• Title/Summary/Keyword: surface degradation

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Studies on the Prediction of the Shelf-life of Kochujang through the Physicochemical and Sensory Analyses during Storage (고추장 저장 중 이화학 및 관능적 특성에 의한 유통기간 예측에 대한 연구)

  • Lee, Ki-Young;Kim, Hyung-Suk;Lee, Hyeon-Gyu;Han, Ouk;Chang, Un-Jae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.4
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    • pp.588-594
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    • 1997
  • In this study, the shelf-life of Kochujang during storage was predicted through physicochemical and sensory analyses. Amino nitrogen, lightness, characteristics of surface color, pH and number of viable cell counts in Kochujang decreased during storage, while ammonia nitrogen, titratable acidity and viscosity increased. Among the physicochemical analyses, amino nitrogen content exhibited the highest correlation with sensory score. The marginal amounts of amino nitrogen was 170.6mg%. Degradation rate of amino nitrogen was a first order reaction. Q$_{10}$-value and the activation energy of Kochujang during storage were 1.80 and 8.6kca1/mol, respectively. The shelf-life Predicted of Kochujang at each storage temperature was calculated. The shelf-life predicted was 467 days at 1$0^{\circ}C$, 261 days at 2$0^{\circ}C$ and 133 days at 35$^{\circ}C$.

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Preparation and Characterization of Electrospun PAN/TiO2 Fiber Mat by Electron Beam Irradiation (전자선 조사에 의한 PAN/TiO2 전기방사 나노섬유 제조 및 특성분석)

  • Kang, Phil-Hyun;Jeun, Joon-Pyo;Seo, Dong-Kwon;Kim, Hyun-Bin;Nho, Young-Chang
    • Polymer(Korea)
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    • v.36 no.1
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    • pp.47-52
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    • 2012
  • Abstract: In this study, PAN/$TiO_2$ fiber mats were fabricated from polyacrylonitrile (PAN) and titanium(IV) butoxide ($Ti(OBu)_4$) by an electrospinning method with various solution concentrations, applied voltages and solution flow rates. The fiber mats were irradiated with an electron beam to induce structural crosslinking and enhance photocatalytic activity. As a result, uniform and bead-free fibers without pits or cracks on surface were obtained at 5 wt% of $Ti(OBu)_4$ solution with 15 kV and 0.02 mL/min flow rate. The PAN/$TiO_2$ fiber mats were irradiated with an electron beam of 1.14 MeV acceleration voltage, 4 mA of current and $1{\times}10^4kGy$. Electron beam irradiation was enhanced the photocatalytic activity of PAN/$TiO_2$ nano fiber mat. The photocatalytic activity of the PAN/$TiO_2$ fiber mat was analyzed by degradation of methylene blue and volatile organic compounds.

Synthesis and Photocatalytic Activity of WO3-xFx Photocatalysts Using a Vapor Phase Fluorination (기상 불소화법을 이용한 WO3-xFx 광촉매의 합성 및 광분해 특성)

  • Lee, Hyeryeon;Lim, Chaehun;Lee, Raneun;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.632-639
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    • 2021
  • In this research, fluorine doping was performed to enhance the photocatalytic activities of WO3 which were measured using methylene blue dye. WO3-xFx photocatalyts were prepared by a vaper phase fluorination during a sintering for preparing WO3 photocatalysts from a WCl6 precursor. The bandgap energy of WO3 photocatalysts decreased from 2.95 eV to 2.54 eV, and the oxygen vacancies site increased by about 55% after fluorine doping. In addition, the initial degradation efficiency of methylene blue showed that the fluorine doped sample showed a 6-fold increase in photocatalytic activities from 10% to 60% compared to that of the untreated sample. It is believed that fluorine is doped to reduce the band gap of photocatalysts, enabling the catalytic activity with low energy, and that oxygen vacancies-generated surface defects increase the visible light absorption region of WO3 photocatalysts, thereby increasing photocatalytic activity. In this study, it was confirmed that fluorine-doped WO3-xFx photocatalysts with an excellent photocatalytic activity can be manufactured easily using a one-step vaper phase fluorination that does not require a post-treatment process.

A Study on the Corrosion Prevention of the Integral Series Generator for Military Vehicles (군용차량용 엔진일체형 직렬 발전기 부식 방지에 관한 연구)

  • Kang, Tae-Woo;Kim, Seong-Gon;Shin, Cheol-Ho;Lee, Kye-Sub
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.6
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    • pp.74-79
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    • 2019
  • The military vehicle produces electric power through an engine-integrated serial hybrid generator that is connected to the engine and does not have a separate generator installation space. However, depending on the mechanical characteristics of the connection between the generator and the engine, iron oxide for internal rusting and lubrication grew scattered. The iron oxide is adhered to the starter to deteriorate the starting performance, and there is a problem that the noise of the leg due to wear of the gear is increased. To solve this problem, the connection spline material and the surface treatment of the engine were improved and the shape was changed to a grease sealing type to prevent the generation of iron oxide inside. As the shape of the generator connector composing the shafting system was changed, the integrity of the structure was confirmed through the torsional endurance test. In addition, through the actual vehicle load test, it was verified that no corrosion occurred during the target life span without internal corrosion. It was confirmed that the anti-scattering structure of the grease effectively suppresses the generation of iron oxide, thereby reducing the noise generated from the generator. In this paper, we propose a fundamental solution to the degradation of the starter and the noise generation by preventing the back corrosion caused by the serial hybrid generator installed between the engine and the transmission.

