• Title/Summary/Keyword: temperature stable

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촉매성 산화물 전극 (DSA, Dimensionally Stable Anode)의 가속수명 테스트 방법과 장치에 관한 기초 연구 (A Basic Study on Accelerated Life Test Method and Device of DSA (Dimensionally Stable Anode) Electrode)

  • 김동석;박영식
    • 한국환경과학회지
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    • 제27권6호
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    • pp.467-475
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    • 2018
  • The lifetime of the electrode is one of the most important factors on the stability of the electrode. Since the lifetime of the DSA (Dimensionally stable anode) electrode is long, an accelerated lifetime test is required to reduce the test time. Beacuse there is no basis or standard method for accelerated lifetime testing, many researchers use different methods. Therefore, there is a need for basis and methods for accelerated lifetime testing that other researchers can follow. We designed a reactor system for accelerated lifetime testing and planned specific methods. Reactor system was circulating batch reactor. Reactor volume and cooling water tank were 12.5 L and 100 L, respectively. Electrode size was $2cm{\times}3cm$ (real electrolysis area, $5cm^2$). In order to maintain the harsh conditions, accelerated lifetime test was carried out in a high current density ($0.6A/cm^2$) and low electrolyte concentration (NaCl, 0.068 mol/L). Maintaining a constant temperature was an important operation parameter for exact accelerated lifetime test. As the accelerated lifetime test progressed, the active component of electrode surface was consumed and desorption occurred. At the point of 5 V rise, corrosion of the surface of the base material(titanium) also started.

혐기 소화조 유출수의 아질산화 반응에 온도가 미치는 영향 (Effect of Temperature on Nitritation using Effluent of Anaerobic Digester)

  • 임지열;길경익
    • 한국물환경학회지
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    • 제27권3호
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    • pp.286-292
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    • 2011
  • Preparing for the Standards for Effluents which will be strengthen from 2012, many ways like remodellings and repairs of sewage treatment plant (STP) are considered. The treatment of the recycle water from the sludge treatment process contains high-strength organic compounds and nitrogen is considered as alternative. In the treatment of high-strength nitrogen, nitritation has more economic advantages than nitrification. In this study, lab-scale reactor was operated at the $35^{\circ}C$, $20^{\circ}C$ and $10^{\circ}C$ conditions using effluent of anaerobic digester to investigate the nitrogen removal by nitritation. Long-term stable nitritation was achieved at the $35^{\circ}C$, $20^{\circ}C$ but $10^{\circ}C$. In the stable nitritation states, nitrite conversion was higher at the high temperature of $35^{\circ}C$ than the room temperature of $20^{\circ}C$. Also shorter solid retention time (SRT) was needed to induce high nitrite conversion at the high temperature of $35^{\circ}C$. It was showed that temperature and SRT are important factors to induce nitritation.

Stability and Formation Mechanism for MLV liposomes with Phospholipid Film by Use of the Microfluidizer

  • Kim, In-Young;Seo, Bong-Seok
    • 대한화장품학회지
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    • 제22권2호
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    • pp.99-114
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    • 1996
  • The MLV liposomes have been developed in many drugs and cosmetics fields. The phospholipid base is made from ceramides, cholesterol, cholesteryl ester, lecithin, lanolin ester, and B-sitosterol, and surfactants are made by using (PEG)n-sitosterol(n=5) and K-cetyl phosphate. We made visicles stable by passing samples through Microfludizer and croated multilamellar vesicles to make MLV liposomes similar to the structure of men's skin. In order to make MLV liposomes, we created lipid membrane films which a mixure of phospholipid base and polyol group was reacted above Tc(95$^{\circ}C$) by gelation for 3 hours. As the optimum conditions of Microfluidizer, we figured out 700 bar for the passing pressure of samples, 4$0^{\circ}C$ for its temperature, and 3 times of frequency to pass through samples. Our MLV liposomes is stable on conditions of a low temperature(5$^{\circ}C$) and a high temperature(45$^{\circ}C$), which is not to be split in a large range. We produced our own moisturizing cream which has a good affinity to skin by means of this system.

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Methacrylate/Polyurethane이 함유된 Epoxy 복합재료의 직류 절연 파괴 특성에 관한 연구 (A Study on the DC Dielectric Breakdown Properties of Epoxy Composites Containing Methacrylate/Polyurethane)

  • 김명호;김경환;이덕진;가출현;신성궝;김재환
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1357-1359
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    • 1994
  • In this study, in order to improve the problem that dielectric breakdown strength decrease remarkably at high temperature, simultaneous interpenetrating polymer networks method was Introduced so that epoxy insulating material could have stable temperature characteristics and stable dielectric breakdown characteristics at whole temperature range. So network structure of epoxy/$SiO_2$ composite material was changed by adding MA and MA/PU into epoxy resin. DC voltage is applied into the specimen fabricated by this method, and then the result was compared and investigated.

