• Title/Summary/Keyword: technology frontier

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Influence of kneading ratio on the binding interaction of coke aggregates on manufacturing a carbon block

  • Kim, Jong Gu;Kim, Ji Hong;Bai, Byong Chol;Choi, Yun Jeong;Im, Ji Sun;Bae, Tae-Sung;Lee, Young-Seak
    • Carbon letters
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    • v.28
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    • pp.24-30
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    • 2018
  • Coke aggregates and carbon artifacts were produced to investigate the interactions of coke and pitch during the kneading process. In addition, the kneading ratio of the coke and binder pitch for the coke aggregates was controlled to identify the formation of voids and pores during carbonization at $900^{\circ}C$. Experiments and thermogravimetric analysis revealed that carbon yields were improved over the theoretical yield calculated by the weight loss of the coke and binder pitch; the improvement was due to the binding interactions between the coke particles and binder pitch by the kneading process. The true, apparent, and bulk densities fluctuated according to the kneading ratio. This study confirmed that an excessive or insufficient kneading ratio decreases the density with degradation of the packing characteristics. The porosity analysis indicated that formation of voids and pores by the binder pitch increased the porosity after carbonization. Image analysis confirmed that the kneading ratio affected the formation of the coke domains and the voids and pores, which revealed the relations among the carbon yields, density, and porosity.

Probing the movement of helix F region and the stepwise insertion of reactive site loop in $\alpha_1$-Antitrypsin variants

  • Baek, Je-Hyun;Lee, Cheolju;Kang, Un-Beom;Kim, Joon;Yu, Myeong-Hee
    • Proceedings of the Korean Biophysical Society Conference
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    • 2003.06a
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    • pp.63-63
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    • 2003
  • $\alpha$$_1$-Antityrpsin is a member of the serine protease inhibitor (SERPIN) family that shares a common tertiary structure. The reactive site loop (RSL) of serpins is exposed at one end of the molecule for protease binding. Upon cleavage by a target protease, the RSL is inserted into the major $\beta$-sheet A, which is a necessary process for formation of a tight inhibitory complex. Various biochemical and structural studies suggest that the rate of the RSL insertion upon binding a target protease is critical for inhibitory activity, and it is thought that helix F region (thFs3A and helix F) located in front of $\beta$-sheet A, should be lifted for the loop insertion during complex formation.

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Spray coating of electrochemically exfoliated graphene/conducting polymer hybrid electrode for organic field effect transistor

  • Kim, Youn;Kwon, Yeon Ju;Hong, Jin-Yong;Park, Minwoo;Lee, Cheol Jin;Lee, Jea Uk
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.399-405
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    • 2018
  • We report the fabrication of organic field-effect transistors (OFETs) via spray coating of electrochemically exfoliated graphene (EEG) and conducting polymer hybrid as electrodes. To reduce the roughness and sheet resistance of the EEG electrodes, subsequent coating of conducting polymer (poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)) and acid treatment was performed. After that, active channel layer was developed by spin coating of semiconducting poly(3-hexylthiophene) on the hybrid electrodes to define the bottom gate bottom contact configuration. The OFET devices with the EEG/PEDOT:PSS hybrid electrodes showed a reasonable electrical performances (field effect mobility = $0.15cm^2V^{-1}\;s^{-1}$, on/off current ratio = $10^2$, and threshold voltage = -1.57V). Furthermore, the flexible OFET devices based on the Polydimethlsiloxane (PDMS) substrate and ion gel dielectric layer exhibited higher electrical performances (field effect mobility = $6.32cm^2V^{-1}\;s^{-1}$, on/off current ratio = $10^3$, and threshold voltage = -1.06V) and excellent electrical stability until 1000 cycles of bending test, which means that the hybrid electrode is applicable to various organic electronic devices, such as flexible OFETs, supercapacitors, organic sensors, and actuators.

Photofield-Effect in Amorphous InGaZnO TFTs

  • Fung, Tze-Ching;Chuang, Chiao-Shun;Mullins, Barry G.;Nomura, Kenji;Kamiya, Toshio;Shieh, Han-Ping David;Hosono, Hideo;Kanicki, Jerzy
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1208-1211
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    • 2008
  • We study the amorphous In-Ga-Zn-O thin-film transistors (TFTs) properties under monochromatic illumination ($\lambda=420nm$) with different intensity. TFT off-state drain current ($I_{DS_off}$) was found to increase with the light intensity while field effect mobility ($\mu_{eff}$) is almost unchanged; only small change was observed for sub-threshold swing (S). Due to photo-generated charge trapping, a negative threshold voltage ($V_{th}$) shift is also observed. The photofield-effect analysis suggests a highly efficient UV photocurrent conversion in a-IGZO TFT. Finally, a-IGZO mid-gap density-of-states (DOS) was extracted and is more than an order lower than reported value for a-Si:H, which can explain a good switching properties of the a-IGZO TFTs.

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Implementation of Adaptive Movement Control for Waiter Robot using Visual Information

  • Nakazawa, Minoru;Guo, Qinglian;Nagase, Hiroshi
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2009.01a
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    • pp.808-811
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    • 2009
  • Robovie-R2 [1], developed by ATR, is a 110cm high, 60kg weight, two wheel drive, human like robot. It has two arms with dynamic fingers. It also has a position sensitive detector sensor and two cameras as eyes on his head for recognizing his surrounding environment. Recent years, we have carried out a project to integrate new functions into Robovie-R2 so as to make it possible to be used in a dining room in healthcare center for helping serving meal for elderly. As a new function, we have developed software system for adaptive movement control of Robovie-R2 that is primary important since a robot that cannot autonomously control its movement would be a dangerous object to the people in dining room. We used the cameras on Robovie-R2's head to catch environment images, applied our original algorithm for recognizing obstacles such as furniture or people, so as to control Roboie-R2's movement. In this paper, we will focus our algorithm and its results.

