• 제목/요약/키워드: surface energy effects

검색결과 1,235건 처리시간 0.027초

산란 및 투과된 수소 이온의 분자 전산 연구 II. 니켈 (100) 표면의 45° 입사 (Molecular Simulation Studies of Scattered and Penetrated Hydrogen Ions II. 45° Incident Angle to Ni (100) Surface)

  • 서승혁;민웅기
    • 한국수소및신에너지학회논문집
    • /
    • 제12권1호
    • /
    • pp.51-63
    • /
    • 2001
  • In this paper molecular dynamics simulations were employed to investigate the structural and dynamic properties of hydrogen ions impacted on the Ni (100) surface with the $45^{\circ}$ incident angle. The initial kinetic energies of the hydrogen ion range from 100 to 1,600 eV. Together with the trajectory visualization of hydrogen ions, we computed scattering and penetration yields, mean energies and angles, and probability and energy distributions as a function of longitudinal and azimuthal directions. In the case of lower energy scattering ions, the multiple collision effects were found to be important to the third layers or lower. For higher energy penetrating ions, compared with the normal incident angle, it was significant the effective channeling effects through the Ni layers and the angle dependencies were indicated both in the longitudinal and the azimuthal angle directions.

  • PDF

확장표면을 적용한 액체식 제습시스템의 성능특성에 관한 연구 (Performance characterization of liquid desiccant system with extended surface)

  • 장영수;송귀은;이대영
    • 대한설비공학회:학술대회논문집
    • /
    • 대한설비공학회 2009년도 하계학술발표대회 논문집
    • /
    • pp.639-644
    • /
    • 2009
  • This study presents the new idea of liquid desiccant system with extended surface to reduce the system size. The extended surface is inserted between vertical cooling/heating tubes to increase the mass transfer area, and the liquid desiccant flows through the tube wall and the extended surface. Mathematical models for heat and mass transfer between liquid desiccant and air stream at tube wall and extended surface are provided. Dimensionless design parameters governing heat and mass transfer phenomena around the tube and the extended surface are identifier, and dimensionless operating parameters depicting system operating condition including flow rate ratio between dehumidification/regeneration processes, and mass flow rate ratio between air stream and liquid desiccant are explained. The effects of the parameters on system performance are summarized.

  • PDF

고성능 섬유형 슈퍼커패시터를 위한 탄소섬유의 표면 기능화 (Surface Functionalization of Carbon Fiber for High-Performance Fibrous Supercapacitor)

  • 이영근;안건형
    • 한국재료학회지
    • /
    • 제32권2호
    • /
    • pp.107-113
    • /
    • 2022
  • Fibrous supercapacitors (FSs), owing to their high power density, good safety characteristic, and high flexibility, have recently been in the spotlight as energy storage devices for wearable electronics. However, despite these advantages, FCs face many challenges related to their active material of carbon fiber (CF). CF has low surface area and poor wettability between electrode and electrolyte, which result in low capacitance and poor long-term stability at high current densities. To overcome these limits, fibrous supercapacitors made using surface-activated CF (FS-SACF) are here suggested; these materials have improved specific surface area and better wettability, obtained by introducing porous structure and oxygen-containing functional groups on the CF surface, respectively, through surface engineering. The FS-SACF shows an improved ion diffusion coefficient and better electrochemical performance, including high specific capacity of 223.6 mF cm-2 at current density of 10 ㎂ cm-2, high-rate performance of 171.2 mF cm-2 at current density of 50.0 ㎂ cm-2, and remarkable, ultrafast cycling stability (96.2 % after 1,000 cycles at current density of 250.0 ㎂ cm-2). The excellent electrochemical performance is definitely due to the effects of surface functionalization on CF, leading to improved specific surface area and superior ion diffusion capability.

Effects of surface modification of $Nafion^{(R)}$ Membrane on the Fuel Cell Performance

  • Prasanna, M.;Cho, E.A.;Ha, H.Y.;Hong, S.A.;Oh, I.H.
    • 한국에너지공학회:학술대회논문집
    • /
    • 한국에너지공학회 2004년도 추계 학술발표회 논문집
    • /
    • pp.133-138
    • /
    • 2004
  • Proton exchange membrane fuel cell (PEMFC) is considered as a clean and efficient energy conversion det ice for mobile and stationary applications. Anions all the components of the PEMFC, the interface between the electrolyte ,and electrode catalyst plays an important role in determining tile cell performance since the electrochemical reactions take place at the interface in contact with tile reactant gases. Therefore, to increase the interface area and obtain a high-performance PEMFC, surface of the electrolyte membrane was roughened by Ar$^{+}$ beam bombardment. The results imply that by modifying surface of the electrolyte membrane, platinum loading can be reduced significantly without performance loss. To optimize the surface treatment condition, effects of ion dose density on characteristics of the membrane/electrode interface were examined by measuring the cell performance, impedance spectroscopy, and cyclic voltammograms. Surface of the modified membranes were characterized using scanning electron microscopy and FT-IR.R.

  • PDF

표면에너지와 거칠기가 응착력에 미치는 영향 (The Effects of Surface Energy and Roughness on Adhesion Force)

  • 나종주;권식철;정용수
    • 대한기계학회논문집A
    • /
    • 제30권11호
    • /
    • pp.1335-1347
    • /
    • 2006
  • Surface energies calculated from measured contact angles between several solutions and test samples, such as Si wafer, $Al_2O_3$, $SiO_2$, PTFE(Polytertrafluoroethylene), and DLC(Diamond Like Carbon) films, based on geometric mean method and Lewis acid base method. In order to relate roughness to adhesion force, surface roughness of test samples were scanned large area and small by AFM(Atomic Force Microscopy). Roughness was representative of test samples in large scan area and comparable with AFM tip radius in small scan area. Adhesion forces between AFM tip and test samples were matched well with order of roughness rather then surface energy. When AFM tips having different radius were used to measure adhesion force on DLCI film, sharper AFM tip was, smaller adhesion force was measured. Therefore contact area was more important factor to determine adhesion force.

