• Title/Summary/Keyword: theoretical analyses

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Modeling on thermal conductivity of MOX fuel considering its microstructural heterogeneity

  • Lee, Byung-Ho;Koo, Yang-Hyun;Sohn, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1999.10a
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    • pp.247-247
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    • 1999
  • This paper describes a new mechanistic thermal conductivity model considering the heterogeneous microstructure of MOX fuel. Even though the thermal conductivities of MOX have been investigated numerously by experimental measurements and theoretical analyses, they show the large scattering making the performance analysis of MOX fuel difficult. Therefore, a thermal conductivity model that depends on the heterogeneous microstructure of MOX fuel has been developed by using a general two-phase thermal conductivity model. In order to apply this model for developing the thermal conductivity for heterogeneous MOX fuel, the fuel is assumed to consist of Purich particles and U02 matrix including Pu02 in solid solution. Since little relevant data on Purich particles is available, FIGARO and SiemensKWU results are only used to characterize the microstructure of unirradiated and irradiated fuel. Philliponneaus and HALDEN models are selected for the local thermal conductivities for Purich particles and matrix, respectively. Then by combining the two models, overall thermal conductivity of MOX fuel is obtained. The new proposed model estimates the MOX thermal conductivity about 10% less than the value of U02 fuel, which is in the range of MOX thermal conductivity from HALDEN. The developed thermal conductivity model has been incorporated into KAERIs fuel performance code, COSMOS, and then verified using the measured data in the FIGARO program. Comparison of predicted and measured temperatures shows the reasonable agreement within acceptable error bounds together with satisfactory results for the fission gas release and gap pressure.essure.

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Effect of oxygen containing compounds in uranium tetrafluoride on its non-adiabatic calciothermic reduction characteristics

  • Gupta, Sonal;Kumar, Raj;Satpati, Santosh K.;Sahu, Manharan L.
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1931-1938
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    • 2021
  • Uranium ingot is produced by metallothermic reduction of uranium tetrafluoride using magnesium or calcium as reductant. Presence of oxygen containing compounds viz. uranyl fluoride and uranium oxide in the starting uranium fluoride has a significant effect on the firing time, final temperature of the charge, slag-metal separation and hence the metal recovery. As reported in the literature, the maximum tolerable limit for uranyl fluoride in the UF4 is 2.5 wt% and limit for uranium oxide content is in the range 2-3 wt%. No theoretical or experimental basis is available till date for these limits. Analyses have been carried out in this study to understand the effect of UO2F2 concentration in the starting fluoride on the final temperature of the products and thus the reduction characteristics. UF4 having uranyl fluoride concentration, less than as well as more than 2.5 wt%, have been investigated. Thermodynamic calculations have been carried out to arrive at a general expression for the final temperature attained by the products during calciothermic reduction of UF4. Finally, an upper limit for the oxygen containing impurities has been estimated using the CaO-CaF2 phase diagram.

The MFN Principle at Peril in Investment Treaties - with Particular References to Ansung Housing and Beijing Urban Construction

  • Chung, Chan-Mo
    • Journal of Korea Trade
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    • v.24 no.2
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    • pp.15-30
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    • 2020
  • Purpose - This paper investigates the theories and practices of Most-Favored-Nation (MFN) clauses. The MFN clause became a controversial issue during the past two decades, especially in the context of investment arbitration. This paper aims to clarify a reasonable way to apply MFN clauses. It in particular focuses on the territoriality requirements and the scope of investment activity which are common features included in most of investment treaties. Design/methodology - This paper analyses two investment arbitration cases, Ansung Housing and Beijing Urban Construction. Through the case study, this paper reveals limitations of the currently dominant views on the operation of MFN clauses. It then tries to reconstruct the system of MFN application within the relevant arbitration principles. Findings - Tribunals of recent investment arbitration as represented in the two cases above employed strict literal interpretation of the treaty provisions, especially of the phrase "in its territory". This paper finds a more functional interpretation is appropriate and consistent with theories of public international law and developments of global economy. Originality/value - Existing studies either stuck to literal interpretation or suggested more flexible interpretation of the phrase "in its territory" without full explanation. This paper tries to fill the gap in the existing discussion by analyzing legal foundations and theoretical structure for an effective interpretation of MFN clauses.

