• Title/Summary/Keyword: surface accumulation

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Study on Corrosion of Automotive Coil Spring Steel by Electrochemical Impedance Spectroscopy (전기화학 임피던스 분석을 통한 자동차용 코일스프링 강의 부식 평가)

  • Lee, Kyu Hyuk;Park, Jung-Hyun;Ahn, Seung Ho;Seo, Ji Won;Jang, HeeJin
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.298-304
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    • 2017
  • Coil spring steels from the automobile suspension part after field exposure for 10 years and those after anti-corrosion validation test in proving ground of 5,000 ~ 10,000 km were examined for corrosion damages. Partial loss of paint, accumulation of corrosion product, and cracking of paint and superficial material were observed. The surface and subsurface region of spring steels had compressive residual stress and high hardness by shot peening. The surface hardness values of the specimens were 620 ~ 670 Hv. They were 60 ~ 80 Hv higher than those of the samples taken from the middle part of the spring. The maximum compressive stress was -916 ~ -1208 MPa measured at depth of about $100{\mu}m$. Electrochemical impedance spectroscopy showed that the resistances of charge transfer and the paint layer of the spring steels ranged from several tens to millions ${\Omega}{\cdot}cm^2$. The resistance of the field samples was much higher than that of the proving ground samples used in this study, implying that the proving ground test condition would be more corrosive than the field environment.

Current-Time Characteristics of Arachidic acid LB Thin Films (Arachidic acid LB박막의 전류-시간 특성)

  • Chon, Donn-Kyu;Chang, Hun;Choi, Young-I1;Kim, Young-Heun;Kang, Young-Chul;Choi, Chung-Seog;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1696-1698
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    • 2000
  • We give pressure stimulation into long chain fatty acid of LB thin films then manufacture a device under the accumulation condition that the state surface pressure is 20[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Arachidic acid/Al, the number of accumulated layers are 13, 17 and 19. The I-V characteristic of the device is measured from 0[V] to +1.5[V] and the capacitor. The maximum value of measured current is increased as the number of accumulated layers are decreased. The capacitor properties of a thin film is better as the distance between electrodes is smaller.

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Breakdown Voltage and Electrical Characteristics of Organic Thin Film (유기박막의 파괴전압과 전기특성)

  • Song, Jin-Won;Kang, Yong-Chul;Kim, Hyung-Gon;Lee, Woo-Sun;Chung, Hun-Sang;Chang, Hee-Dong;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1497-1499
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    • 2000
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 30 [mN/m]. LB layers of Arac. acid deposited by LB method were deposited onto y-type silicon wafer as y-type film. In processing of a device manufacture. we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/arachidic acid/Al. the number of accumulated layers are 9$\sim$21. Also. we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from -3 to +3[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

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Square Wave Voltammetric Determination of Indole-3-acetic Acid Based on the Enhancement Effect of Anionic Surfactant at the Carbon Paste Electrode

  • Zhang, Sheng-Hui;Wu, Kang-Bing
    • Bulletin of the Korean Chemical Society
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    • v.25 no.9
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    • pp.1321-1325
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    • 2004
  • Sodium dodecyl sulfate (SDS), an anionic surfactant, can strongly adsorb at the surface of a carbon paste electrode (CPE) via the hydrophobic interaction. In pH 3.0 $Na_2HPO_4$-citric acid buffer (Mcllvaine buffer) and in the presence of SDS, the cationic indole-3-acetic acid (IAA, $pK_a$ = 4.75) was highly accumulated at the CPE surface through the electrostatic interaction between the negative-charged head group of SDS and cationic IAA, compared with that in the absence of SDS. Hence, the oxidation peak current of IAA increases greatly and the oxidation peak potential shifts towards more negative direction. The experimental parameters, such as pH, varieties of surfactants, concentration of SDS, and scan rate were optimized for IAA determination. The oxidation peak current is proportional to the concentration of IAA over the range from $5\;{\times}\;10^{-8}$ mol/L to $2\;{\times}\;10^{-6}$ mol/L. The detection limit is $2\;{\times}\;10^{-8}$ mol/L after 3 min of accumulation. This new voltammetric method was successfully used to detect IAA in some plant leaves.

A study on the I-V Properties of Long Chain Fatty Acid of LB Thin Films (장쇄지방산 LB박막의 전류-전압 특성에 관한 연구)

  • Chon, Dong-Kyu;Chang, Hun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.913-919
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    • 2000
  • We give pressure stimulation into long chain fatty acid of LB thin films then manufacture a device under the accumulation condition that the state surface pressure is 20[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Arachidic acid/Al, the number of accumulated layers are 13, 17 and 19. The I-V characteristic of the device is measured from 0[V] to +1.5[V]. We have investigated the capacitance because this fatty acid system have a accumulated layers. The maximum value of measured current is increased as the number of accumulated layers are decreased. The capacitor properties of a thin film is better as the distance between electrodes is smaller. The results have shown the insulating materials and could control the conductivity by accumulated layers.

