• Title/Summary/Keyword: surface investigation

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First-Principles Investigation of the Surface Properties of LiNiO2 as Cathode Material for Lithium-ion Batteries (제일원리계산을 이용한 리튬이차전지 양극활물질 LiNiO2의 표면 특성에 관한 연구)

  • Choi, Heesung;Lee, Maeng-Eun
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.169-176
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    • 2013
  • Solid state lithium oxide compounds of layered structure, which has high stability of structure, are mainly used as the cathode materials in lithium-ion batteries (LIBs). Recently, the investigation of Solid Electrolyte Interphase (SEI) between active materials and electrolyte has been focusing to improve the performance of lithium-ion batteries. For the investigation of the SEI, the study of surface properties of cathode materials and anode materials is also required in advance. $LiNiO_2$ and $LiCoO_2$ are very similar layered structure of cathode active materials and representative solid state lithium oxide compounds in LIBs. Various experimental and theoretical studies have been doing for $LiCoO_2$. The theoretical investigation of $LiNiO_2$ is not sufficient, however, even if experimental studies of $LiNiO_2$ are enough. In this study, the surface energies of nine facets of $LiNiO_2$ crystal facets were calculated by Density Functional Theory. In XRD data of $LiNiO_2$, (003), (104), (101), et al. facets are main surfaces in order. However, the results of calculation are different with XRD data. Thus, both (104) and (101) facets, which are energetically stable and measured in XRD, are mainly exposed in the surface of $LiNiO_2$ and it is expected that intercalation and de-intercalation of Li-ion will be affected by them.

A STUDY ON SURFACE ALTERATION OF IMPLANT SCREWS AFTER FUNCTION

  • Han, Myung-Ju;Chung, Chae-Heon;Choi, Han-Cheol
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.3
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    • pp.275-286
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    • 2002
  • Statement of problem. Surface alteration of the implant screws after function may be associated with mechanical failure. Theses metal fatigue appears to be the most common cause of structural failure. Purpose. The purpose of this study was to evaluate surface alteration of the implant screws after function through the examination of used and unused implant screws in SEM(scanning electron microscope). Materials and methods. In this study, abutment screws(Steri-oss, 3i), gold retaining screw(3i) and titanium retaining screw(3i) were retrieved from patients. New, unused abutment and retaining screws were prepared for control group. Each of the old, used screws was retrieved with a screwdriver. And retrieved implant complex of Steri-oss system was prepared for this study. Then, SEM investigation and EDS analysis of abutment and retaining screws were performed. And SEM investigation of cross-sectioned sample of retrieved implant complex was performed. Results. In the case of new, unused implant screws, as maunfactured circumferential grooves are regularly examined and screw thread are sharply remained. Before ultrasonic cleansing of old, used implant screw, a lot of accumulation and corrosion products were existed. After ultrasonic cleansing of old, used implant screws, circumferential grooves as examined before function were randomly deepened and scratches increased. Also, dull screw thread was examined. More surface alterations after function were examined in titanium screw than gold screw. And more surface alteration was examined when retrieved with driver than retrieved without driver. Conclusions. These surface alteration after function may result in the screw instability. Regularly cleansing and exchange of screws was recommended. We recommend the use of gold screw rather than titanium screw, and careful manipulation of the driver.

Surface Analysis of Modified Polymer Samples by X-Ray Photoelectron Spectroscopy and Rutherford Backscattering Spectroscopy (X-선 광전자 분광법 및 라더포드 후방산란법에 의한 개질된 고분자 시료의 표면분석)

  • Park, Sung-Woo;Kim, Dong-Hwan;Kim, Young-Man;Park, Byung-Sun;Han, Wan-Soo;Suh, Bae-Suk
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.301-313
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    • 1994
  • X-Ray Photoelectron Spectroscopy(XPS) and Rutherford Backscattering Spectroscopy(RBS) are used for the analysis of additives, examination of chemical structure and determination of identity with qualitative and quantitative analysis of surface elements, binding energy level and depth profiling in the surface. We analyzed surface of polyethylene, acrylonitrile butadien rubber, polypropylene, glass, fiber and paper treated with $XeF_2$ or C-F plasma by XPS and RBS. It was found that fluoro element was penetrated to sample surface and the distribution of surface elements are different than untreated samples.

