• Title/Summary/Keyword: temperature stabilization

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Effect of Stabilization Processing Conditions on the Thermal Shrinkage and the Thermal Stability of Rayon Fabrics Untreated and Surface-Treated with Phosphoric Acid (인산처리 유·무에 따른 레이온직물의 열수축과 열안정성에 미치는 안정화 공정 조건의 영향)

  • Cho, Donghwan;Lee, Jongmoon;Park, Jong Kyoo
    • Journal of Adhesion and Interface
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    • v.5 no.3
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    • pp.10-17
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    • 2004
  • We investigated the effect of stabilization processing parameters on the thermal shrinkage, thermal stability and microstructure of rayon fabrics stabilized under various conditions such as heating rate, stabilization temperature, atmosphere gas, and chemical treatment. The presence and absence of phosphoric acid treatment and the heating rate have most importantly influenced the thermal shrinkage and the weight change of rayon fabrics. Especially, the phosphoric acid treatment decreases the reduction of thickness, length, and weight of the fabrics by about 80%, 20%, and 26%, respectively, in comparison with the untreated counterparts, showing the protective effectiveness of the thermal shrinkage involved. The thermal stability of stabilized rayon fabrics is also affected by all the processing conditions used: stabilization temperature, phosphoric acid treatment, atmosphere gas, and heating rate. In addition, the surface and diameter of the stabilized fiber significantly depend on the treatment of phosphoric acid prior to stabilization process.

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The Temperature Dependent C-H/V Constitutive Modeling for Magnesium Alloy Sheet (마그네슘 판재를 위한 온도 의존형 C-H/V 구성 모델에 관한 연구)

  • Park, J.H.;Lee, J.K.;Kim, H.Y.
    • Transactions of Materials Processing
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    • v.21 no.4
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    • pp.221-227
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    • 2012
  • The automotive and electronic industries have seriously considered the use of magnesium alloys because of their excellent properties such as strength to weight ratio, EMI shielding capability, etc. However, it is difficult to form magnesium alloys at room temperature because of the mechanical deformation related to twinning. Hence, magnesium alloys are normally formed at elevated temperatures. In this study, a temperature dependent constitutive model, the C-H/V model, for the magnesium alloy AZ31B sheet is proposed. A hardening law based on nonlinear kinematic and H/V(Hollomon/Voce) hardening model is used to properly characterize the Bauschinger effect and the stabilization of the flow stress. Material parameters were determined from a series of uni-axial cyclic experiments(C-T-C) with the temperature ranging between 150 and $250^{\circ}C$. The developed models are fit to experimental data and a comparison is made.

Structural evolution and kinetic study of high isotacticity poly(acrylonitrile) during isothermal pre-oxidation

  • Zhang, Li;Dai, Yongqiang;Kai, Yi;Jin, Ri-Guang
    • Carbon letters
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    • v.12 no.4
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    • pp.229-235
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    • 2011
  • Isotactic polyacrylonitrile (PAN) with triad isotacticity of 0.53, which was determined by $^{13}C$ NMR, using dialkylmagnesium as an initiator, was successfully synthesized. Isothermal treatment of iso-PAN was conducted in air at 200, 220, 250 and $280^{\circ}C$. Structural evolutions and chemical changes were studied with Fourier transformation infrared and wide-angle X-ray diffraction during stabilization. A new parameter $CNF={I_{2240cm}}^{-1}/ ({I_{1595cm}}^{-1}+f^*{I_{1595cm}}^{-1})$ was defined to evaluate residual nitrile groups. Crystallinity and crystal size were calculated with X-ray diffraction dates. The results indicated that the nitrile groups had partly converted into a ladder structure as stabilization proceeded. The rate of reaction increased with treatment temperature; crystallinity and crystal size decreased proportionally to pyrolysis temperature. The iso-conversional method coupled with the Kissinger and Flynn-Wall-Ozawa methods were used to determine kinetic parameters via differential scanning calorimetry analysis with different heating rates. The active energy of the reaction was 171.1 and 169.1 kJ/mol, calculated with the two methods respectively and implied the sensitivity of the reaction with temperature.

A Study on the Stabilization Effects of 1-Chlorobutadiene-Butadiene Copolymer by Triazine Thiol Derivative (Triazine Thiol 유도체(誘導體)에 의한 1-Chlorobutadiene-Butadiene Copolymer의 안정화효과(安定化效果)에 관한 연구(硏究))

  • Yoo, Chong-Sun;Yamashita, S.;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.22 no.2
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    • pp.109-120
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    • 1987
  • In this study, as one of the developing ways of the functional elastomer, improvement of the functionality of CB-BR was attemped through stabilization. At first the stabilization effect of CB-BR and the concentration dependancy in CB-BR were determined. Then, triazine thiol derivative(BPTT) was synthesized by reacting p-aminodiphenylamine with cyanuric chloride. Further the functional mechanism and the effects of the antioxidants were investigated using BPTT together with other various antioxidants in liquid and solid states. The results obtained are as follows: 1) The aging of CB-BR depended on the concentration and temperature. Thus, at a low temperature of $50^{\circ}C$, the aging proceeded with gel formation; at high temperature above $100^{\circ}C$ and in above 4wt% concentration, the aging occured by the formation of gel. And in concentrations below that, the aging proceeds with a decomposition caused by oxygen attacked to elastomer molecules. 2) The effect of antioxidation of CB-BR in the liquid state was at it's best when the MBIZ and BPTT were used at $110^{\circ}C$, 4hrs after the oxidation. 3) The effect of antioxidation of CB-BR in the solid state was the best choice the simultaneous use of NDBC and BPTT at $50^{\circ}C$, 30days after the oxidation.