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Surface Structure Image of Stearic acid Organic Thin Films (Stearic acid 유기박막의 표면구조 Image)

  • Chang, Hun;Song, Jin-Won;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.562-564
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    • 2001
  • Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic matter thin film that accumulate molecular film in archaism board only that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. The stable images are probably due to a strong interaction between the monolayer film and glass substrate. We are unable to obtain molecule resolution in images of the films but did see a marked contrast between images of the bare substrate and those with the network structure film deposited onto it. Formation that prevent when gas phase state and liquid phase state measure but Could know organic matter that molecules form equal and stable film when molecules were not distributed evenly, and accumulated in solid state only.

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A Study on the Electronic Properties of LB Thin Films (LB박막의 전자이동 특성에 관한 연구)

  • Song, Jin-Won;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.08a
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    • pp.101-104
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    • 2002
  • Abstract We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Al; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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Numerical analysis of offshore monopile during repetitive lateral loading

  • Chong, Song-Hun;Shin, Ho-Sung;Cho, Gye-Chun
    • Geomechanics and Engineering
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    • v.19 no.1
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    • pp.79-91
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    • 2019
  • Renewed interest in the long-term pile foundations has been driven by the increase in offshore wind turbine installation to generate renewable energy. A monopile subjected to repetitive loads experiences an evolution of displacements, pile rotation, and stress redistribution along the embedded portion of the pile. However, it is not fully understood how the embedded pile interacts with the surrounding soil elements based on different pile geometries. This study investigates the long-term soil response around offshore monopiles using finite element method. The semi-empirical numerical approach is adopted to account for the fundamental features of volumetric strain (terminal void ratio) and shear strain (shakedown and ratcheting), the strain accumulation rate, and stress obliquity. The model is tested with different strain boundary conditions and stress obliquity by relaxing four model parameters. The parametric study includes pile diameter, embedded length, and moment arm distance from the surface. Numerical results indicate that different pile geometries produce a distinct evolution of lateral displacement and stress. In particular, the repetitive lateral load increases the global lateral load resistance. Further analysis provides insight into the propagation of the shear localization from the pile tip to the ground surface.

A Study on the Adsorption Kinetics of 133Cs by Different Impregnations of Prussian Blue (프러시안 블루 고정화에 따른 133Cs의 흡착거동 모델링)

  • Choi, S.S.;Lee, Y.J.;Yun, K.J.;Cho, Y.J.;Lee, J.H.;Lee, S.H.
    • Journal of the Korean Society of Safety
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    • v.36 no.1
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    • pp.80-85
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    • 2021
  • Radionuclides, particularly radioactive cesium (Cs), are a concern of human health in some nuclear power accidents. It could lead to a high level of intracellular accumulation due to its high radioactivity and long half-life. Therefore, it is imperative to develop a method to remove Cs from wastewater. Herein, we synthesized activated carbon fibers (ACFs) doped with Prussian blue (PB) via in situ methods. We classified samples by their preparation method as either physical (PB-ACF-A) or physicochemical (PB-ACF-B) syntheses for comparison. The PB-ACF-B sample showed a significant surface loss compared to PB-ACF-A but a better 133Cs adsorption capacity. All samples fit well to Langmuir isotherms and the values of qmax were directly correlated to the amount of PB on the surface of the ACFs. Adsorption characteristics were further confirmed by the calculated free energy, enthalpy, and entropy.

Calculation of fuel temperature profile for heavy water moderated natural uranium oxide fuel using two gas mixture conductance model for noble gas Helium and Xenon

  • Jha, Alok;Gupta, Anurag;Das, Rajarshi;Paraswar, Shantanu D.
    • Nuclear Engineering and Technology
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    • v.52 no.12
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    • pp.2760-2770
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    • 2020
  • A model for calculation of fuel temperature profile using binary gas mixture of Helium and Xenon for gap gas conductance is proposed here. In this model, the temperature profile of a fuel pencil from fuel centreline to fuel surface has been calculated by taking into account the dilution of Helium gas filled during fuel manufacturing due to accumulation of fission gas Xenon. In this model an explicit calculation of gap gas conductance of binary gas mixture of Helium and Xenon has been carried out. A computer code Fuel Characteristics Calculator (FCCAL) is developed for the model. The phenomena modelled by FCCAL takes into account heat conduction through the fuel pellet, heat transfer from pellet surface to the cladding through the gap gas and heat transfer from cladding to coolant. The binary noble gas mixture model used in FCCAL is an improvement over the parametric model of Lassmann and Pazdera. The results obtained from the code FCCAL is used for fuel temperature calculation in 3-D neutron diffusion solver for the coolant outlet temperature of the core at steady operation at full power. It is found that there is an improvement in calculation time without compromising accuracy with FCCAL.