A Study on the Effect of Collector Well on the Landcreep Slope (땅밀림 비탈면내 집수정 설치 효과 연구)

  • Jeon, Byeong Chu;Lee, Su Gon
    • The Journal of Engineering Geology
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    • v.29 no.2
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    • pp.123-136
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    • 2019
  • This study examines the effect of collector well installed to reduce groundwater level in the regions with the occurrence of landcreep, a soil mass movement triggered by instability on slopes. Slopes are prone to failure as a result of instability caused by its internal, topographic and geological properties as well as due to external factors such as rainfall and earthquake. In Korea during the rain season, rainfall infiltration affects the groundwater level in soil, building up porewater pressure and load, and finally drives slopes to collapse. Slope failure caused by rainfall infiltration has been leading to a drastic forest degradation. The studied slope is located adjacent to a valley, its terrain corresponds to piedmont gentle slope, while the upper part of the failure surface is steep. After reinforcing the terrain where landcreep had occurred and installing collector well on the slope, we measured the changes in the groundwater level. In order to analyze the relationship between the well and the slope, we calculated the ratio of groundwater level to rainfall before and after the installation of the collector well. As a result, it is confirmed that the ratio increases after the installation of the well, which in turn reduces the groundwater level. Analysis of the change in groundwater level after 3, 7, 15 days antecedent rainfall showed that the higher the overall groundwater level, the less the value ($r_p$) of groundwater level-rainfall ratio is, while the value becomes relatively greater when the groundwater level is low. In particular, if a slope has a large catchment basin as is in the case of the studied site, antecedent rainfall affects groundwater level in the order of 3 < 7 < 15 days.

Integrative analysis of cellular responses of Pseudomonas sp. HK-6 to explosive RDX using its xenA knockout mutant (Pseudomonas sp. HK-6의 xenA 돌연변이체를 이용하여 RDX 폭약에 노출된 세포반응들의 통합적 분석)

  • Lee, Bheong-Uk;Choi, Moon-Seop;Seok, Ji-Won;Oh, Kye-Heon
    • Korean Journal of Microbiology
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    • v.54 no.4
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    • pp.343-353
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    • 2018
  • Our previous research demonstrated the essential role of the xenB gene in stress response to RDX by using Pseudomonas sp. HK-6 xenB knockout. We have extended this work to examine the cellular responses and altered proteomic profiles of the HK-6 xenA knockout mutant under RDX stress. The xenA mutant degraded RDX about 2-fold more slowly and its growth and survival rates were several-fold lower than the wild-type HK-6 strain. SEM revealed more severe morphological damages on the surface of the xenA mutant cells under RDX stress. The wild-type cells expressed proportionally-increased two stress shock proteins, DnaK and GroEL from the initial incubation time point or the relatively low RDX concentrations, but slightly less expressed at prolonged incubation period or higher RDX. However the xenA mutant did not produced DnaK and GroEL as RDX concentrations were gradually increased. The wild-type cells well maintained transcription levels of dnaA and groEL under increased RDX stress while those in the xenA mutant were decreased and eventually disappeared. The altered proteome profiles of xenA mutant cells under RDX stress also observed so that the 27 down-regulated plus the 3 up-regulated expression proteins were detected in 2-DE PAGE. These all results indicated that the intact xenA gene is necessary for maintaining cell integrity under the xenobiotic stress as well as performing an efficient RDX degradation process.

The Roles of Lactic Acid Bacteria for Control of Fungal Growth and Mycotoxins (곰팡이 생육 및 곰팡이 독소 생산의 억제에 있어서의 유산균의 역할)

  • Kim, Jihoo;Lee, Heeseob
    • Journal of Life Science
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    • v.30 no.12
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    • pp.1128-1139
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    • 2020
  • Over recent years, it has become evident that food and agricultural products are easily contaminated by fungi of Aspergillus, Fusarium, and Penicillium due to rapid climate change, which is not only a global food quality concern but also a serious health concern. Owing to consumers' interest in health, resistance to preservatives such as propionic acid and sorbic acid (which have been used in the past) is increasing, so it is necessary to develop a substitute from natural materials. In this review, the role of lactic acid bacteria as a biological method for controlling the growth and toxin production of fungi was examined. According to recent studies, lactic acid bacteria effectively inhibit the growth of fungi through various metabolites such as organic acids with low molecular weight, reuterin, proteinaceous compounds, hydroxy fatty acids, and phenol compounds. Lactic acid bacteria effectively reduced mycotoxin production by fungi via adsorption of mycotoxin with lactic acid bacteria cell surface components, degradation of fungal mycotoxin, and inhibition of mycotoxin production. Lactic acid bacteria could be regarded as a potential anti-fungal and anti-mycotoxigenic material in the prevention of fungal contamination of food and agricultural products because lactic acid bacteria produce various kinds of potent metabolic compounds with anti-fungal activities.