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Geotechnical Site Investigation for Designing of Tidal Power Plant Structures (조력발전 구조물 설계를 위한 지반조사;인천만 지반조사 사례)

  • Oh, Myoung-Hak;Lee, Kwang-Soo;Park, Jin-Soon;Yum, Ki-Dai;Cha, Dai-Wook;Yang, Geun-Hun
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.613-616
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    • 2007
  • The main structures that comprise a tidal power plant are turbine structure, sluice structure, tide embankment and gate. Since these structures are founded on seabed ground, an extensive geotechnical site investigation to evaluate the engineering properties of field soils must be conducted prior to design and construction. According to the results of geotechnical site investigation conducted at the planned site for construction of Incheon bay tidal power plant, soft ground generally lie 7 meters below the seabed surface level. This research suggests the reliable and economical design of foundations and ground improvements required for construction of main structures in Incheon bay tidal power plant, with considerations on field conditions.

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The Characteristice of Safety on a Slope of Pyroclastic Rock (화산쇄설암 사면의 안정 특성)

  • Kim, Byoung-Gon;Park, Sung-Kwon;Choi, Kil-Hyun;Baek, Seung-Cheol
    • 한국방재학회:학술대회논문집
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    • 2008.02a
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    • pp.557-560
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    • 2008
  • In this paper, it discusses about the stability of rock slope of pyroclastic rock, which can easily meet at construction site. Basically carry out the investigation about the development of a surface of discontinuity, too. With that, it refers to the basic groups of sedimentary rock, treats of general details about investigation of rock slope and stability analysis, and discusses general characteristics and stability analysis case study about rock slope of pyroclastic rock. Achieved basic geological investigation on rock slope of pyroclasic rock, and examine the stability of slope by doing limit equilibrium and geometric stability analysis due to the result of investigation. It is considered to be able to accumulate many data about slope design of pyroclastic rock hereafter estimating degrees of rock mass properties of pyroclastic rock quantitatively.

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Investigation of Reflectance Distribution and Trend for the Double Ray Located in the Northwest of Tycho Crater

  • Yi, Eung Seok;Kim, Kyeong Ja;Choi, Yi Re;Kim, Yong Ha;Lee, Sung Soon;Lee, Seung Ryeol
    • Journal of Astronomy and Space Sciences
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    • v.32 no.2
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    • pp.161-166
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    • 2015
  • Analysis of lunar samples returned by the US Apollo missions revealed that the lunar highlands consist of anorthosite, plagioclase, pyroxene, and olivine; also, the lunar maria are composed of materials such as basalt and ilmenite. More recently, the remote sensing approach has enabled reduction of the time required to investigate the entire lunar surface, compared to the approach of returning samples. Moreover, remote sensing has also made it possible to determine the existence of specific minerals and to examine wide areas. In this paper, an investigation was performed on the reflectance distribution and its trend. The results were applied to the example of the double ray stretched in parallel lines from the Tycho crater to the third-quadrant of Mare Nubium. Basic research and background information for the investigation of lunar surface characteristics is also presented. For this research, resources aboard the SELenological and ENgineering Explorer (SELENE), a Japanese lunar probe, were used. These included the Multiband Imager (MI) in the Lunar Imager/Spectrometer (LISM). The data of these instruments were edited through the toolkit, an image editing and analysis tool, Exelis Visual Information Solution (ENVI).

