• Title/Summary/Keyword: thermal processes

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Activation Energies of Hydrogen Absorption and Desorption in Pd Thin Films for the α phase (팔라디움박막의 α 상영역 수소 활성화에너지)

  • Cho, Youngsin
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.4
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    • pp.191-196
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    • 1999
  • 4-probe resistivity measurement technique was used to study hydrogen A-D(Absorption-Desorption)kinetics on Pd films(18 to 67nm thick) from 25 to $50^{\circ}C$, from 0 to 5 torr hydrogen pressure. Pd films were made on sapphire substrate by thermal evaporation technique under high vacuum at room temperature. Upto about 100 hydrogen A-D cyclings, no pulverization was observed, but film was detached partially from substrate. Forward reaction and backward reaction rate were analyzed separately. The activation energies of hydrogen A-D processes were obtained from the Arrhenius plot of the reaction rates. The activation energies of Pd films are not strongly dependent on the thickness of the film. But the activation energy of very thin film( l8nm thick) was smaller than the others.

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Deformation Measurement of Electronic Components in Mobile Device Using High Sensitivity Shadow Moiré Technique (고감도 그림자 무아레 기법을 이용한 모바일 전자부품의 변형 측정)

  • Yang, Hee-Gul;Joo, Jin-Won
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.1
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    • pp.57-65
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    • 2017
  • The electronic components in mobile device are composed of electronic chips and various other materials. These components become extremely thin and the constituent materials have different coefficient of thermal expansion, so that considerable warpages occurs easily due to temperature change or external load. Shadow $moir{\acute{e}}$ is non-contact, whole field technique for measuring out-of-plane displacement, but the measurement sensitivity is not less than $50{\mu}m/fringe$, which is not suitable for measuring the warpage of the electronic components. In this paper, we implemented a measurement method with enhanced sensitivity of $25{\mu}m/fringe$ by investigating and optimizing various experimental conditions of the shadow $moir{\acute{e}}$. In addition, four $moir{\acute{e}}$ fringe patterns recorded by the phase shift are processes to obtain a $moir{\acute{e}}$ fringe patterns with a sensitivity four times higher. The measurement technique is applied to small electronic components of a smart phone for measuring warpage with a high sensitivity of $5{\mu}m/fringe$ at room temperature and at the temperature of $100^{\circ}C$.

Examination of Conductor and Sheath Temperatures Dependent on the Load Currents through High-Power Live Cables at a Power Station (발전소에서 활선 고전력 케이블의 운전 부하전류에 따른 도체 및 피복표면의 온도 분석)

  • Um, Kee-Hong
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.17 no.1
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    • pp.213-218
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    • 2017
  • High-voltage power systems operate in order to generate and transmit electric power at power stations. Compared to low-power systems, high-power systems are complex in structure, large-scale, and expensive. When high-power cable accidents occur, most facilities are incapacitated-including low-power systems-causing huge economic losses. Great care must therefore be taken in designing, installing and managing power systems. Although dependent on installation circumstances and usage conditions, in some cases the cross-sectional areas of cables fall short of the critical area due to the expansion of and improper design and installation of power facilities. In this situation, the exceeded ampacity (allowable current) above the critical value caused by the operating current initiates the deterioration processes of power cables. In order to systematically monitor power cables operating at power stations, we have developed the first device of its kind in Korea. In this paper, we present the analyzed characteristics of expected temperatures of cables based on the load current of high-voltage cables operating at Korean Western Power Co. Ltd. We can predict the lifetime of cables by analyzing the temperature obtained from our device.

Modeling and Analysis for the Growth/Dissolution of Oxygen Precipitation in CZ-grown Silicon (CZ 방법에 의해 성장된 실리콘에서 산소 석출물의 성장/감소에 관한 모델 및 해석)

  • 고봉균;곽계달
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.10
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    • pp.29-38
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    • 1998
  • In this paper, we have induced a model for the growth and dissolution of oxygen precipitates which is generated during arbitrary thermal treatments or VLSI processes in CZ-grown silicon. Based on diffusion-limited growth law and detailed balance equilibrium theory, growth and dissolution rates are induced and inserted into a set of chemical rate equations and a Fokker-Planck equation. Then this is solved by numerical analysis. And because phenomenon at the silicon surface must be considered differently in various annealing conditions, in particular in $O_2$ ambient we have considered the growth model of SiO$_2$ at the surface of silicon wafer and the enhancement of oxygen solubility. By this method, oxygen depth profile and density distribution of oxygen precipitates are calculated more accurately than the other simulation results.