A Study on Rust Cleaning of Various Industrial Equipment Using Cosmetic and Food Materials (화장품과 식품 재료를 이용한 각종 산업장비 녹(rust) 세정에 관한 연구)

  • Yeom, Seok-Jae;Jung, Sundo;Oh, Eunha
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.1
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    • pp.19-28
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    • 2021
  • Corrosion is the degradation of metals by reaction with the environment. It is difficult to completely remove. Corrosion proceeds rapidly after the protective barrier is destroyed, and several reactions occur that alter the composition and properties of the metal surface and local environments, such as diffusion of metal cations into the matrix, the formation of oxides, and local pH changes. The study of corrosion of steel and iron is of theoretical and practical interest and is receiving considerable attention. Acid solutions, which are widely used in industrial pickling, acid descaling, cleaning and acidification of oil wells, require the use of corrosion inhibitors to suppress corrosion attacks on metallic materials. Physical removal of rust requires expensive special equipment, and chemical removal of it can cause corrosion or shorten the life of the metal. In this study, an eco-friendly rust cleaner was developed using cosmetics and food materials by applying the concept of perm reducing agent and chelate, and applied to remove rust from industrial and hot water pipes and various industrial devices. As a result, it was found that rust cleaners remove rust more effectively and safely compared to conventional treatment methods. At the same time, the rust removal efficiency was 1.75 to 2.5 times better for industrial piping and 1.56 to 2.2 times better for boiler hot water than conventional methods.

Effect of Curing Solution and Pre-Rust Process on Rebar Corrosion in the Cement Composite (시멘트 복합체 내부 철근 부식에 양생 용액과 철근 사전 부식이 미치는 영향)

  • Du, Rujun;Jang, Indong;Lee, Hyerin;Yi, Chongku
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.2
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    • pp.1-8
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    • 2022
  • The corrosion of reinforcement is the main reason for the performance degradation of concrete structures. The pre-rusted parts of rebar in concrete structures are vulnerable to the corrosion, especially if the structure is exposed to wet or chlorinated environments. In this study, effects of different curing solution on corrosion behavior of the pre-rusted rebars in the cement composites were investigated. HCl(3%) and CaCl2(10%) solution were utilized to accelerate the pre-rust of the rebar, and each pre-rust condition rebar including reference (RE) were placed in mortar cylinder. Three kinds of samples then were cured in CaCl2 (3%) solution and tap water respectively for 120 days. Electrochemical polarization and half-cell potential measurement were used to monitor the influence of curing water on the corrosion behavior of pre-rusted steel bar in cement composite. The surface morphology and composition of corroded steel bar were analyzed by scanning electron microscope and energy dispersive X-ray diffraction. The results show that the corrosion rates of pre-rusted samples in both curing water are higher than that of non-pre-rusted samples. The corrosion rates of RE, CaCl2 and HCl pre-rusted samples in salt water were 8.14, 4.48, 13.81 times higher than those in tap water respectively, on the 120th day.

A Study on the Frictional Characteristics of Fiber Reinforced Composites under Corrosive Environment (부식 환경 하에서의 섬유강화복합재료의 마찰 및 마모 특성 연구)

  • Choong-Yong Park;Dong-Hyun Park;Soo-Jeong Park;Yun-Hae Kim
    • Composites Research
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    • v.36 no.1
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    • pp.37-41
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    • 2023
  • The treated water inside the ballast electrolytic cell creates a highly alkaline atmosphere due to hydroxide generated at the DSA(Dimension Stable Anode) electrode during electrolysis. In this study, a composite material that can replace the weakness of the PE-coated steel pipe used in the existing ballast pipe was prepared. The test samples are BRE(Basalt fiber reinforced epoxy), BRP(Basalt fiber reinforced unsaturated polyester), GRE(Glass fiber reinforced epoxy), and GRP(Glass fiber reinforced unsaturated polyester). And then it was immersed in NaOH for 720 hours. The friction test of each specimen was conducted. The Friction coefficient analysis according to material friction depth and interfacial adhesion behavior between resin and fiber were analyzed. As a result, the mechanism of interfacial separation between resin and fiber could be analyzed. In the case of the unsaturated polyester resin with low interfacial bonding strength the longer the immersion time in the alkaline solution, the faster the internal deterioration caused by the deterioration that started from the surface, resulting in a decrease in the friction coefficient. It is hoped that this study will help to understand the degradation behavior of composite materials immersed in various chemical solutions such as NaOH, acid, and sodium hypochlorite in the future.