• Title/Summary/Keyword: system separation method

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Simulation Study on the Application of LNG Cold Energy for Hydrogen Liquefaction Process (수소액화공정에서 LNG 냉열 적용에 관한 시뮬레이션 연구)

  • HAN, DANBEE;BYUN, HYUNSEUNG;BAEK, YOUNGSOON
    • Journal of Hydrogen and New Energy
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    • v.31 no.1
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    • pp.33-40
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    • 2020
  • As hydrogen utilization becomes more active recently, a large amount of hydrogen should be supplied safely. Among the three supply methods, liquefied hydrogen, which is an optimal method of storage and transportation convenience and high safety, has a low temperature of -253℃, which is complicated by the liquefaction process and consumes a lot of electricity, resulting in high operating costs. In order to reduce the electrical energy required for liquefaction and to raise the efficiency, hydrogen is cooled by using a mixed refrigerant in a precooling step. The electricity required for the precooling process of the mixed refrigerant can be reduced by using the cold energy of LNG. Actually, LNG cold energy is used in refrigeration warehouse and air liquefaction separation process, and a lot of power reduction is achieved. The purpose of this study is to replace the electric power by using LNG cold energy instead of the electric air-cooler to lower the temperature of the hydrogen and refrigerant that are increased due to the compression in the hydrogen liquefaction process. The required energy was obtained by simulating mixed refrigerant (MR) hydrogen liquefaction system with LNG cold heat and electric system. In addition, the power replacement rate of the electric process were obtained with the pressure, the temperature of LNG, the rate of latent heat utilization, and the hydrogen liquefaction capacity, Therefore, optimization of the hydrogen liquefaction system using LNG cold energy was carried out.

Mixed Micellar Properties of DPC with Other Cationic Surfactants (DTAB, TTAB, and CDEAB) (DPC와 다른 양이온성 계면활성제(DTAB, TTAB 및 CDEAB)와의 혼합마이셀화에 관한 연구)

  • Lee, Byung Hwan
    • Journal of the Korean Chemical Society
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    • v.42 no.5
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    • pp.519-525
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    • 1998
  • The critical micelle concentration $(CMC^{\ast})$ and the counterion binding constant (B) in a micellar state of the mixed surfactant systems of dodecylpyridinium chloride (DPC) with dodecyltrimethylammonium bromide (DTAB), tetradecyltrimethylammonium bromide (TTAB), and cetyldimethylethylammonium bromide (CDEAB) were determined at $25^{\circ}C$ as a function of ${\alpha}_1$ (the overall molc fraction of DPC) by the use of electric conductivity method. Various thermodynamic parameters $(X_{i},\;{\gamma}_{I},\;C_{i},\;a^{M}_{i}, \beta,\;{\Delta}H_{mix}, \;and\; {\Delta}G^{o}_{m})$ for the micellization of DPC/DTAB, DPC/TTAB, and DPC/CDEAB mixtures were calculated and analyzed for each system by means of the equations derived from the pseudophase separation model. The results show that the DPC/DTAB mixed system has the greatest deviation and the DPC/CDEAB mixed system has the smallest deviation from the ideal mixed micellar model.

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A Two-Phase Shallow Semantic Parsing System Using Clause Boundary Information and Tree Distance (절 경계와 트리 거리를 사용한 2단계 부분 의미 분석 시스템)

  • Park, Kyung-Mi;Hwang, Kyu-Baek
    • Journal of KIISE:Computing Practices and Letters
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    • v.16 no.5
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    • pp.531-540
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    • 2010
  • In this paper, we present a two-phase shallow semantic parsing method based on a maximum entropy model. The first phase is to recognize semantic arguments, i.e., argument identification. The second phase is to assign appropriate semantic roles to the recognized arguments, i.e., argument classification. Here, the performance of the first phase is crucial for the success of the entire system, because the second phase is performed on the regions recognized at the identification stage. In order to improve performances of the argument identification, we incorporate syntactic knowledge into its pre-processing step. More precisely, boundaries of the immediate clause and the upper clauses of a predicate obtained from clause identification are utilized for reducing the search space. Further, the distance on parse trees from the parent node of a predicate to the parent node of a parse constituent is exploited. Experimental results show that incorporation of syntactic knowledge and the separation of argument identification from the entire procedure enhance performances of the shallow semantic parsing system.