Influence of Device Parameters Spread on Current Distribution of Paralleled Silicon Carbide MOSFETs

  • Ke, Junji;Zhao, Zhibin;Sun, Peng;Huang, Huazhen;Abuogo, James;Cui, Xiang
    • Journal of Power Electronics
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    • v.19 no.4
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    • pp.1054-1067
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    • 2019
  • This paper systematically investigates the influence of device parameters spread on the current distribution of paralleled silicon carbide (SiC) MOSFETs. First, a variation coefficient is introduced and used as the evaluating norm for the parameters spread. Then a sample of 30 SiC MOSFET devices from the same batch of a well-known company is selected and tested under the same conditions as those on datasheet. It is found that there is big difference among parameters spread. Furthermore, comprehensive theoretical and simulation analyses are carried out to study the sensitivity of the current imbalance to variations of the device parameters. Based on the concept of the control variable method, the influence of each device parameter on the steady-state and transient current distributions of paralleled SiC MOSFETs are verified separately by experiments. Finally, some screening suggestions of devices or chips before parallel-connection are provided in terms of different applications and different driver configurations.

Design-Oriented Stability of Outer Voltage Loop in Capacitor Current Controlled Buck Converters

  • Zhang, Xi;Zhang, Zhongwei;Bao, Bocheng;Bao, Han;Wu, Zhimin;Yao, Kaiwen;Wu, Jing
    • Journal of Power Electronics
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    • v.19 no.4
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    • pp.869-880
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    • 2019
  • Due to the inherent feedforward of load current, capacitor current (CC) control shows a fast transient response that makes it suitable for the power supplies used in various portable electronic devices. However, considering the effect of the outer voltage loop, the stable range of the duty-cycle is significantly diminished in CC controlled buck converters. To investigate the stability effect of the outer voltage loop on buck converters, a CC controlled buck converter with a proportion-integral (PI) compensator is taken as an example, and its second-order discrete-time model is established. Based on this model, the instability caused by the duty-cycle is discussed with consideration of the outer voltage loop. Then the dynamical effects of the feedback gain of the PI compensator and the equivalent series resistance (ESR) of the output capacitor on the CC controlled buck converter with a PI compensator are studied. Furthermore, the design-oriented closed-loop stability criterion is derived. Finally, PSIM simulations and experimental results are supplied to verify the theoretical analyses.

Numerical Simulation of Diffusion and Flow in Fabrication of Carbon/Carbon Composite Using Chemical Vapor Infiltration (다단계 화학반응과 밀도화 모델을 이용한 탄소/탄소 복합재 화학기상침투 공정의 확산 및 유동 수치해석)

  • Kim, Hye-gyu;Ji, Wooseok;Jo, Namchun;Park, Jonggyu
    • Composites Research
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    • v.32 no.1
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    • pp.56-64
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    • 2019
  • In this paper, a model is developed to simulate carbon/carbon composite fabrication using chemical vapor infiltration, considering density and porosity change in the preform and multi-step hydrocarbons reactions. The model considers the preform as a porous medium whose diffusion and flow properties changes due to the porosity. To verify the theoretical model, two numerical analyses were performed for the case that the flow inside the preform is zero and the case that the flow inside the preform is calculated by fluid mechanics. The numerical results showed good agreement with the experimental data.

A Study on the Influence of the Perceived Service Quality on the Customer's Loyalty - Focusing on the Service Industry Consumers (지각된 서비스품질이 고객충성도에 미치는 영향에 관한 연구 : 서비스 산업 고객을 대상으로)

  • Do, Hyun-Ok
    • Journal of Industrial Convergence
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    • v.13 no.2
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    • pp.25-37
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    • 2015
  • The purpose of this study is about the influence of the Service quality on the customer loyalty depending on the customer value(social and psychological value, functional value) because of the dynamic business environment is react quickly and flexibly, many of today's companies are required to consult an expert. According to the circumstances, Service Firms(Hotel) should be provide a differentiated service for each customer. And this paper attempt to theoretical organize and take advantage of practical in Service industry. The questionaries of 154 from the companies which have received Service in 3 years in the metropolis and small and medium-sized cities were used to test hierarchical regression model with mediating effects of customer value between Service quality and Customer loyalty by SPSS(PASW) 18.0 version. From these analyses, the following results were obtained: First, social-psychological value have partially mediated effect on the tangibility, responsibility, assurance and customer loyalty. Second, functional value have partially mediated effects on the between tangibles, reliability and customer loyalty. The result suggests that 'tangibility', 'reliability', 'responsibility', 'assurance', 'empathy' are the most important factors to affect customer loyalty, and there are partially mediated effects of customer intention between Service quality and Customer loyalty. In conclusion, to improve the specific and actual meaning and value about the Hotel service quality and to give the suggestions on the Hotel's marketing communication by understanding the customer action.