Investigation of Droplet Vaporizatio Phenomena in High Pressure Environments (고압에서의 액적의 증발현상에 관한 연구)

  • Lee, Hyun-Chang;Baek, Seung-Wook
    • Journal of the Korean Society of Combustion
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    • v.13 no.3
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    • pp.17-23
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    • 2008
  • The spray combustion and spray cooling depends on droplet evaporation. So, evaporation model for spray has been requested and lots of investigation has been done and various reliable models have been developed also for last few decades. In the present study, One dimensional quasi-steady spherically symmetric droplet evaporation model for micro-gravity is developed. The gas phase was assumed as steady state and the thermophysical properties are calculated as a function of temperature, pressure and composition and the properties used in the model was validated by NIST web data and overall evaporation history results was compared with experimental results by Nomura and Qasim and gave satisfactory agreements. Through this model, diverse phenomenon was investigated, especially regarding the effects of ambient pressure and temperature. The effects of pressure for the droplet evaporation time were studied. The high pressure increased the droplet surface temperature and made effect on the evaporation time depend on atmospheric temperature. The role of the ambient temperature was investigated and explained. The basic investigation for the evaporation process according to variation of droplet diameter and surface temperature were also investigated and the well-known phenomena, like D-square-law, were reported, too.

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Investigation of Pressure Loss in Bent Duct (Bent Duct 내부 유동의 손실 측정)

  • Roh, U-Jin;Im, Ju-Hyun;Song, Seung-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.295-298
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    • 2009
  • Bent ducts add loss and decrease efficiency. Many researchers have been conducted the performances of bent ducts, but their shapes of inlet and outlet are same. However, in this investigation, the focus is on a bent duct which is annular at the inlet and circular at the outlet. The bent duct of these complex shapes has not been investigated, but has been used in many fields. The performance of such bent duct is investigated under inlet speed 54 m/s and Re = 238,000. Wall static pressure tappings are located surface of the bent duct to measure the static pressure and a probe is traversed at the inlet and outlet of the bent duct to measure the total pressure. As a result, it presents static pressure distribution on the bent duct surface, streamwise velocity profile at inlet and outlet of the bent duct and total pressure loss profile at outlet. In this investigation, the total pressure loss coefficient is 0.243.

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Investigation on the Description Method of Extrusion Die Surface using NURBS Surface and Area Mapping Method (NURBS 곡면과 면적 사상법을 이용한 압출 금형곡면의 표현 방법에 관한 연구)

  • 유동진;권혁홍;임종훈
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.343-346
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    • 2003
  • In order to construct the extrusion die surface of arbitrarily shaped sections, an automatic surface construction method based on NURBS surface and area mapping method is proposed in the present work. In the present study, a center point for area mapping is determined by introducing the marring concept based on constant area proportionality between original billet and final product. The characteristic points of inlet profile is determined using the traditional area mapping method and the root finding numerical method. The inlet and outlet profiles are precisely described with NURBS curves using the characteristic points of entry and exit sections. For the construction of NURBS surface, an interpolation method for the pre-determined two section curves has been developed to be used in the generation of interior control points and weights. To show the validity of the proposed method, automatic die surface generation is carried out for the several kinds of shaped sections.

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Experimental Investigation on Separated Flows of Axial Flow Stator and Diagonal Flow Rotor

  • Kinoue, Yoichi;Shiomi, Norimasa;Setoguchi, Toshiaki;Jin, Yingzi
    • International Journal of Fluid Machinery and Systems
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    • v.2 no.3
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    • pp.223-231
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    • 2009
  • Experimental investigations were conducted for the internal flows of the axial flow stator and diagonal flow rotor. Corner separation near the hub surface and the suction surface of stator blade are mainly focused on. For the design flow rate, the values of the axial velocity and the total pressure at stator outlet decrease between near the suction surface and near the hub surface by the influence of corner wall. For the flow rate of 80-90% of the design flow rate, the corner separation of the stator between the suction surface and the hub surface is observed, which becomes widely spread for 80% of the design flow rate. At rotor outlet for 81% of the design flow rate, the low axial velocity region grows between near the suction surface of rotor and the casing surface because of the tip leakage flow of the rotor.