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Fabrication and Properties of Natural Fiber-Reinforced Waste Wool/Polypropylene Composites (NFRP) (천연섬유강화 폐양모/폴리프로필렌 복합재료(NFRP)의 제조 및 특성)

  • Kim, Ki Hyun;Cho, Donghwan;Kim, Jong Hyun
    • Journal of Adhesion and Interface
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    • v.9 no.2
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    • pp.16-23
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    • 2008
  • In this study, novel waste wool/polypropylene NFRPs (natural fiber reinforced polymer composites), which are constituted with waste wool discarded as industrial scrap during manufacturing processes of woven fabrics and general purpose thermoplastic polypropylene (PP), were fabricated by means of compressionmolding and their mechanical and thermal properties were characterized. The mechanical properties of PP resin were significantly improved by an introduction of waste wool to PP. In particular, as the loading of waste wool was 50 vol% in the NFRP, the flexural strength of the NFRP was increased about 20%, the flexural modulus about 143%, the tensile strength about 76%, and the tensile modulus about 90% in comparison with each of PP control. In addition, the maximum value of the heat deflection temperature (HDT) obtained with the NFRP was $138^{\circ}C$ at a 50 vol% loading of waste wool. This is $21^{\circ}C$ higher than the HDT of PP control. The result here suggests that waste wool be a potential candidate for a reinforcing material of thermoplastic matrix resins.

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A study on reactive chlorine species generation enhanced by heterojunction structures on surface of IrO2-based anodes for water treatment (IrO2 기반 수처리용 산화 전극의 표면 이종 접합 구성에 따른 활성 염소종 발생 증진 특성 연구)

  • Hong, Sukhwa;Cho, Kangwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.4
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    • pp.349-355
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    • 2018
  • This study interrogated multi-layer heterojunction anodes were interrogated for potential applications to water treatment. The multi-layer anodes with outer layers of $SnO_2/Bi_2O_3$ and/or $TiO_2/Bi_2O_3$ onto $IrO_2/Ta_2O_5$ electrodes were prepared by thermal decomposition and characterized in terms of reactive chlorine species (RCS) generation in 50 mM NaCl solutions. The $IrO_2/Ta_2O_5$ layer on Ti substrate (Anode 1) primarily served as an electron shuttle. The current efficiency (CE) and energy efficiency (EE) for RCS generation were significantly enhanced by the further coating of $SnO_2/Bi_2O_3$ (Anode 2) and $TiO_2/Bi_2O_3$ (Anode 3) layers onto the Anode 1, despite moderate losses in electrical conductivity and active surface area. The CE of the Anode 3 was found to show the highest RCS generation rate, whereas the multi-junction architecture (Anode 4, sequential coating of $IrO_2/Ta_2O_5$, $SnO_2/Bi_2O_3$, and $TiO_2/Bi_2O_3$) showed marginal improvement. The microscopic observations indicated that the outer $TiO_2/Bi_2O_3$ could form a crack-free layer by an incorporation of anatase $TiO_2$ particles, potentially increasing the service life of the anode. The results of this study are expected to broaden the usage of dimensionally stable anodes in water treatment with an enhanced RCS generation and lifetime.

