• 제목/요약/키워드: synthesis methods

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Qualitative comparison of chemical and green synthesized Fe3O4 nanoparticles

  • Gokila, V.;Perarasu, V.T.;Rufina, R. Delma Jones
    • Advances in nano research
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    • 제10권1호
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    • pp.71-76
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    • 2021
  • Synthesis of nanoparticles using green technology using plants is gaining significant attention as it is an environmentally friendly substitute to conventional physical and chemical methods. The present study was focused on the chemical and green synthesis of Iron Oxide nanoparticles from ferric chloride. The green synthesis was achieved by utilizing the bio components of Hibiscus rosa-sinensis. The Fe3O4 nanoparticles with the size range of 87-400 nm were synthesized by wet chemical reduction technique which are unstable, prone to aggregation while in green synthesis the phytochemicals present in the leaf extract acts as the capping as well as the reducing agent thus the green synthesized iron (III) oxide nanoparticles were naturally stabilized, spherical shaped and are in the size range of 2-80 nm. The results of both the protocols are compared and presented briefly.

Design of Multivariable PID Controllers: A Comparative Study

  • Memon, Shabeena;Kalhoro, Arbab Nighat
    • International Journal of Computer Science & Network Security
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    • 제21권8호
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    • pp.212-218
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    • 2021
  • The Proportional Integral Derivative (PID) controller is the most popular industrial controller and more than 90% process industries use this controller. During the past 50 years, numerous good tuning methods have been proposed for Single Input Single Output Systems. However, design of PI/PID controllers for multivariable processes is a challenge for the researchers. A comparative study of three PID controllers design methods has been carried-out. These methods include the DS (Direct Synthesis) method, IMC (Internal model Control) method and ETF (Effective Transfer Function) method. MIMO PID controllers are designed for a number of 2×2, 3×3 and 4×4 process models with multiple delays. The performance of the three methods has been evaluated through simulation studies in Matlab/Simulink environment. After extensive simulation studies, it is found that the Effective Transfer Function (ETF) Method produces better output responses among two methods. In this work, only decentralized methods of PID controllers have been studied and investigated.

Design of Multivariable PID Controllers: A Comparative Study

  • Memon, Shabeena;Kalhoro, Arbab Nighat
    • International Journal of Computer Science & Network Security
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    • 제21권9호
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    • pp.11-18
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    • 2021
  • The Proportional Integral Derivative (PID) controller is the most popular industrial controller and more than 90% process industries use this controller. During the past 50 years, numerous good tuning methods have been proposed for Single Input Single Output Systems. However, design of PI/PID controllers for multivariable processes is a challenge for the researchers. A comparative study of three PID controllers design methods has been carried-out. These methods include the DS (Direct Synthesis) method, IMC (Internal model Control) method and ETF (Effective Transfer Function) method. MIMO PID controllers are designed for a number of 2×2, 3×3 and 4×4 process models with multiple delays. The performance of the three methods has been evaluated through simulation studies in Matlab/Simulink environment. After extensive simulation studies, it is found that the Effective Transfer Function (ETF) Method produces better output responses among two methods. In this work, only decentralized methods of PID controllers have been studied and investigated.

Toward Industrial Applications of Graphene Electrodes

  • 홍병희
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.39-39
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    • 2010
  • There have been many efforts to utilize the outstanding properties of graphene for macroscopic applications such as transparent conducting films useful for flexible/stretchable electronics. However, the lack of efficient synthesis, transfer, and doping methods limited the scale and the quality needed for the practical production of graphene films. In this presentation, we introduce ultra-large scale (~30 inch) synthesis and roll-to-roll transfer of graphene films showing excellent electrical and physical properties suitable for practical applications. Considering the outstanding scalability/processibility of roll-to-roll and CVD methods and the extraordinary flexibility/conductivity of graphene films, we expect the commercial production and application electrodes replacing the use of ITO can be realized in near future.

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암모니아 합성 및 분해를 위한 촉매 탐색의 최근 연구 동향 (Recent Research Trends of Exploring Catalysts for Ammonia Synthesis and Decomposition)

  • 김종영;여병철
    • Korean Chemical Engineering Research
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    • 제61권4호
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    • pp.487-495
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    • 2023
  • 암모니아는 인류의 식량문제를 해결할 수 있는 비료 생산의 주요 원료임과 동시에 무탄소 연료이면서 친환경적인 수소 운반자로서 중요한 에너지원으로 알려져 있다. 그래서 지금까지도 암모니아를 합성하거나 분해하는 기술들이 각광을 받고 있다. 암모니아 합성 및 분해 반응을 촉진시키기 위해서는 반드시 촉매 재료가 필요하다. 고성능 및 값싼 암모니아 합성 및 분해용 신촉매를 설계하기 위해서는 무수히 많은 합성 가능한 촉매 후보군들을 다루어야만 하는데 전통적인 접근법만으로 탐색 및 분석을 하기엔 시간적, 경제적인 비용이 많이 들 수밖에 없다. 최근에 4차 산업혁명의 핵심기술에 속하는 머신러닝을 이용하여 이용하여 고성능 촉매를 빠르고 정확하게 찾을 수 있는 탐색 모델이 개발되어 왔다. 본 연구에서는 암모니아 합성 및 분해용 반응 메커니즘에 대해서 알아보고, 고성능 및 경제적인 암모니아 합성 및 분해 촉매를 효율적으로 탐색할 수 있는 머신러닝 기반 방법에 대한 최신 연구 및 전망을 기술하였다.

