the pyrolysis reraction rate in the order of activated clay, diatomaceous earth, bentonite, perlites, and kaolinite. In the DSC experiments, addition of antifogging-agent and clay decreased the heat of fusion and the heat of pyrolysis reaction. Bentonite decreased 20% of the heat of fusion and 25% of the heat of pyrolysis reaction. In the batch system experiments, the mixing of clay retarded the initial producing rate of fuel oil, but increased the yield of fuel oil. Addition of bentonite increased the yield of fuel oil from LDPE resin. Mixing of antifogging-agent and longevity-agent produced the fuel oil having lower carbon number. The amounts of the carbon number below 12 in fuel oil decreased with adding the clay. That below 23 in fuel oil increased with mixing of bentonite, perlite, kaolinite, and activated clay. But the mixing of diatomaceous earth did not affect the carbon contents of fuel oil from pure LDPE resin. In the silica-alumina type inorganic material used in this experiments, bentonite was the most effective from the pyrolysis heat, yields, and the characteristics of fuel oil.

• Journal of the Korean Wood Science and Technology
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• v.35 no.6
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• pp.31-42
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• 2007

To investigate the pyrolytic and anatomical characteristics of Korean softwood, Pinus densi-flora, Pinus rigida and Larix leptolepis, and hardwood, Acer palntatum, Fraxinus rhynchophylla and Quercus variabilis, chemical components analysis, TG-DTA (Thermogravimetric Analysis & Differential Thermal Analysis), MBA (Methylene Blue Adsorption) test and SEM observation were carried out. For TG-DTA, samples were carbonized up to $800^{\circ}C$ at the heating rate of $10^{\circ}C$/min under $N_2$ flows 1 l/min using thermogravimetric analyzer. Chemical component analysis of all samples resulted in typical contents of major wood component. In TG-DTA results, softwood showed higher char yield than hardwood, and lignin displayed the highest char yield among the major wood components. All samples showed typical TGA, DTG and DTA curves for wood pyrolysis except a few differences between softwood and hardwood. Content of lignin influenced its pyrolysis characteristics, while molecular structure of lignin affected not only the weight loss but also the yield of char. In MBA test results, MBA of softwoods was higher than that of hardwoods. Char of Pinus densiflora showed the highest MBA, but its degree was lower than activated carbon or fine charcoal about 23 and 4 times, respectively. SEM observation showed carbonization process preserves wood structure and retain the micro-structure of wood fibers.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.5
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• pp.818-826
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• 2004

The spray-induced mixing characteristics and thermal decomposition of aqueous urea solution into ammonia have been studied to design optimum sizes and geometries of the mixing chamber in SCR(Selective Catalytic Reduction) system. The cold flow tests about the urea-injection nozzle were performed to clarify the parameters of spray mixing characteristics such as mean diameter and velocity of drops and spray width determined from the interactions between incoming air and injected drops. Discrete particle model in Fluent code was adopted to simulate spray-induced mixing process and the experimental results on the spray characteristics were used as input data of numerical calculations. The simulation results on the spray-induced mixing were verified by comparing the spray width extracted from the digital images with the simulated Particle tracks of injected drops. The single kinetic model was adopted to predict thermal decomposition of urea solution into ammonia and solved simultaneously along with the verified spray model. The hot air generator was designed to match the flow rate and temperature of the exhaust gas of the real engines The measured ammonia productions in the hot air generator were compared with the numerical predictions and the comparison results showed good agreements. Finally, we concluded that the design capabilities for sizing optimum mixing chamber were established.

• Textile Coloration and Finishing
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• v.22 no.1
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• pp.43-50
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• 2010

The thermal treatment for carbon nanotube was applied to remove the water, metal catalyst and other impurities in carbon nanotube. The surface of carbon nanotube was changed into open structure with acid treatment by mixed solution of $HNO_3$ and $H_2SO_4$. The dispersion property of the functionalized and modified carbon nanotube was assessed with naked eyes by dispersing it in DMF. Carbon nanotube mixd polyurethane film was made to estimate the dispersion property by reflectance of the film with UV-Vis spectrometer. Also the internal structure of carbon nanotube was observed with SEM and TEM and thermal pyrolysis property of the carbon nanotube was measured by TGA and DSC. The surface modification of carbon nanotube by thermal and acid treatments improved the dispersion property of carbon nanotube/polyurethane mixed materials.

• Journal of the Korean Society for Precision Engineering
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• v.27 no.6
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• pp.24-31
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• 2010

Laser carbonization of a polymer layer can be employed in various applications in the microelectronics industry, e.g repairing brightness pixels of an LCD panel. In this work, the process of thermal degradation of LCD color filter polymer by various laser sources with pulsewidths from CW to fs is studied. LCD pixels are irradiated by the lasers and the threshold irradiance of LCD color filter polymer carbonization is experimentally measured. In the numerical analysis, the transient temperature distribution is calculated and the number density of carbonization in the polymer layer is also estimated. It is shown that all the lasers can carbonize the polymer layers if the output power is adjusted to meet the thermal conditions for polymerization and that pulsed lasers can result in more uniform distribution of temperature and carbonization than the CW laser.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.4
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• pp.372-376
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• 2022

Since the ZnO varistor is a semiconductor device, the internal thermal distribution during the varistor operation is recognized as an important factor in the performance and deterioration of the varistor. For an optimal varistor structure design, the thermal runaway phenomenon during the varistor operation was interpreted using the Comsol 5.2 analysis program by a finite element analysis. The maximum temperature of the center measured in the cross section of the ZnO varistor was confirmed to increase as the temperature moved from the lower electrode to the center towards the upper electrode up to 572.6 K. The electrodes are thinned so that the influence of the Schottky barrier is not great. The heat gradient balance is determined to be improved when the electrode of the hybrid form is introduced. The thickness, density, pore distribution, impurity uniformity, and particle size of the ZnO varistor are required, and it is determined that the pyrolysis gradient will be improved regardless of the electrode thickness. When these results are applied to design the ZnO varistor, the optimal structure of the ZnO varistor can be obtained.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.11
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• pp.1955-1968
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• 2000

Thermal gravimetric change characteristics and gas phase product - CO, NO, $NO_2$, VOCs - generated in the process of pyrolysis and oxidation. were investigated with variation of process parameters including furnace reactor temperature both in pyrolytic and oxidative conditions. For the thermal gravimetric change characteristics. paper and wood were mainly decomposed at lower temperatures and they had similar thermal gravimetric change trend due to their similar compositions; plastics were mainly decomposed at higher temperatures; in the case of textile. natural compounds were decomposed at lower temperatures and synthetic compounds at relatively higher temperatures; food was decomposed in the wide range of temperatures possibly due to their different kinds of components. For the analysis results of gas phase product. the concentrations of NO, $NO_2$ were detected at higher level at the oxidative conditions than at the pyrolytic conditions except that of CO, which is due to complete combustion with sufficient oxygen at the oxidative condition; food gave off CO, NO, $NO_2$ more than the other wastes. VOCs were emitted more at the pyrolytic conditions than at the oxidative conditions.