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Multidimensional Conducting Agents for a High-Energy-Density Anode with SiO for Lithium-Ion Batteries

  • Lee, Suhyun;Go, Nakgyu;Ryu, Ji Heon;Mun, Junyoung
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.244-249
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    • 2019
  • SiO has a high theoretical capacity as a promising anode material candidate for high-energy-density Li-ion batteries. However, its practical application is still not widely used because of the large volume change that occurs during cycling. In this report, an active material containing a mixture of SiO and graphite was used to improve the insufficient energy density of the conventional anode with the support of multidimensional conducting agents. To relieve the isolation of the active materials from volume changes of SiO/graphite electrode, two types of conducting agents, namely, 1-dimensional VGCF and 0-dimensional Super-P, were introduced. The combination of VGCF and Super-P conducting agents efficiently maintained electrical pathways among particles in the electrode during cycling. We found that the electrochemical performances of cycleability and rate capability were greatly improved by employing the conducting agent combinations of VGCF and Super-P compared with the electrode using only single VGCF or single Super-P. We investigated the detailed failure mechanisms by using systematic electrochemical analyses.

A stress model reflecting the effect of the friction angle on rockbursts in coal mines

  • Fan, Jinyang;Chen, Jie;Jiang, Deyi;Wu, Jianxun;Shu, Cai;Liu, Wei
    • Geomechanics and Engineering
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    • v.18 no.1
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    • pp.21-27
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    • 2019
  • Rockburst disasters pose serious threat to mining safety and underground excavation, especially in China, resulting in massive life-wealth loss and even compulsive closed-down of some coal mines. To investigate the mechanism of rockbursts that occur under a state of static forces, a stress model with sidewall as prototype was developed and verified by a group of laboratory experiments and numerical simulations. In this model, roadway sidewall was simplified as a square plate with axial compression and end (horizontal) restraints. The stress field was solved via the Airy stress function. To track the "closeness degree" of the stress state approaching the yield limit, an unbalanced force F was defined based on the Mohr-Coulomb yield criterion. The distribution of the unbalanced force in the plane model indicated that only the friction angle above a critical value could cause the first failure on the coal in the deeper of the sidewall, inducing the occurrence of rockbursts. The laboratory tests reproduced the rockburst process, which was similar to the prediction from the theoretical model, numerical simulation and some disaster scenes.

Theoretical Model for Accident Prevention Based on Root Cause Analysis With Graph Theory

  • Molan, Gregor;Molan, Marija
    • Safety and Health at Work
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    • v.12 no.1
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    • pp.42-50
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    • 2021
  • Introduction: Despite huge investments in new technology and transportation infrastructure, terrible accidents still remain a reality of traffic. Methods: Severe traffic accidents were analyzed from four prevailing modes of today's transportations: sea, air, railway, and road. Main root causes of all four accidents were defined with implementation of the approach, based on Flanagan's critical incident technique. In accordance with Molan's Availability Humanization model (AH model), possible preventive or humanization interventions were defined with the focus on technology, environment, organization, and human factors. Results: According to our analyses, there are significant similarities between accidents. Root causes of accidents, human behavioral patterns, and possible humanization measures were presented with rooted graphs. It is possible to create a generalized model graph, which is similar to rooted graphs, for identification of possible humanization measures, intended to prevent similar accidents in the future. Majority of proposed humanization interventions are focused on organization. Organizational interventions are effective in assurance of adequate and safe behavior. Conclusions: Formalization of root cause analysis with rooted graphs in a model offers possibility for implementation of presented methods in analysis of particular events. Implementation of proposed humanization measures in a particular analyzed situation is the basis for creation of safety culture.