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대구 도심에 위치한 대규모 녹지공간의 냉섬 강도: 계절변화와 기상조건에의 관련성 (Cool Island Intensity in a Large Urban Green in Downtown Daegu: Seasonal Variation and Relationship to Atmospheric Condition)

  • 박명희;김해동
    • 한국환경과학회지
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    • 제19권1호
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    • pp.81-87
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    • 2010
  • Cool island intensity urban green space was investigated based in Dalsung Park, that is one of the largest parks in Daegu. Cool island intensity(CII), which is defined as the temperature difference between the green space and its surrounding built-up areas, shows time variations. A through-year measurement(2008-2009) of ground level air temperature revealed seasonal variation and relationship to the atmospheric condition of CII. The temperature variation in the park and the reference downtown Daegu was as same order as CII. The noontime CII is larger in summer than that in winter due to the leaf fall of the park trees. On the other hand, seasonal variation of nighttime CII is not so clear. The nighttime CII was larger under the stable atmosphere.

Synthesis of Core-Modified Porphyins and Studies of Their Temperature-dependent Tautomerism

  • 이창희;김한재;윤대위
    • Bulletin of the Korean Chemical Society
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    • 제20권3호
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    • pp.276-280
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    • 1999
  • The different core-modified porphyrins 21-thia-23-carba-12-aza-5,10-dimesityl-15,20-diphenylporphyrin (6), and their N(12)-methyl derivatives (8) were synthesized by acid-catalyzed [3+1] condensation of the corresponding 16-thia-5,10-dimesityltripyrromethanes and 2,4-bis[(α-hydroxy-α-phenyl)methyl]pyrrole. Spectroscopic evidence indicates the existence of two different tautomeric forms at room temperature in porphyrin (6). A third form of tautomer was observed when the temperature was lowered to 223 K. The most stable tautomer is one in which the nitrogenic proton resides outside the core of the macrocycle. The ratio of the three different tautomers (outer N-H/ two inner N-H, i.e. 6/12/13) was 1/l/0.5 in the case of (6) while the ratio of 1/l/0.3 was observed in the case of (10). In the case of 21-oxa-23-carba-12-aza-5,10,15,20-tetraphenylporphyrin (7), the only stable tautomeric form observed by 1H NMR was the one that nitrogenic proton resides inside the core on

Impact of Temperature and Alkalinity on Nitrogen Removal in the Start-up Period of Partial Nitrification in a Sequence Batch Reactor

  • Nguyen Van Tuyen;Tran Hung Thuan;Chu Xuan, Quang;Nhat Minh Dang
    • 공업화학
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    • 제34권5호
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    • pp.541-547
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    • 2023
  • The effect of temperature and influent alkalinity/ammonia (K/A) ratio on the start-up of the partial nitrification (PN) process for an activated sludge-based domestic wastewater treatment was studied. Two different sequence batch reactors (SBR) were operated at 26 ℃ and 32 ℃. The relationship between temperature and the concentration of free ammonia (FA) and free acid nitrite (FNA) was investigated. A stable PN process was achieved in the 32 ℃ reactor when the influent ammonium concentration was lower than 150 mg-N/L. In contrast, the PN process in the 26 ℃ reactor had a higher nitrite accumulation rate (NAR) and ammonium removal efficiency (ARE) when the influent ammonia concentration was increased to more than 150 mg-N/L. Then three different ranges of the K/A ratio were applied to an SBR reactor. In the K/A range of 2.48~1.65, the SBR reactor achieved the highest NAR ratio (75.78%). This ratio helps to achieve the appropriate level of alkalinity to maintain a stable pH and provide a sufficient amount of inorganic carbon source for the activity of microorganisms. At the same time, FA and FNA values also reached the threshold to inhibit nitrite-oxidizing bacteria (NOB) without a significant effect on ammonia-oxidizing bacteria (AOB). Results showed that the control of temperature and K/A ratio during the start-up period may be important in establishing a stable and steady PN process for the treatment of domestic wastewater.

축열식 고온공기 연소시스템에 대한 실험적 연구 (Experimental Study on High Temperature Air Regenerative Combustion System)

  • 양병옥;임인권
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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    • pp.189-200
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    • 1999
  • Combustion characteristics of a regenerative combustor for high temperature air combustion have experimentally studied. Temperature measurement on regenerative ceramic material and combustor has been carried out with changing equivalence ratio at constant turn-over period. Stable and unstable combustion region have been found and also detailed averaged temperature profile with respect to various air flow conditions have been obtained.

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온도보상형 온라인 굴절계를 이용한 해수의 염도 측정 (Salinity Determination Using Temperature Compensated On-Line Refractometer)

  • 최한욱;김영한
    • 한국항만학회지
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    • 제15권1호
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    • pp.99-105
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    • 2001
  • An on-line refractrometer made of easily obtainable materials is built to determine the salinity and temperature of sea water, and its performance is examined by applying the refractometer to known salt solution. Since refractive index and temperature are measured simultaneously, it is possible to compensate the effect of temperature for accurate measurement. The outcome of salinity measurement for the different concentrations of salt solution indicates that the device is suitable for the salinity measurement by yielding stable and reproducible reading.

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