• 대한화학회지
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• 제31권6호
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• pp.590-600
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• 1987

bis(p-chlorocarbonylphenyl)diphenylsilane (BCCDPS)과 pyromellitic dianhydride(PMDA) 및 몇가지의 디아민으로부터 실리콘을 함유하고 있는 폴리아미드-이미드를 합성하였다. 열중량분석기를 이용하여 합성한 중합체의 열적성질을 조사하였으며 Friedman 방법으로 중합체 열분해 반응의 활성화에너지를 구하였다. 중합체 분자내의 bis(p-carbonylphenyl)diphenylsilane units(BCDPS) 단위의 함량이 증가할수록 열안정성과 열분해 반응의 활성화에너지값은 감소하였으나 용매에 대한 용해성은 증가하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.479-482
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• 1999

Cured epoxy resins are extensively used for the electrical insulation in high-voltage equipments. The bisphenol A-based epoxy resins lured with azine show, especially, good thermal properties and mechanical resistances. For the technical and economic reasons, varing amount of inorganic fillers are added to endow the required special properties. In the large generators and motors of power plants, epoxy insulation is disclosed to the harsh conditions like the superheated steam and abrupt temperature variation. Hygrothermal aging at elevated temperatures tends to induce degradation in epoxy resins. To predict the effect of this degradation in DGEBA/MDA/SN/zeolite system, we proceeded the forced moisture absorption experiment using the autoclave. The thermal properties of the untreated and treated specimens were analyzed by DSC and TGA under the nitrogen flowing condition. The moisture absorption results showed a weight increase during hygrothermal aging at 1207. At the initial aging period, the system leaded to more or less postcuring but more prolonged environmental aging leaded the discoloration of specimen and lowering the T$_{g}$./.

• 한국표면공학회지
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• 제50권6호
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• pp.492-497
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• 2017

In this study, we investigated the effect of thermal aging on mechanical characteristics of Inconel 600 nickel-based alloy. The thermal aging was conducted up to 1000 hours at an atmosphere of $650^{\circ}C$. The microstructure of thermally aged specimens was investigated by an optical microscope (OM), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). In addition, tensile test (strain rate: 2 mm/min) and micro Vickers hardness test were conducted to evaluate mechanical properties with time. As a result of the experiment, Cr-rich carbide continuously precipitated during thermal aging, leading to the change of the mechanical characteristics and fracture mode. With the increase of aging time, tensile strength, yield strength, and hardness gradually decreased. The fracture mode changed from ductile to brittle with the increase of grain boundary carbide.

• International Journal of Korean Welding Society
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• 제3권2호
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• pp.29-39
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• 2003

The durability and reliability of thermal barrier coatings (TBCs) play an important role in the service reliability, availability and maintainability (RAM) of hot­section components in advanced turbine engines for aero and utility applications. Photostimulated luminescence spectroscopy (PSLS) and electrochemical impedance spectroscopy (EIS) are being concurrently developed as complimentary non­destructive evaluation (NDE) techniques for quality control and life­remain assessment of TBCs. This paper overviews the governing principles and applications of the luminescence and the impedance examined in the light of residual stress, phase constituents and resistance (or capacitance) in TBC constituents including the thermally grown oxide (TGO) scale. Results from NDE by PSLS and EIS are discussed and related to the microstructural development during high temperature thermal cycling, examined by using a variety of microscopic techniques including focused ion beam (FIB) in­situ lift­out (INLO), transmission and scanning transmission electron microscopy (TEM and STEM).

• Journal of Electrical Engineering and Technology
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• 제13권3호
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• pp.1166-1172
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• 2018

Degradation due to delamination occurs frequently in the high temperature superconductors (HTS) coil of rotating machines made with 2nd generation (2G) HTS wire, and the authors have observed other similar cases. Since an HTS field coil for a rotating machine is required to have stable current control and maintain a steady state, co-winding techniques for insulation material and epoxy resin for shape retention and heat transfer improvement are applied during coil fabrication. However, the most important limiting factor of this technique is delamination, which is known to be caused by the difference in thermal expansion between the epoxy resin and 2G HTS wire. Therefore, in this study, the experimental results of mixing the ratio of epoxy resin and alumina ($Al_2O3$) filler were applied to the fabrication of small and large test coils to solve the problem of degradation. For the verification of this scheme, eight prototypes of single pancake coils with different shapes were fabricated. They showed good results. The energization and operation maintenance tests of the stacked coils were carried out under liquid neon conditions similar to the operation temperature of an MW-class rotating machine. In conclusion, it was confirmed that the alumina powder mixed with epoxy resin in an appropriate ratio is an effective solution of de-lamination problem of 2G HTS coil.