청간해주탕(淸肝解酒湯)이 인체간세포의 Glutathione 생성에 미치는 영향 (The Effects of Chungganhaeju-Tang on glutathione synthesis in HepG2 cell)

  • 윤여광;이장훈;우홍정;김영철
    • 대한한방내과학회지
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    • 제25권1호
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    • pp.81-91
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    • 2004
  • Objectives : The aim of this study is to investigate the inhibitory effect of Chungganhaeju-Tang on alcohol induced human hepatic cell apoptosis by synthesis of glutathione. Methods : The amount of glutathione in HepG2 cell was measured with colorimetric glutathione assay kit and glutathione-conjugated CDNB(1-chloro-2,4-dinitrobenzene) at $37^{\circ}C$ and then measured by spectrometry to assess the activity of glutathione S-transferase. Results : The synthesis of glutathione and the activity of glutathione S-transferase in HepG2 cell were promoted by Chungganhaeju-Tang and increased in dose/time-dependent manner. Chungganhaeju-Tang inhibited apoptosis induced by ethanol and acetaldehyde dependent to treatment dosage. In Buthione sulfoximine, a glutathione synthesis inhibitor, treated case, the synthesis of glutathione was inhibited and in Chungganhaeju-Tang treated case, the synthesis of glutathione is promoted with or without Buthione sulfoximine. The present findings suggest that Chungganhaeju-Tang inhibits alcohol induced apoptosis by synthesis of glutathione in HepG2 cell. Conclusions : The result indicates that Chungganhaeju-Tang protects human hepatic cell by glutathione synthesis and made the liver recover from alcohol induced damage.

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Synthesis of Multi-View Images Based on a Convergence Camera Model

  • Choi, Hyun-Jun
    • Journal of information and communication convergence engineering
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    • 제9권2호
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    • pp.197-200
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    • 2011
  • In this paper, we propose a multi-view stereoscopic image synthesis algorithm for 3DTV system using depth information with an RGB texture from a depth camera. The proposed algorithm synthesizes multi-view images which a virtual convergence camera model could generate. Experimental results showed that the performance of the proposed algorithm is better than those of conventional methods.

Synthesis of Sulfide-based Phosphors by Multiply Combined Methods Based Upon Inorganic Chemistry

  • Kakihana, Masato;Petrykin, Valery
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.121-124
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    • 2009
  • We developed a panel of innovative solution-based approaches for synthesis of multicomponent sulfide phosphor materials. The application of these synthesis strategies allowed for preparation of high-purity and high-brightness $BaAl_2S_4:Eu$ and $Ba_2SiS_4:Eu$ phosphors and led to the discovery of new phosphors suitable for application in the LED-based lighting including $Sr_2ZnS_3:Eu$, $CaBaSiS_4:Eu$ and $(Ba,Sr)_2ZnS_3:Eu$.

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Identification of Homoserine Lactone Derivatives Using the Methionine Functionalized Solid Phase Synthesis by Gas Chromatography/Mass Spectrometry

  • Moon, Hong-Sik
    • Archives of Pharmacal Research
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    • 제27권1호
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    • pp.25-30
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    • 2004
  • Combinatorial homoserine lactone mixtures and individual products were obtained from the methionine-functionalized resin in solid-phase synthesis. The four-step process consisting of a coupling step of an N-Fmoc-L-methionine, deprotection of N-Fmoc group, N-coupling with a carboxylic acid, and cleavage reaction through a polymer supported strategy is described. Gas chromatography-mass selective detector (GC-MSD) techniques provide the most powerful methods for identifying both the combinatorial mixtures and individual products.

Clarification about Component Mode Synthesis Methods for Substructures with Physical Flexible Interfaces

  • Ohayon, R.;Soize, C.
    • International Journal of Aeronautical and Space Sciences
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    • 제15권2호
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    • pp.113-122
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    • 2014
  • The objective of the paper is to clarify a methodology based on the use of the existing component mode synthesis methods for the case of two damped substructures which are coupled through a linking viscoelastic flexible substructure and for which the structural modes with free geometrical interface are used for each main substructure. The proposed methodology corresponds to a convenient alternative to the direct use either of the Craig-Bampton method applied to the three substructures (using the fixed geometric interface modes) or of the flexibility residual approaches initiated by MacNeal (using the free geometric interface modes). In opposite to a geometrical interface which is a topological interface on which there is a direct linkage between the degrees of freedom of substructures, we consider a physical flexible interface which exists in certain present technologies and for which the general framework linear viscoelasticity is used and yields a frequency-dependent damping and stiffness matrices of the physical flexible interface.