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NDVI RESPONSES TO THE FOREST CANOPY AND FLOOR IN EASTERN SIBERIA

  • Suzuki, Rikie;Kobayashi, Hideki;Delbart, Nicolas;Hiyama, Tetsuya;Asanuma, Jun
    • Proceedings of the KSRS Conference
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    • 2007.10a
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    • pp.325-328
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    • 2007
  • We discuss the Normalized Difference Vegetation Index (NDVI) of the forest canopy and floor separately based on airborne spectral reflectance measurements and simultaneous airborne land surface images acquired around Yakutsk, Siberia in 2000. The aerial land surface images were visually classified into four forest types: no-green canopy and snow floor (Type-1), green canopy and snow floor (Type-2), no-green canopy and no-snow floor (Type-3), and green canopy and no-snow floor (Type-4). The mean NDVI was calculated for these four types. Although Type-2 had green canopy, the NDVI was rather small (0.17) because of high reflection from the snow cover on the floor. Type-3, which had no green canopy, indicated considerably large NDVI (0.45) due to the greenness of the floor. Type-4 had the largest NDVI (0.75) because of the greenness of both the canopy and floor. These results reveal that the NDVI depends considerably on forest floor greenness and snow cover in addition to canopy greenness.

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Observation of Unusual Structural Phase Transition in $VO_2$ Thin Film on GaN Substrate

  • Yang, Hyeong-U;Son, Jeong-In;Cha, Seung-Nam;Kim, Jong-Min;Gang, Dae-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.573-573
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    • 2012
  • High quality $VO_2$ thin films were successfully grown on GaN substrate by optimizing oxygen partial pressure during the growth using RF sputtering technique. The $VO_2$ thin film grown on GaN substrate exhibited an unusual metal insulator transition behavior, which was known to be observed only either in doped sample or under uniaxial stress. Raman spectra also confirmed that metal insulator transition occurred from monoclinic M1 to rutile R phase via monoclinic M2 phase with increasing temperature. We believe that large lattice mismatch between $VO_2$ and GaN substrate may cause M2 phase to be thermodynamically stable. Optical transmittance and its electrical switching behavior were carefully investigated to elucidate the underlying physics of its metal insulator transition behavior. This study may lead to a unique opportunity to better understand the growth mechanism of M2 phase dominant $VO_2$ thin films.

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Phytogenic silver nanoparticles (Alstonia scholaris) incorporated with epoxy coating on PVC materials and their biofilm degradation studies

  • Supraja, Nookala;Tollamadugu, Naga Venkata Krishna Vara Prasad;Adam, S.
    • Advances in nano research
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    • v.4 no.4
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    • pp.281-294
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    • 2016
  • The advantages of nano-scale materials (size 1-99 nm in at least in one dimension) could be realized with their potential applications in diversified avenues. Herein, we report for the first time on the successful synthesis of homogeneous epoxy coatings containing phytogenic silver nanoparticles (Ag) on PVC and glass substrates by room-temperature curing of fully mixed epoxy slurry diluted by acetone. Alstonia scholaris bark extract was used to reduce and stabilize the silver ions. The surface morphology and mechanical properties of these coatings were characterized using the techniques like, UV-Vis (UV-Visible) spectrophotometry, X-ray diffraction (XRD), Fourier transform infrared spectrophotometry (FT-IR), Epifluorescence microscopy and scanning electron microscopy (SEM). The effect of incorporating Ag nanoparticles on the biofilm (scale) resistant epoxy-coated PVC was investigated by total viable counts ($CFU/cm^2$) from epoxy coating from (Initial) $1^{st}$ day to $25^{th}$ days. The phytogenic Ag nanoparticles were found to be significantly improving the microstructure of the coating matrix and thus enhanced the anti-biofilm performance of the epoxy coating. In addition, the antimicrobial mechanism of Ag nanoparticles played an important role in improving the anti-biofilm performance of these epoxy coatings.

Monitoring Cathodic Shielding and Corrosion under Disbonded Coatings

  • Varela, F.;Tan, M. YJ;Hinton, B.;Forsyth, M.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.109-114
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    • 2017
  • Monitoring of corrosion is in most cases based on simulation of environmental conditions on a large and complex structure such as a buried pipeline using a small probe, and the measurement of thermodynamics and kinetics of corrosion processes occurring on the probe surface. This paper presents a hybrid corrosion monitoring probe designed for simulating deteriorating conditions wrought by disbonded coatings and for measuring current densities and distribution of such densities on a simulated pipeline surface. The concept of the probe was experimentally evaluated using immersion tests under cathodic protection (CP) in high resistivity aqueous solution. Underneath the disbonded area, anodic currents and cathodic currents were carefully measured. Anodic current densities were used to calculate metal loss according to Faraday's law. Calculated corrosion patterns were compared with corrosion damage observed at the surface of the probe after a series of stringent tests. The capability of the probe to measure anodic current densities under CP, without requiring interruption, was demonstrated in high resistivity aqueous solution. The pattern of calculated metal loss correlated well with corrosion products distribution observed at the array surface. Working principles of the probe are explained in terms of electrochemistry.