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Numerical Investigation of On-orbit Thermal Characteristics for Cube Satellite with Permanent Magnet Attitude Stabilization Method (영구자석 안정화 자세제어 방식이 적용된 큐브위성의 열적 특성분석)

  • Kang, Soo-JIn;Jung, Hyun-Mo;Oh, Hyun-Ung
    • Journal of Aerospace System Engineering
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    • v.7 no.3
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    • pp.26-32
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    • 2013
  • Passive attitude stabilization method has been widely usde for attitude determination and control of cube satellite due to its advantage of system simplicity. The permanent magnet installed on the cube satellite passively controls the attitude of the satellite such that the satellite is aligned with the earth magnetic field. In this paper, on-orbit thermal behavior of the cube satellite with the permanent magnet attitude stabilization method has been investigated through on-orbit thermal analysis. THe orbit profile obtained from the aforementioned attitude control method has been reflected in the analysis. The analysis results indicate that the thermal design proposed in this study is effective for satisfying the temperature requirements of the commericial mission equipments.

A Study on the Optical Communication System using Heterodyne Detection Method(Design of Thermal Chamber for LD Frequency Stabilization) (헤테로다인검파방식을 이용한 광통신시스템에 관한 연구 (LD의 주파수안정화를 위한 항온기설계 에 관하여))

  • 임명섭;홍완희;박한규
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.10 no.4
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    • pp.168-174
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    • 1985
  • The wavelength and output power of semiconductor laser is varying sensitively with temperature. It must be stabilized by the aid of some proper stabilization technique in order to use it as a radiative source for heterodyne optical communication, optical metrology, and high resolution spectroscopy. In this paper, the temperature of the thermal chamber was variable from -27$-50^{\circ}C$ to +73$-50^{\circ}C$ and the temperature stability was within ${\pm}2m{\circ}K$ or better.

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A Study on the Stabilization Scheme of Optical Source for Precision Measurement (정밀측정을 위한 안정된 광원에 관한 연구)

  • 김지대;서호성;이동주
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.04a
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    • pp.265-271
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    • 2003
  • This study is for the stable optical source in order to get the precision measurement, which contributes to help the laser frequency and the output to be settled. The laser optical frequency is changed by the length of resonance cavity. The length variation of the laser resonance amplitude is affected by the thermal expansion of that system. So, we try not only to adjust the temperature of the laser tube using the heater for fine length of resonance cavity, but also to maintain the fixed temperature of the resonance cavity for outputting the safe laser optical frequency. Therefore, we must take materials with the thermal expansion of the supporting system, which is closer to it of the laser resonance cavity. Using the materials, we can promote to stabilize the temperature of it. In advance, we also plan to get the settlement of the laser frequency and the output in the long km, optimizing and stabilizing the system.

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Chemical Stability through CO2 Curing of Cement Paste Exposed to High Temperature (고온 환경에 노출된 시멘트 페이스트의 DCG 양생을 통한 화학적 안정화)

  • Kim, Min-Hyouck;Cho, Hyeon-Seo;Lee, Gun-Cheo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.73-74
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    • 2019
  • In order to examine the chemical stabilization through DCG curing of cement paste exposed to high temperature environment, we produced a sample of 40% W/C cement paste and heated it for 180 minutes under the heating temperature of $800^{\circ}C$. The DCG curing time was 6, Three time conditions were divided into 12 and 18 hours. As a result of XRD analysis, Calcite ($CaCO_3$) was found in Theta 29.4, 40, and 46.5o. As the curing time increased, the peak of Calcite also increased, which is due to the increased reaction time with DCG. Therefore, Calcite produced through DCG curing seems to have stabilized chemically by filling the pores generated by heating.

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Direct Observation of Premixed Flame Propagation Characteristics in an Annular Coaxial 5-Tubes Burner (환형 5중 동축관 연소기 내부에서의 예혼합 화염의 전파 특성 직접 관찰)

  • Cho, Moon Soo;Baek, Da Bin;Kim, Nam Il
    • Journal of the Korean Society of Combustion
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    • v.18 no.3
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    • pp.24-30
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    • 2013
  • Flame stabilization characteristics of premixed flames in an annular coaxial 5-tubes burner (AC5TB) were investigated experimentally. The AC5TB was made of five quartz tubes, and the flame stabilization conditions in that burner were investigated with the variation of equivalence ratio and the flow velocities. Flame behaviors inside of narrow annular tubes could be observed directly. Overall flame stabilization conditions were similar to that of the previous study, while the flame behaviors and structures were different mainly due to the controlled uniform distribution of the velocities in channels. Flame flashback conditions were thought to be governed by the competition between heat release rate, heat loss and heat recirculation in each channel. Stationary flames at a fixed location were compared in its velocity distribution and burned gas temperature across the channel. This AC5TB can be a basic configuration for the development of flame stabilization model of porous media combustors, and it will help understand about the real behavior of flames in meso-scale combustion spaces.