• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.194-202
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• 1996

Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

• Advances in nano research
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• v.15 no.6
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• pp.495-511
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• 2023

In this research, the impact of micro-silica, nano-silica, and polypropylene fibers on the fracture energy of self-compacting concrete was thoroughly examined. Enhancing the fracture energy is very important to increase the crack propagation resistance. The study focused on evaluating the self-compacting properties of the concrete through various tests, including J-ring, V-funnel, slump flow, and T50 tests. Additionally, the mechanical properties of the concrete, such as compressive and tensile strengths, modulus of elasticity, and fracture parameters were investigated on hardened specimens after 28 days. The results demonstrated that the incorporation of micro-silica and nano-silica not only decreased the rheological aspects of self-compacting concrete but also significantly enhanced its mechanical properties, particularly the compressive strength. On the other hand, the inclusion of polypropylene fibers had a positive impact on fracture parameters, tensile strength, and flexural strength of the specimens. Utilizing the response surface method, the relationship between micro-silica, nano-silica, and fibers was established. The optimal combination for achieving the highest compressive strength was found to be 5% micro-silica, 0.75% nano-silica, and 0.1% fibers. Furthermore, for obtaining the best mixture with superior tensile strength, flexural strength, modulus of elasticity, and fracture energy, the ideal proportion was determined as 5% micro-silica, 0.75% nano-silica, and 0.15% fibers. Compared to the control mixture, the aforementioned parameters showed significant improvements of 26.3%, 30.3%, 34.3%, and 34.3%, respectively. In order to accurately model the tensile cracking of concrete, the authors used softening curves derived from an inverse algorithm proposed by them. This method allowed for a precise and detailed analysis of the concrete under tensile stress. This study explores the effects of micro-silica, nano-silica, and polypropylene fibers on self-compacting concrete and shows their influences on the fracture energy and various mechanical properties of the concrete. The results offer valuable insights for optimizing the concrete mix to achieve desired strength and performance characteristics.

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.1232_1233
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• 2009

Paraquat is well-known to cause hepatotoxic responses in human and other mammal species. In solution, it forms free radicals and charge-transfer complex of which formation plays an important role in determination of its biological activity in the presence of various anions. The HepG2 cells were cultured onto a quartz crystal sensor which is possible to detect the density and a viscosity changes using the resonance frequency (F) and the resonance resistance (R). The plot of F-R diagram is able to explain the rheological change of cells onto the surface of the quartz crystal sensor. In this paper, we investigated the physical properties of the HepG2 cells cultured onto a ITO electrode of the quartz crystal sensor according to the paraquat injection at various concentrations (100 mM, 10 mM, 1 mM). We also observed the morphological changes with a micro CCD camera, simultaneously. The HepG2 cells were cultured onto the ITO electrode surface of the quartz crystal modified a collagen film in $CO_2$ incubator. After the paraquat injection, we observed the changes of the morphologies by the micro CCD camera depending on time and analyzed the physical changes of cells on the electrode surface of quartz crystal using F-R diagram. From all results, we proved the effect of paraquat at various concentrations which is led to an apoptosis such as weakening and death of the cells by oxidation and reduction reaction that were produced the superoxide anions and other free radicals.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.382-387
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• 2013

Biodegradable polyurethane (PU)/clay nanocomposite films were prepared via extrusion compounding process followed by casting film process. Organically modified montmorillonite (denoted as C30B) with a large amount of hydroxyl groups on its surface was used for the formation of strong bonding with PU resin. From both XRD analysis and TEM observations, the intercalated and exfoliated structure, and dispersion state of silicate platelets in the compounded nanocomposite films were confirmed. In addition, the rheological and tensile properties, optical transparency, oxygen permeability of the prepared nanocomposites were investigated as a function of added nanoclay content, and moreover based on these results, the corelation between the morphology and the resulting properties of the nanocomposites could be presented. The inclusion of nanoclays at appropriate content resulted in remarkable improvement in the nanocomposite performance including tensile modulus, elongation, transparency, and oxygen barrier property, however at excess amount of nanoclays, reduction or very slight increase was observed due to poor dispersion. The biodegradability of the prepared nanocomposite film was evaluated by examining the deterioration in the barrier and tensile properties during degradation period under compost.

• Advances in concrete construction
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• v.8 no.1
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• pp.65-76
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• 2019

This paper investigates the effect of recycled glass powder (RGP) on flowing properties of self-compacting mortars (SCMs) containing different ratios of fillers and superplasticizer dosages. Fly ash (FA), nano-silica (NS), micro-silica (MS), metakaolin (MK) and rice husk ash (RHA) are used as fillers and their synergistic effect with RFP is studied. The effects of fillers and high-range water reducer (HRWR) on flowing ability of mortars are primarily determined by slump flow and V-funnel flow time tests. The results showed that for composites with a higher RGP content, the mortar flowing ability increased but tended to decrease when the composites containing 10% MK or 5% RHA. However, the flowing ability of samples incorporating 5% RGP and 10% SF or 25% FA showed an opposite result that their slump flow spread decreased and then increased with increasing RGP content. For specimens with 3% NS, the influence of RGP content on flowing properties was not significant. Except RHA and MS, the fillers studied in this paper could reduce the dosage of HRWR required for achieving the same followability. Also, the mixture parameters were determined and indicated that the flowability of mixtures was also affected by the content of sand and specific surface area of cement materials. It is believed that excess fine particles provided ball-bearing effect, which could facilitate the movement of coarse particles and alleviate the interlocking action among particles. Also, it can be concluded that using fillers in conjunction with RGP as cementitious materials can reduce the material costs of SCM significantly.

