• Title/Summary/Keyword: surface shell

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Preparation of Styrene-Ethyl acylate Core-shell Structured Detection Materials for aMeasurement of the Wall Contamination by Emulsion Polymerization

  • Hwang, Ho-Sang;Seo, Bum-Kyoung;Lee, Dong-Gyu;Lee, Kune-Woo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.06a
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    • pp.84-85
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    • 2009
  • New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

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Functionalized magnetite / silica nanocomposite for oily wastewater treatment

  • Hakimabadi, Seyfollah Gilak;Ahmadpour, Ali;Mosavian, Mohammad T. Hamed;Bastami, Tahereh Rohani
    • Advances in environmental research
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    • v.4 no.2
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    • pp.69-81
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    • 2015
  • A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.

Medial Surface Generation by Using Chordal Axis Transform in Shell Structures (쉘 구조물에서 Chordal Axis Transform 을 이용한 중립면 생성)

  • 권기연;박정민;이병채;채수원
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.865-870
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    • 2004
  • This paper describes the generation of chordal surface for various shell structures, such as automobile bodies, plastic injection mold components and shell metal parts. After one-layered tetrahedral mesh is generated by an advancing front algorithm, the chordal surface is generated by cutting a tetrahedral element. It is generated one or two elements at a tetrahedral element and the chordal surface is composed with triangular or quadrilateral elements. This algorithm has been tested on several models with rib structure.

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A Study on Medial Surface Extraction from Point Samples on 3D Closed Surfaces in Shell Shapes (셸 형상의 3차원 폐곡면상에서 추출된 점데이터군으로부터 중립곡면 계산에 관한 연구)

  • Woo, Hyuck-Je
    • Korean Journal of Computational Design and Engineering
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    • v.15 no.1
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    • pp.33-42
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    • 2010
  • In this study, new medial surface calculation methods using Voronoi diagrams are investigated for the point samples extracted on closed surface models. The medial surface is defined by the closure of all points having more than one closest point on the shape boundary. It is a one of essential geometric information in 3D and can be used in many areas such as 3D shape analysis, dimension reduction, freeform shape deformation, image processing, computer vision, FEM analysis, etc. In industrial parts, the idealized solid parts and shell shapes including sharp edges and vertices are frequently used. Other medial surface extraction methods using Voronoi diagram have inherent separation and branch problems, so that they are not appropriate to the sharp edged objects and have difficulties to be applied to industrial parts. In addition, the branched surfaces on sharp edges in shell shapes should be eliminated to obtain representative medial shapes. In order to avoid separation and branch problems, the new approach by analyzing the shapes and specially sampling on surfaces has been developed.

Shell Finite Element Based on B-Spline Representation for Finite Rotations (B-Spline 곡면 모델링을 이용한 기하비선형 쉘 유한요소)

  • 노희열;조맹효
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2003.10a
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    • pp.429-436
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    • 2003
  • A new linkage framework between elastic shell element with finite rotation and computar-aided geometric design (CAGD) (or surface is developed in the present study. The framework of shell finite element is based on the generalized curved two-parametric coordinate system. To represent free-form surface, cubic B-spline tensor-product functions are used. Thus the present finite element can be directly linked into the geometric modeling produced by surface generation tool in CAD software. The efficiency and accuracy of the Previously developed linear elements hold for the nonlinear element with finite rotations. To handle the finite rotation behavior of shells, exponential mapping in the SO(3) group is employed to allow the large incremental step size. The integrated frameworks of shell geometric design and nonlinear computational analysis can serve as an efficient tool in shape and topological design of surfaces with large deformations.

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Nanostructure Construction of SiO2@Au Core-Shell by In-situ Synthesis (코어-쉘 구조 SiO2@Au 나노입자의 in-situ 합성)

  • Pyeon, Mu-Jae;Kim, Do Kyung;Jeong, Young-Keun
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.420-425
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    • 2018
  • Core-shell structured nanoparticles are garnering attention because these nanoparticles are expected to have a wide range of applications. The objective of the present study is to improve the coating efficiency of gold shell formed on the surface of silica nanoparticles for $SiO_2@Au$ core-shell structure. For the efficient coating of gold shell, we attempt an in-situ synthesis method such that the nuclei of the gold nanoparticles are generated and grown on the surface of silica nanoparticles. This method can effectively form a gold shell as compared to the conventional method of attaching gold nanoparticles to silica particles. It is considered possible to form a dense gold shell because the problems caused by electrostatic repulsion between the gold nanoparticles in the conventional method are eliminated.

