• Corrosion Science and Technology
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• v.20 no.4
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• pp.183-188
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• 2021

The increasing demand for energy storage in mobile electronic devices and electric vehicles has emphasized the importance of electrochemical energy storage devices such as Li-ion batteries (LIBs) and supercapacitors. For reversible Li storage, alternative anode materials are actively being developed. In this study, we designed and fabricated an Nb₂O₅-Li₃VO₄ composite for use as an anode material in LIBs and hybrid supercapacitors. Nb₂O₅ powders were dissolved into a solution and the precursors were precipitated onto Li₃VO₄ through a simple, low-temperature hydrothermal reaction. The annealing process yielded an Nb₂O₅-Li₃VO₄ composite that was characterized by X-ray diffraction, electron microscopy, and X-ray photoelectron spectroscopy. Electrochemical tests revealed that the Nb₂O₅-Li₃VO₄ composite electrode demonstrated increased capacities of approximately 350 and 140 mAh g^-1 at 0.1 and 5 C, respectively, were maintained up to 1000 cycles. The reversible capacity and rate capability of the composite electrode were enhanced compared to those of pure Nb₂O₅-based electrodes. These results can be attributed to the microstructure design of the synthesized composite material.

• Journal of Ceramic Processing Research
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• v.19 no.5
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• pp.372-377
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• 2018

MgO or gadolinium-doped ceria (GDC, $Ce_{0.9}Gd_{0.1}O_{2-{\delta}}$) was added as a promoter to improve the oxygen transfer kinetics of $MgMnO_3$ oxygen carrier material for chemical looping combustion. Neither MgO nor GDC reacted with $MgMnO_3$, even at the high temperature of $1100^{\circ}C$. The average oxygen transfer capacities of $MgMnO_3$, 5 wt% $MgO-MgMnO_3$, and 5 wt% $GDC-MgMnO_3$ were 8.74, 8.35, and 8.13 wt%, respectively. Although the addition of MgO or GDC decreased the oxygen transfer capacity, no further degradation was observed during their use in 5 redox cycles. The addition of GDC significantly improved the conversion rate for the reduction reaction of $MgMnO_3$ compared to the use of MgO due to an increase in the surface adsorption process of $CH_4$ via oxygen vacancies formed on the surface of GDC. On the other hand, the conversion rates for the oxidation reaction followed the order 5 wt% $GDC-MgMnO_3$ > 5 wt% $MgO-MgMnO_3$ >> $MgMnO_3$ due to morphological change. MgO or GDC particles suppressed the grain growth of the reduced $MgMnO_3$ (i.e., (Mg,Mn)O) and increased the specific surface area, thereby increasing the number of active reaction sites.

• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.668-673
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• 2020

In this work, ultrathin and two-dimensional (2D) cobalt hydroxide [Co(OH)2] nanosheets were synthesized by a sonication assisted liquid-phase exfoliation of bulk Co(OH)2. The resulting exfoliated Co(OH)2 is a hexagonal mono-layered nanosheet with a high specific surface area of 27.5 ㎡ g-1. The depolymerization of polyethylene terephthalate (PET) based on glycolysis reaction was also performed using an exfoliated Co(OH)2 catalyst. Excellent catalytic reaction performances were demonstrated; a high PET conversion and bis(2-hydroxyethyl) terephthalate (BHET) yield of both 100% using the nanosheet catalyst were achieved within a reaction time and temperature of 30 min and 200 ℃, respectively. The long-term stability of exfoliated Co(OH)2 catalysts was also demonstrated by recyclability tests of the catalyzed glycolysis reaction of PET over four cycles, showing both 100% of high PET conversion and BHET yield.

• Membrane Journal
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• v.32 no.6
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• pp.496-513
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• 2022

In this study, we sought to verify the applicability of anion exchange membrane water electrolysis system using FAA-3-50, Neosepta-ASE, Sustainion grade T, and Fujifilm type 10, which are commercial anion exchange membranes. The morphology of the commercial membranes and the elements on the surface were analyzed using SEM/EDX to confirm the distribution of functional groups included in the commercial membranes. In addition, mechanical strength and decomposition temperature were measured using UTM and TGA to check whether the driving conditions of the water electrolyte were satisfied. The ion exchange capacity and ion conductivity were measured to understand the performance of anion exchange membranes, and the alkaline resistance of each commercial membrane was checked and durability test was performed because they were driven in an alkaline environment. Finally, a membrane-electrode assembly was manufactured and a water electrolysis single cell test was performed to confirm cell performance at 60℃, 70℃, and 80℃. The long-term cell test was measured 20 cycles at other temperatures to compare water electrolysis performance.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.178-178
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• 2023

Drought and flooding have historically coexisted in Korea, occurring at different times and with varying cycles and trends. The drought indicators measured were (PDSI), (SPI), and (SPEI) in order to statistically analyze the annual or periodic drought occurrence and objectively evaluate statistical characteristics such as the periodicity, tendency, and frequency of occurrence of droughts in the Doam watershed. To compute potential evapotranspiration (PET), both Thornthwaite (Thor) and Penman-Monteith (PM) parameterizations were considered, and the differences between the two PET estimators were analyzed. Hence, SPIs 3 and SPIs 6 revealed a tendency to worsen drought in the spring and winter and a tendency to alleviate drought in the summer in the study area. The seasonal variability trend did not occur in the SPIs 12 and PDSI, as it did in the drought index over a short period. As a result of the drought trend study, the drought from winter to spring gets more severe, in addition to the duration of the drought, although the periodicity of the recurrence of the drought ranged from 3 years to 6 years at the longest, indicating that SPIs 3 showed a brief time of around 1 year. SPIs 6 and SPIs 12 had a term of 4 to 6 years, and PDSI had a period of roughly 6 years. Based on the indicators of the PDSI, SPI, and SPEI, the drought severity increases under climate change conditions with the decrease in precipitation and increased water demand as a consequence of the temperature increase. Therefore, our findings show that national and practical measures are needed for both winter and spring droughts, which happen every year, as well as large-scale and extreme droughts, which happen every six years.

