Optical Properties of PVA Polarizing Films Surface-modified by UV Irradiation

자외선 조사에 의해 표면 개질된 PVA 편광필름의 광학특성

  • Koo, Gwang-Hoe (Dept. of Textile and Fashion Engineering, School of Advanced Materials and System Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (Dept. of Textile and Fashion Engineering, School of Advanced Materials and System Engineering, Kumoh National Institute of Technology)
  • 구광회 (금오공과대학교 신소재시스템공학부 섬유패션공학과) ;
  • 장진호 (금오공과대학교 신소재시스템공학부 섬유패션공학과)
  • Published : 2006.12.27

Abstract

Surface treatment using UV irradiation was carried out to improve optical properties of polarizing films. The effects of UV energy of the UV-treated PVA films were investigated by measuring reflectance, surface roughness, contact angles, ESCA, and ATR. Reflectance decreased at wavelength of 450 nm or less and surface roughness increased with increasing UV energy. Water contact angle increased in the irradiated PVA films and surface energy decreased with increase in w energy. An analysis showed that the OH groups were broken and some new groups were introduced such as C=C and C=O bonds together with increased $O_{1s}/C_{1s}$, resulting in the observed surface modification effect. Surface modified PVA polarizing films showed improvement in light transmittance of polarizing films at high wavelength region without deteriorating polarization efficiency, which was not affected by UV irradiation sequence during manufacturing processes such as coloring and drawing.

Keywords

References

  1. J. P. Kim and D. H. Song, Manufacture of Highly Functional PVA Film and Its Application to Polarizing Film, Polym. Sci. Technol., 15(1), 31-37(2004)
  2. W. S. Lyoo, J. H. Yeum, and J. H. Choi, Studies on the Syndiotactic Poly(Vinyl Alcohol) Polarizing Film, Polymer, 24(5), 713-720(2000)
  3. W. S. Lyoo, J. H. Yeum, J. M. Park, J. W. Kwak, J. H. Kim,S. S. Kim, B. C. Ji, and S. K. Noh, Role of Molecular Weight of Atactic Poly (Vinyl Alcohol) in the Polarizing Efficiency of PVA/ Azo Dye Complex film with High Durability, J. Appl. Polym. Sci., 96, 967-974(2005) https://doi.org/10.1002/app.20642
  4. H. Sata, M. Murayama, and S. Shimamoto, Properties and Applications of Cellulose Triacetate Film, Macromol. Symp., 208, 232-333(2004)
  5. Y. M. Park, J. H. Hwang, and K. Koo, A Study on Adhesive Properties of Cellulose Triacetate Film by Argon Low Temperature Plasma Treatment, J. Korean Soc. Dyers & Finishers, 16(5), 28-34(2004)
  6. Y. M. Park, J. H. Hwang, and K. Koo, Functional Improvement of Poly(Vinyl Alcohol) Polarized Film by $O_2$ Low Temperature Plasma Treatment, J. Korean Soc. Dyers & Finishers, 16(3), 14-21(2004)
  7. S. S. Kim, H. L. Woo, and W. S. Lyoo, A Study on the Preparation of Poly(Vinyl Alcohol) Polarizing Film, J. Korean Soc. Dyers & Finishers, 16(4), 19-25(2004)
  8. S. Y. Oh and D. Y. Shin, Durability and Polarization Characteristics of PVA Polarizing Film Prepared with a Dichroic Azo Dye, J. Korean Ind. Eng. Chem., 11(4), 426-431(2000)
  9. S. Y. Oh, J. H. Oh, and D. Y. Shin, Preparation and Polarization Characteristics of Polarizing Film Using a Dichroic Azo Dye with UV Absorbing Moiety, J. Korean Ind. Eng. Chem., 39(4), 411-416(2001)
  10. B. Gongjian, W. Yunxuan, and H. Xingzhou, Surface Modification of Polyolefine by UV Light/Ozone Treatment, J. Appl. Polym. Sci., 60, 2397-2402(1996) https://doi.org/10.1002/(SICI)1097-4628(19960627)60:13<2397::AID-APP11>3.0.CO;2-2
  11. H. Y. Nie, M. J. Walzak, B. Berno, and N. S. McIntyre, Atomic Force Microscopy Study of Polypropylene Surfaces Treated by UV and Ozone Exposure: Modification of Morphology and Adhesion Force, Appl. Surf. Sci., 144-145, 627-632(1999)
  12. C. Ton-That, D. O. H. Teare, P. A. Campbell, and R. H. Bradley, Surface Characterization of Ultraviolet-Ozone Treated PET Using Atomic Force Microscopy and X-Ray Photoelectron Spectroscopy, Surf. Sci., 433-435, 278-282(1999)
  13. L. F. Macmanus, M. J. Walzak, and N. S. McIntyre, Study of Ultraviolet Light and Ozone Surface Modification of Polypropylene, J. Polym. Sci.: Part A: Polym. Chem. Ed., 37, 2489-2501(1999) https://doi.org/10.1002/(SICI)1099-0518(19990715)37:14<2489::AID-POLA23>3.0.CO;2-G
  14. D. O. H. Teare, C. Ton-That, and R. H. Bradley, Surface Characterization and Ageing of Ultraviolet-Ozone-Treated Polymers Using Atomic Force Microscopy and X-Ray Photoelectron Spectroscopy, Surf. Interface Anal., 29, 276-283(2000) https://doi.org/10.1002/(SICI)1096-9918(200004)29:4<276::AID-SIA740>3.0.CO;2-P
  15. D. O. H. Teare, N Emmison, C. Ton-That, and R. H. Bradley, Effects of Serum on the Kinetics of CHO Attachment to Ultraviolet-Ozone Modified Polystyrene Surface, J. Colloid Interface Sci., 234, 84-89(2001) https://doi.org/10.1006/jcis.2000.7282
  16. C. J. van Oss and R. J. Good, Prediction of the Solubility of Polar Polymers by Means of Interfacial Tension Combining Rules, Langmuir, 8, 2877-2879(1992) https://doi.org/10.1021/la00048a006
  17. J. H. Lee, Influence of$CF_4$ Plasma Treatment on the Surface Characteristics of Poly(vinyl alcohol) Film, Textile Science & Engineering, 42(2), 136-141(2005)
  18. J. H. Jang, G. H. Koo, S. H. Back, I. H. Park, and E. J. Choi, Effects of Coloration Method on the Optical Properties of a Polarizing Film, Textile Science & Engineering, 43(3), 121-126(2006)