자외선 조사에 의해 표면 개질된 PVA 편광필름의 광학특성 (Optical Properties of PVA Polarizing Films Surface-modified by UV Irradiation)

  • 구광회;장진호
    • 한국염색가공학회지
    • /
    • 제18권6호
    • /
    • pp.49-56
    • /
    • 2006
  • Surface treatment using UV irradiation was carried out to improve optical properties of polarizing films. The effects of UV energy of the UV-treated PVA films were investigated by measuring reflectance, surface roughness, contact angles, ESCA, and ATR. Reflectance decreased at wavelength of 450 nm or less and surface roughness increased with increasing UV energy. Water contact angle increased in the irradiated PVA films and surface energy decreased with increase in w energy. An analysis showed that the OH groups were broken and some new groups were introduced such as C=C and C=O bonds together with increased $O_{1s}/C_{1s}$, resulting in the observed surface modification effect. Surface modified PVA polarizing films showed improvement in light transmittance of polarizing films at high wavelength region without deteriorating polarization efficiency, which was not affected by UV irradiation sequence during manufacturing processes such as coloring and drawing.

Microstructure of Laser Surface Melted Ni-Base Alloy 600 after Heat Treatment

  • Lim, Yun-Soo;Cho, Hai-Dong;Kuk, Il-Hiun;Kim, Joung-Soo
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1998년도 춘계학술발표회논문집(2)
    • /
    • pp.66-71
    • /
    • 1998
  • A study of treatment effects on laser surface melted Ni-base alloy 600, especially on precipitation behavior ad chemical composition changes on the grain boundary were conducted with microscopic equipments. Long-term aging treatment at 40$0^{\circ}C$ caused no considerable effects on the grain boundary properties. Cr-rich M$_2$$_3$C$_{6}$ and Cr$_{7}$C$_3$ carbides were precipitated and the resultant Cr depletion below 12 wt pct on some high angle grain boundaries was occurred by heat treatment at $600^{\circ}C$ for 24 hours. These results can imply that the resistance of intergranular stress corrosion cracking of heat treated alloy 600 might not be changed considerably in comparion with the as-LSM one.e.e.

  • PDF

무성방전내에서 톨루엔 제거에 미치는 운전변수의 영향 (Effects of Operating Parameters on Toluene Removal in Dielectric Barrier Discharge Process)

  • 정재우;이용환;박경렬
    • 한국대기환경학회지
    • /
    • 제18권3호
    • /
    • pp.173-182
    • /
    • 2002
  • We investigated the effects of operating variables, such as electrical. reactor and gas parameters on toluene removal and discharge property in the dielectric barrier discharge (DBD) process. The toluene removal was initiated with the energy transfer to the reactor by loading of voltages higher than the discharge onset value. The energy transfer and toluene removal increased with the applied voltage. Higher removal rate was observed with smooth surface electrode despite of lower energy transfer compared with the coarse electrode, because more uniform discharge can be obtained on smooth surface state. The decrease of dielectric material thickness enhanced the removal efficiency by increasing the discharge potential. The toluene removal efficiency decreased with the increase of the inlet concentration. The increase of gas retention time enhanced the removal efficiency by the increase of energy density. The oxygen and humidity contents seem to exert significant influences on the toluene removal by dominating the generation of electrons, ions, and radicals which are key factors in the removal mechanism.

The Effects of pH and Buffer Materials on the Leaching of Simulated Waste Glass

  • Kim, S.S.;Kim, J.G.;Kim, J.S.;Chun, K.S.;Lee, G.H.
    • Nuclear Engineering and Technology
    • /
    • 제30권1호
    • /
    • pp.1-7
    • /
    • 1998
  • Effects of pH, bentonite and Portland cement on the leaching of the simulated waste glass were investigated. The simulated waste glass showed the low leach rate in the neutral pH region, while the leach rate in both acidic and alkaline regions increased. Addition of bentonite to the leachant enhanced the leaching of the waste glass. When the waste glass was leached at 72$^{\circ}C$ for 36 days in the ground water with gel state Na-bentonite, approximately 2.2${\mu}{\textrm}{m}$ of the surface was corroded out and the large amount of Ti, Nd, and Zr was observed on the surface. The amount of B leached from the simulated waste glass in the presence of domestic bentonite was about three times higher than that in the presence of Aldrich bentonite as well as Portland cement.

  • PDF

확대 전열관의 비등열전달에 관한 이론적 연구 (A Theoretical Study on the Boiling Heat Transfer Performance of Tubes with Extended Surfaces)

  • 조시기
    • 태양에너지
    • /
    • 제19권2호
    • /
    • pp.45-56
    • /
    • 1999
  • The performance of vertical and horizontal tubes with extended surface of rectangular and triangular cross section was investigated theoretically for boiling heat transfer. A simple method for numerical program assuming one-dimensional heat flow was used to predict the performance of these extended surface tubes. The object of this study was to predict the effects of the height, thickness, numbers and, clearance of the extended surface on boiling heat transfer. The results showed that extended surfaces are quite effective as compared to plane surfaces especially near the bum-out point and to promote heat flux in boiling heat transfer.

  • PDF