Development of Coolant/Waste-oil Separating and Cooling System with Chip Treatment (칩 처리가 포함된 절삭유/폐유 분리 및 냉각 시스템 개발)

  • Kim, Joong-Seon;Lee, Dong-Seop;Wang, Duck-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.3
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    • pp.16-23
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    • 2017
  • For most machine tools, it is necessary to remove chips and coolant oil because it they will continue to be created during the manufacture of workpieces. Existing products that are in use are installed and used as they reflect depending on the characteristics of each device separately. This study proposes a method to remove the security chip as well as developing an integrated system capable of reducing coolant damage. The Leverage AutoCAD and CATIA program was used for 2D and 3D design, shapes were identified by utilizing the KeyShot program, and the load and displacement analysis of the development apparatus was performed utilizing the ANSYS program. After the prototype underwent sufficient design review, the mixed oil separation device had a complete sensor control program using the LabVIEW program. The chip design process for transferring experiments and experiments on the mixed oil cooling device were developed for performance tests of the product. The final product resulted in an increase in space utilization during commercialization, reduced installation costs, and caused social effects such as pulmonary flow reduction, which, through the economic costs, reduces pollution, resulting in various benefits to the industry, such as deceased errors in the workplace decreases.

Development of Molecular Dynamics Model for Water Electrolysis Ionomer (수전해용 이오노머 분자동역학 모델 개발)

  • Kang, Hoseong;Park, Chi Hoon;Lee, Chang Hyun
    • Membrane Journal
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    • v.30 no.6
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    • pp.433-442
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    • 2020
  • In this study, in order to build a molecular dynamics simulation model of ionomer for water electrolysis, an ionomer model that reflects the characteristics of a water electrolysis system in which excess water molecules exist was compared to an ionomer built according to the conventional simulation method of the fuel cells membrane. The final ionomer MD models have a strong phase separation and water channel that is one of the important characteristics of the perfluorinated ionomer, and are stable and water-insoluble under excessive water and high temperature conditions. In the ionomer MD models built in this study, the excess water molecules decrease an ion conductivity due to the dilution of ions, but increase a hydrogen diffusivity. Therefore, it is necessary to design the molecular structure of ionomers for water electrolysis in experimental studies as well as molecular dynamics studies according to the characteristics of the water electrolysis system reported in this study.

A Case Study on MIL-STD-1760E based Test Bench Implementation for Aircraft-Weapon Interface Testing (항공기-무장간의 연동 시험을 위한 MIL-STD-1760E 기반 테스트 벤치 구축 사례 연구)

  • Kim, Tae-bok;Park, Ki-seok;Kim, Ji-hoon;Jung, Jae-won;Kwon, Byung-gi
    • Journal of Advanced Navigation Technology
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    • v.22 no.2
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    • pp.57-63
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    • 2018
  • In the case of aircraft-launched guided weapons, various interface tests such as MIL-STD-1760 based power source, discrete signal, MUX communication as well as BIT of missile can verify system safety and reliability. The purpose of this case study is to develop a test bench based on MIL-STD-1760E for interoperability testing between aircraft and weapons. We proposed a testing method of the launch sequence based on the defined TIME LINE in the development phase of the missile system from the application of the power of the missile to the targeting, the transfer order, and the missile separation process. Furthermore, it will be a reference model that can maximize the verification scope in the development phase of the air to surface missile system by simulating abnormal situation to the inert missile using the error insertion function.

Determination of Volatile Organic Compounds emitted from Municipal Solid Waste Landfill Site by Thermal Desorption-Cryofocusing-GC/FID/FPD (열탈착-저온농축-GC/FID/FPD에 의한 도시 생활폐기물 매립장에서 방출되는 휘발성 유기화합물의 측정에 관한 연구)

  • Kim, Man-Goo;Jung, Young-Rim;Seo, Young-Min;Nam, Sung-Hyun;Kwon, Young-Jin
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.274-285
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    • 2001
  • In this study, the thermal desorption-cryofocusing-gas chromatographic(TD-C-GC) method was developed for determination of volatile organic compounds(VOCs) in ambient air and was applied at the municipal solid waste landfill sites. On-column cryofocusing was possible only with a 100 ml dewars bottle in TD-C-GC method with a stainless steel column. However, high operating pressure was needed for purging VOCs from the absorbent trap, which was able to solve by pressure programming with a electric pressure controller. By using both pressure and temperature programming brought increasing of resolution power in on-column cryofocusing method, but the high pressure caused a leakage of sample tube with repeated use. A loop cryofocusing devise was also developed and compared with the direct on-column method. In loop cryofocusing method, VOCs were concentrated on a 0.8mm i.d. loop which is located between the injector and separation column by using liquid nitrogen. In order to purge VOCs from the absorbent trap, only 0.4 psi of pressure was need in the loop cryofocusing method. Dual detection system was applied for the analysis of VOCs; a FID was used for hydrocarbons and a FPD was used for sulfur-containing compounds. Qualitative analysis was done by on-column cryofocusing GC-MS system. Among the large number of VOCs, toluene was the most abundant. Hydrogen sulfide, dimethyl sulfide, carbon disulfide, dimethyl disulfide and methyl propyl disulfide were detected at landfill site by FPD.