• Korean Journal of Pharmacognosy
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• v.19 no.2
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• pp.133-140
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• 1988

The effect of ethanol extracts of Gilkyung(Platicodi Radix, Platicodongrandiflorum A, DC), Onji(Polygalae Radix, Polygala tennuifolia Willdenow) and Deoduk(Codonopsis lanceolate Radix, Codonopsis lanceolata) on expectorant activity of rat trachea was investigated. Following treatment of 50% ethanol extract of these medicinal plants (25 mg/rat), the content of neurotransmitters such as acetylcholine and histamine in tissue was significantly increased. The secretions of acid glycoproteins and the artificially injected phenol red were also increased. However, there was no significant difference except Onji From the histological study through periodic acid Schiff and alcian blue stain, the thickness of inner membrane of acinar glands and the stained glycoproteins on surface of epithelium and on the glands were observed in all the rats trachea treated with extract of medicinal plants. In vitro, the viscosity of mucin solution was slightly decreased with an addition of the extracts. Onji showed the most effective expectorant activity among them at the identical conditions. The mechanism of expectorant activity of these medicinal plants seems to be due to stimulation of secretion and changes of rheological properties of mucus.

• Korean Chemical Engineering Research
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• v.48 no.3
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• pp.397-400
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• 2010

The interfacial hydrodynamic issues in the screen printing are experimentally investigated by using model inks that are prepared by dispersing alumina nanoparticles in water. The printing patterns of the inks that are passed through differing geometrical shapes of screen on solid surfaces with differing wettability are not solely determined by the pattern on the screen. The dynamic contact angle cannot solely explain the physics of the problem, either. The difference between the screen and printing patterns was not the same for concave and convex corners. Especially the elasticity of ink affects the edge shape.

• Journal of the Korean Ceramic Society
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• v.56 no.5
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• pp.461-467
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• 2019

Ink-jet printing technology, which utilizes a digitalized design to print fine ink directly on a substrate, has been of interest in various industries due to its high efficiency and adaptability to various materials. Recently, active attempts have been made to apply ceramic materials having excellent heat resistance, light resistance, and chemical resistance to the ink-jet printing process. In this study, ceramic ink was synthesized by combining ceramic pigments with UV curable polymer. 3D printability at various contact angles between ceramic ink and substrate was analyzed in detail. Rheological properties of the synthesized ceramic ink were optimized to meet the requirements of the ink-jet printing process, and the contact angle of UV curable ceramic ink was controlled through surface treatment of the substrate. The potential for additive manufacturing of ceramic material using ink-jet printing was investigated by analyzing the effect of contact angle control on ceramic ink droplets and their 3D printability.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.28 no.3
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• pp.123-129
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• 2018

Ink-jet printing technology with ceramic ink of the four digital primary colors (cyan, magenta, yellow, and black; CMYK) can provide stable coloration even in the high-temperature firing process. Ceramic ink-jet printing can be widely applied in construction and ceramic industries due to the advantages of accurate and fast printing process of digital images for various products. Generally, organic solvent with proper viscosity and surface tension has been used in digital ink-jet printing process. However, the needs of ceramic ink without VOCs emission is increasing. In the present study, eco-friendly ceramic ink was synthesized by combining alumino boro-silicate glass frit and $CoAl_2O_4$ inorganic pigment based on an aqueous solvent that does not generate VOCs. The rheological properties and dispersion stability of aqueous ceramic ink were optimized. Jetting behavior and printing characteristics of the ceramic ink were also investigated in detail. As a result, the formulated aqueous ceramic complex ink showed a suitable jetting behavior without satellite drop by adjusting viscosity and surface tension. The ceramic ink can be printed on glass substrate with minimized spreading phenomena duo to high contact angle.

• Journal of Life Science
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• v.16 no.7 s.80
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• pp.1164-1168
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• 2006

This study was carried out to investigate the possible for utilization of garbage in pig feed by investigating the functional characteristics of pork from pigs fed dried citrus byproduct. The samples consisted of the pork loin from pigs not fed with dried citrus pulp (DCP-0) and fed with 6% and 10% dried citrus pulp during growing and fattening period (DCP-1) there is no respective comparison here The pH, VBN content, TBARS value, bacterial counts, surface color, water holding capacity, loss degree and rheological properties of the samples were determined by physicochemical properties, and the sensory scores were evaluated. The pH, VBN content, surface color, water holding capacity and loss degree were not different between the samples, but the TBARS value and bacterial counts of DCP-1 were significantly lower than those of the DCP-0 (p<0.05). The cohesiveness, gumminess, chewiness, shear forte value, taste, flavor, tenderness, juiciness and palatability were not different between the samples, but the hardness of DCP-0 was higher than that of the DCP-1 and the springiness of DCP-1 was higher than that of the DCP-0 (p<0.05).