• 드라이브 ㆍ 컨트롤
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• 제12권1호
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• pp.1-8
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• 2015

The stability of friction characteristics and thermal management for a dry type dual clutch transmission (DCT) are inferior to those of a wet clutch. Too high temperature resulting from frequent engagement of DCT speeds up degradation or serious wear of the pressure plate or burning of the clutch disk lining. Even though it is significantly important to estimate the temperature of a dry double clutch (DDC) in real-time, few meaningful study of the thermal model of DDC has been known yet. This study presented a thermal analytical model of lumped parameters for a DDC by analyzing its each component firstly. Then a series of experimental test was carried out on the test bench with a patented temperature telemetry system to validate the proposed thermal model. The thermal model, whose optimal parameter values were found by optimization algorithm, was also simulated on the experimental test conditions. The simulation results of DDC temperature show consistency with the experiment, which validates the proposed thermal model of DDC.

• 한국의류학회지
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• 제34권6호
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• pp.1042-1052
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• 2010

The Degradation of amur cork tree extract is investigated by GC-MS after treating the dye with three thermal degradation systems of, room temperature (RT), $4^{\circ}C$ refrigeration (LT), $100^{\circ}C$ oven (OV), and $H_2O_2$/UV/$O_2$ (PER) degradation system for 0-24 days. It was found that PER degradation system represented the highest intensity of degradation treatment followed by OV treatment among the four degradation parameters. The possible fingerprint products of amur cork tree dye, that yielded 68% (or higher) reliability in the NIST spectral match, were isobenzofuran-1,3-dione,4,5-dimethoxy- (8.37 min, PER only), 1,3-dioxolo[4,5-g]isoquinolin-5(6H)-one,7,8-dihydro (9.41 min, PER only), canthine-6-one (10.24 min, RT, LT, OV only), and dihydroberberine (15.05 min, RT, LT, OV, PER) in the order of higher to lower possibility of detection. Unknown products 7 (13.43 min) and 8 (16.35 min) are two other possible fingerprint products of amur cork tree dye that require future identification.

• Journal of Welding and Joining
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• 제31권3호
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• pp.22-30
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• 2013

Due to ELV banning, automotive electronics cannot use four kinds of heavy metal element (Pb, Hg, Cd, $Cr^{6+}$) from 2016. Therefore, this study was focused on degradation characteristics of Sn-3.0Ag-0.5Cu Lead-free solder joint with OSP and ENIG finsh under various reliability assessment method, as like to thermal shock test and high temeprature/high humidity test with test duration for cabin electronics. Also, we compared bonding strength degradation to other advanced research results of electronic control unit for engine room because of difference service temperature with mount location in automotive. Whisker growth phenomenon and mitigation method which were essentially consideration items for Pb-free car electronics were examined. Conformal coating is a strong candidate for mitigating whisker growth in automotive electronics. Necessary condition to adapt Pb-free in car electronics was shown.

• 한국전기전자재료학회논문지
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• 제15권1호
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• pp.93-101
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• 2002

In this study, the stator form-winding sample coils based on silicone resin and polyimide were made for fault prediction and reliability estimation on the C-Class(200$\^{C}$ ) insulation system of traction motors. The complex accelerative degradation was periodically performed during 10 cycles, which was composed of thermal stress, fast rising surge voltage, vibration, water immersion and overvoltage applying. After aging of 10 cycles, the condition diagnosis test such as insulation resistance '||'&'||' polarization index, capacitance '||'&'||' dielectric loss and partial discharge properties were investigated in the temperature range of 20 ∼ 160$\^{C}$. Relationship among condition diagnosis tests was analyzed to find a dominative degradation factor and an insulation state at end-life point.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.763-766
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• 2000

In this paper, stator form-winding sample coils based on silicone resin and polyimide were made for fault prediction and reliability estimation on the 200 Class insulation system of traction motors. The complex accelerative degradation was performed by periods during 10 cycles, which was composed of thermal stress, fast rising surge voltage, vibration, water immersion and overvoltage applying. After aging of 10 cycles, condition diagnosis test such as insulation resistance & polarization index, capacitance & dielectric loss and partial discharge properties were investigated in the temperature range of 20∼160$^{\circ}C$. Relationship among condition diagnosis test was analyzed to find an dominative degradation factor and an insulation state at end-life point.