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Evaluation of Cleanness and Physical Properties of W/O Microemulsion (W/O Microemulsion 세정제의 물성 및 세정성 평가)

  • Lee, Myung Jin;Han, Ji Won;Lee, Ho Yeol;Han, Sang Won;Bae, Jae Heum;Park, Byeong Deog
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.769-777
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    • 2002
  • Using four components - nonionic surfactants, water, hydrocarbon oil and an alcohol as cosurfactant, 12 types of cleaning agents were prepared, and their physical properties such as surface tension, viscosity, electroconductivity and phase stability were measured. As the formulated cleaning agents have low surface tensions(30.5-31.1 dyne/cm) and low viscosities (1.6-7.2 c.p.), they are satisfied with the general physical properties of water-in-oil(W/O) microemulsions for their industrial use. They showed a tendency that their temperature range for stable one-phase microemulsion decreased in accordance with the increase of alcohol/surfactant(A/S) ratio in the formulations. However, the temperature range of one-phase microemulsion was much more affected by hydrophilic lipophillic balance(HLB) value of the nonionic surfactant which increased its temperature range and it increased in accordance with the higher HLB value in the formulations. And the maximum content of water which can keep stable one-phase W/O microemulsion was measured at each sample. In addition, their temperature range for stable one-phase microemulsion was also measured. It was confirmed that the selection of surfactant type was very important for formulating a cleaning agent, since the W/O microemulsion system with the nonionic surfactant of the lower HLB value showed better cleaning efficacy that of the higher HLB value for abietic acid as a soil, which was used for preparing a rosin-type flux. In the formulated cleaning agents with the increase of A/S ratio in the formulations, however, there was no significant difference in cleaning efficacy. It was investigated that the differences of their cleaning efficacy was affected by the change of the condition of temperature and sonicating frequency as important factors in the industrial cleaning. That is, the higher, their cleaning temperature and the lower, their sonicating frequency, the more increased, their cleaning efficacy. Furthermore, using optical instruments like UV/Visable Spectrophotometer and FT-IR Spectrometer, their cleaning efficacy for abietic acid was measured. The removal of soil from the contaminated rinse water was measured by gravity separation method in the rinse bath. As a result, the cleaning agent system having the nonionic surfactant of HLB value 6.4 showed over 85% water-oil separation efficacy at over $25^{\circ}C$. Therefore, it was demonstrated in this work that the formulating cleaning agents were very effective for cleaning and economical in the possible introduction of water recycling system.

A Study on A Mathematical Formulation of Protection Ratio and Its Calculation for Fixed Radio Relay System with Diversity (다이버시티를 갖는 고정 무선 중계 시스템에 대한 보호비의 수학적 표현과 계산에 대한 연구)

  • Suh Kyoung-Whoan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.4 s.107
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    • pp.358-367
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    • 2006
  • In this paper, a mathematical formulation of protection ratio and its calculation method are suggested for a radio relay system with diversity techniques. The analysis of protection ratio and its physical meaning have been performed for the space or frequency diversity system, and in particular protection ratios are reviewed in terms of the parameters of diversity improvement factor, which comprises antenna gain, separation distance between antennas, frequency and its difference between carriers, and distance. As one of simulated results, the co-channel protection ratio of 60 dB is obtained for the space diversity system regarding 6.2 GHz, 60 km, 64-QAM, and 25 m between antennas, which gives 15 dB less than the co-channel protection ratio of the non-space diversity system. In addition, the co-channel protection ratio for the frequency diversity system gives 64 dB in case of frequency offset of 0.5 GHz under the same conditions as the space diversity system, which brings about 11 dB less than the co-channel protection ratio of non-frequency diversity system. In consequency, it is interesting to note that the space diversity system is less sensitive to interference in comparison to the frequency diversity system and provides better quality of service for a given interference.

Determination of Natural Gas Components by Gas Chromatographic Multicolumn System (기체 크로마토그래피 복합컬럼 시스템에 의한 천연가스 성분의 정량)

  • Choi, Yong-Wook;Choe, Kun-Hyung
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.339-347
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    • 1994
  • A multicolumn system consisted of two valve(10-port and 6-port valve)-three column (28% DC 200, SP 1700 and Chromosorb 102 column) was developed. Nine natural gas components composed of $N_2$, $CH_4$, $CO_2$, $C_2H_6$, $C_3H_8$, $i-C_4H_{10}$, $n-C_4H_{10}$, $i-C_5H_{12}$$n-C_5H_{12}$ completed all the baseline separation within 18 minutes. The accuracy and the precision of this system was tested. The retention times and the peak areas were determined with a repeatability between 0.02 and 0.16%, and less than 1%, respectively. Calibration curves for natural-gas components were plotted by the partial pressure injection method of pure gases, and good linear relationships for each component were presented. By using these calibration curves the accuracy of the multicolumn system compaired with that of the single column system for a certified standard gas of natural gas. As a result, relative error in the single and the multicolumn system was less than 0.5% and 0.04%, respectively. The result of application of this system in the analysis of importing LNG composition showed that the heating values calculated by the multicolum system were estimated lower compared with those calculated by the single column system and consequently, the importing price of LNG was able to be cut down.

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