The Analysis of T. L. Shell (T.L.SHELL의 응력해설)

  • Im, Yeong-Bae;Lee, Su-Gon
    • Korean Architects
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    • v.4 no.14 s.14
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    • pp.74-79
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    • 1969
  • As we all know a large number of thin shell with the shape of E.P and H.P have been constructed. In this paper, we will be interested to the bending problem of thin translational shell. Two basic differential equations of shallow shell are to be used to derive approximate solution of it. Stress analysis of E.P. translational shell with constant thickness under uniform surface oad is to be given as an example. More exact solution formulated by K. Apeland can be found in the proceeding, Journal of the Engineering Mechanics Division, A.S.C.E., Feburary, 1961.

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Development Plan for the First GMT ASM Reference Body

  • Yang, Ho-Soon;Oh, Chang-Jin;Biasi, Roberto;Gallieni, Daniele
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.76.3-77
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    • 2021
  • GMT secondary mirror system consists of 7 segmented adaptive mirrors. Each segment consists of a thin shell mirror, actuators and a reference body. The thin shell has a few millimeters of thickness so that it can be easily bent by push and pull force of actuators to compensate the wavefront disturbance of light due to air turbulence. The one end of actuator is supported by the reference body and the other end is adapted to this thin shell. One of critical role of the reference body is to provide the reference surface for the thin shell actuators. Therefore, the reference body is one of key components to succeed in development of GMT ASM. Recently, Korea Research Institute of Standards and Science (KRISS) and University of Arizona (UA) has signed a contract that they will cooperate to develop the first set of off-axis reference body for GMT ASM. This project started August 2021 and will be finished in Dec. 2022. The reference body has total 675 holes to accommodate actuators and 144 pockets for lightweighting. The rear surface has a curved rib shape with radius of curvature of 4387 mm with offset of 128.32mm. Since this reference body is placed just above the thin shell so that the front surface shape needs to be close to that of thin shell. The front surface has a concave off-axis asphere, of which radius of curvature is 4165.99 mm and off-axis distance is about 1088 mm. The material is Zerodur CTE class 1 (CTE=0.05 ppm/oC) from SCHOTT. All the actuator holes and pockets are machined normal to the front surface. It is a very complex challenging optical elements that involves sophisticated machining process as well as accurate metrology. After finishing the fabrication of reference body in KRISS, it will be shipped to UA for final touches and finally sent to Adoptica in Italy, in early 2023. This paper presets the development plan for the GMT ASM Reference Body and relevant fabrication and metrology plans.

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The Effect of Surface Roughness on the Trajectory of Howitzer Shell (표면 거칠기가 곡사포탄의 탄도에 미치는 영향)

  • Shin, Geonho;Cheon, Kangmin;Shin, Baekcheon;Go, Jeongil;Lee, Junhyeok;Hur, Jangwook
    • Journal of the Korea Institute of Military Science and Technology
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    • v.25 no.4
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    • pp.364-371
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    • 2022
  • Surface state change of ammunition generated during the storage period increases the surface roughness and this affects the flight of ammunition, but there are no research results quantitatively indicating this. In this study, the drag force for each Mach number of howitzer shells was calculated through CFD to which the surface data of the howitzer shell was applied, and analysis of trajectory was performed using drag force values as an input of the 4th Runge-Kutta method, and the degree of decrease of the maximum range caused by the surface roughness of the howitzer shell was estimated. As a result, it was confirmed that the maximum range of howitzer shell with high surface roughness was 1.12 % shorter than that of howitzer shell without roughness. It was confirmed that the effect of surface roughness on the trajectory is not negligible.

Fimite Element Analysis for Shell Surface using R-adativity (R-adptivity 기법을 이용한 쉘 곡면의 유한요소해석)

  • 전성기;조맹효
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2001.10a
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    • pp.311-318
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    • 2001
  • The R-adaptivity method to the shell surface which is presented by the NURBS is proposed. The r-adaptiivty method , given by Liao and Anderson〔2〕, aggregate the grid in the region where is relatively high weight function without any grid-tanggling. In numerical examples, the strain energy error estimate of shell in the whole domain can be reduced effectively by using applied r- adaptivity method mesh.

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