Preparation and Characteristics of Cellulose Acetate Based Nanocomposites Reinforced with Cellulose Nanocrystals (CNCs) (셀룰로오스 나노크리스탈 강화 셀룰로오스 아세테이트 나노복합소재 제조 및 특성)

  • Gwon, Jae-Gyoung;Lee, Dan-Bee;Cho, Hye-Jung;Lee, Sun-Young
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.5
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    • pp.565-576
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    • 2018
  • Cellulose acetate (CA) has been widely utilized for composite materials due to its high transparency and thermal resistance. In this study, CNCs (cellulose nanocrystals) were reinforced in CA nanocomposites for fortifying mechanical properties of the composites. In addition, CA nanocomposites reinforced with CNCs were manufactured by extrusion/injection processes applied with CNC-predispersion method for achieving a high dispersion level of CNCs in the CA matrix. According to the analysis of mechanical properties, the CA nanocomposite with 3 wt% CNCs has the highest tensile and flexural strengths due to the reinforcing effect of CNC nanoparticles. Thermogravimetric analysis (TGA) showed that the addition of acid hydrolyzed CNCs slightly lowered the initial pyrolysis temperature of CA nanocomposite.

Degradation analysis of SiC fiber at elevated temperature for dust filtering applications (분진필터링 적용을 위한 SiC 섬유의 고온 열화분석)

  • Joo, Young Jun;Park, Cheong Ho;Khishigbayar, Khos-Erdene;Kim, Cheol Jin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.1
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    • pp.28-33
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    • 2017
  • SiC fiber can be used up to $1800^{\circ}C$ in both inert and air atmosphere without any problems such as melting and oxidation. SiC fibers can be applied to dust filtering processes as a bag filter at a high temperature above $700^{\circ}C$, which is far beyond the temperature range of currently available industrial bag filter. However the studies for the degradation of SiC fibers were still lacked in the harsh environment of steel industries and thermoelectric power plants. In this study, SiC fibers were reacted with steel dust and thermal power plant dust at a high temperature of $500^{\circ}C$ or higher, and the degraded shape of the fiber surface was observed by SEM. Also the degree of oxygen diffusion on the surface and inside of SiC fiber was analyzed by EDS.

The Effect of Grain Boundary Diffusion on the Boundary Structure and Electrical Characteristics of Semiconductive $SrTiO_3$ Ceramics (입계확산에 의한 반도성 $SrTiO_3$ 세라믹스의 입계구조 및 전기적 특성 변화)

  • 김태균;조남희
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.23-30
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    • 1997
  • Semiconductive SrTiO3 ceramic bodies were prepared by conventional ceramic powder processes in-cluding sintering in a reducing atmosphere. Sodium or potassium ions were diffused from the surface of the sintered bodies into the inner region using thermal diffusion process at 800-120$0^{\circ}C$. The effects of such ther-mal treatments on the electrical and chemical characteristics of the grain boundaries were investigated. The presence of sodium or potassium ions at grain boundaries produces non-linear current-voltage behaviors, electrical boundary potential barriers of 0.1-0.2eV, and threshold voltages of 10-70V. The diffused ions form diffusion layers with thicknesses of 20-50nm near the grain boundaries, reducing the concentration of strontium and oxygen.

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HTGR Nuclear Fuel Microsphere Preparation Using the Modified Sol-Gel Method (변형 Sol-Gel 방법을 이용한 고온가스로 핵연료 미세구입자 제조)

  • Jeong, Kyung-Chai;Kim, Yeon-Ku;Oh, Seung-Chul;Cho, Moon-Sung
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.574-582
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    • 2009
  • $UO_2$ microsphere particles, core material of HTGR(High Temperature Gas Reactor) nuclear fuel, were prepared using by the GSP(Gel Supported Precipitation) method which is a modified-method of the wet sol-gel process. The spherical shape of initial liquid ADU droplets from the vibration nozzle system was continuously kept till the conversion to the final $UO_2$ microsphere. But the size of a final $UO_2$ microsphere was shrunken to about 25% of an initial ADU droplet size. Also, we found that the composition of dried-ADU gel particles was constituted of the very complicated phases, coexisted the U=O, C-H, N-H, N-O, and O-H functional groups by FT-IR. The important factors for obtain the no-crack $UO_2$ microsphere during the thermal treatment processes must perfectly wash out the remained-$NH_4NO_3$ within the ADU gel particle in washing process and the selections of an appropriate heating rate at a suitable gas atmosphere, during the calcining of ADU gel particles, the reducing of $UO_3$ particles, and the sintering of $UO_2$ particles, respectively.