• Resources Recycling
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• v.31 no.6
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• pp.3-17
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• 2022

The cement industry, which is an energy-intensive and high carbon dioxide emission industry, requires strategy for carbon neutrality and sustainable development. Most domestic cement companies are generating electricity by waste heat recovery system to improve energy efficiency during cement processes; however, few studies exist on recycling of energy related to this. Certain countries with high cement production researched on modifying the conventional waste heat recovery system to maximize waste heat recovery using various methods such as applying the Rankine cycle depending on the temperature, comparing working fluids, applying two or more Rankine cycles, and combining with other industries. In this study, we reviewed the research direction for energy efficiency improvement by summarizing waste heat recovery and utilization methods in the domestic and overseas cement industries.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.2
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• pp.226-233
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• 2023

In this study, we compared the performance of several refrigeration cycles using different refrigerants and utilizing the cold heat of liquefied natural gas (LNG) for the liquefaction of carbon dioxide. The final conditions for the liquefied CO₂ were set to -20℃ and 20 bar. The refrigerants used included R404a, ammonia, propane, and propylene using a vapor recompression refrigeration cycle. For the refrigeration cycle, the CO₂ at room temperature and pressure was compressed in a two-stage compression process with an intermediate cooling stage using a refrigeration unit. To compare with the liquefaction process using refrigeration, we compressed the CO₂ to 8 bar in a single compression stage and cooled it to around -50℃ using the cold heat of the LNG before liquefying it. Results showed that using ammonia as the refrigerant required the least amount of compressor power for the liquefaction process, and the heat transfer area of the evaporator was the smallest when using propylene as the refrigerant. Using the cold heat of LNG instead of refrigeration using R404a resulted in approximately 69% less energy consumption.

• Composites Research
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• v.20 no.3
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• pp.37-42
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• 2007

Tensile residual stress is occurred by difference of coefficients of thermal expansion between fiber and matrix is one of the serious problems in metal matrix composite(MMC). TiNi alloy fiber was used to solve the problem of the tensile residual stress as the reinforced material. TiNi alloy fiber improves the tensile strength of composite with occurring of compressive residual stress in the matrix by its shape memory effect. A hot press method was used to create the optimal fabrication condition for a Shape Memory Alloy(SMA) composite. The bonding effect of the matrix and the reinforcement within the SMA composite by the hot press method was strengthened by cold rolling. In addition, acoustic emission technique was used to quantify the microscopic damage behavior of cold rolled TiNi/A16061 shape memory alloy composite at low temperature. The damage degree for the specimen that underwent thermal shock cycles was also discussed.

• Restorative Dentistry and Endodontics
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• v.46 no.4
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• pp.54.1-54.10
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• 2021

Objectives: The purpose of this study was to quantify phase transformation after hydrofluoric acid (HF) etching at various concentrations on the surface of yttria-stabilized tetragonal zirconia polycrystal (Y-TZP), and to evaluate changes in bonding strength before and after thermal cycling. Materials and Methods: A group whose Y-TZP surface was treated with tribochemical silica abrasion (TS) was used as the control. Y-TZP specimens from each experimental group were etched with 5%, 10%, 20%, and 40% HF solutions at room temperature for 10 minutes. First, to quantify the phase transformation, Y-TZP specimens (n = 5) treated with TS, 5%, 10%, 20% and 40% HF solutions were subjected to X-ray diffraction. Second, to evaluate the change in bond strength before and after thermal cycling, zirconia primer and MDP-containing resin cement were sequentially applied to the Y-TZP specimen. After 5,000 thermal cycles for half of the Y-TZP specimens, shear bond strength was measured for all experimental groups (n = 10). Results: The monoclinic phase content in the 40% HF-treated group was higher than that of the 5%, 10%, and 20% HF-treated groups, but lower than that of TS-treated group (p < 0.05). The 40% HF-treated group showed significantly higher bonding strength than the TS, 5%, and 10% HF-treated groups, even after thermal cycling (p < 0.05). Conclusions: Through this experiment, the group treated with SiO₂ containing air-borne abrasion on the Y-TZP surface showed higher phase transformation and higher reduction in bonding strength after thermal cycling compared to the group treated with high concentration HF.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.2A
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• pp.121-129
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• 2010

In this paper, the characteristics of high damping rubber bearing were studied through various prototype test. The characteristics of HDRB were dependent on displacements, repeated cycles, frequencies, vertical pressure, temperature, the capability of shear deformation and the vertical stiffness. The prototype test showed that the displacement was the most governing factor influencing on characteristics of HDRB. The effective stiffness and equivalent damping of HDRB were decreased with displacement, and increased with frequency. The effective stiffness was decreased with high vertical pressure, while the equivalent damping was increased. In which, the equivalent damping was more dependent on the vertical pressure than the effective stiffness. According to the results of this study, more careful examination is required to design the effective stiffness and equivalent damping ratio considering the dependencies of design displacement and exciting velocity.