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Study on Corrosion of Automotive Coil Spring Steel by Electrochemical Impedance Spectroscopy

전기화학 임피던스 분석을 통한 자동차용 코일스프링 강의 부식 평가

  • Lee, Kyu Hyuk (Advanced Materials Engineering, Chosun University) ;
  • Park, Jung-Hyun (Polybiotech) ;
  • Ahn, Seung Ho (Accelerated Durability Development Team, Hyundai Motor R&D Center) ;
  • Seo, Ji Won (Accelerated Durability Development Team, Hyundai Motor R&D Center) ;
  • Jang, HeeJin (Department of Materials Science and Engineering, Chosun University)
  • 이규혁 (조선대학교 첨단소재공학과) ;
  • 박중현 (폴리바이오텍) ;
  • 안승호 (현대자동차 남양연구소 가속내구개발팀) ;
  • 서지원 (현대자동차 남양연구소 가속내구개발팀) ;
  • 장희진 (조선대학교 재료공학과)
  • Received : 2017.11.22
  • Accepted : 2017.12.19
  • Published : 2017.12.31

Abstract

Coil spring steels from the automobile suspension part after field exposure for 10 years and those after anti-corrosion validation test in proving ground of 5,000 ~ 10,000 km were examined for corrosion damages. Partial loss of paint, accumulation of corrosion product, and cracking of paint and superficial material were observed. The surface and subsurface region of spring steels had compressive residual stress and high hardness by shot peening. The surface hardness values of the specimens were 620 ~ 670 Hv. They were 60 ~ 80 Hv higher than those of the samples taken from the middle part of the spring. The maximum compressive stress was -916 ~ -1208 MPa measured at depth of about $100{\mu}m$. Electrochemical impedance spectroscopy showed that the resistances of charge transfer and the paint layer of the spring steels ranged from several tens to millions ${\Omega}{\cdot}cm^2$. The resistance of the field samples was much higher than that of the proving ground samples used in this study, implying that the proving ground test condition would be more corrosive than the field environment.

Keywords

References

  1. K. D. Park, W. T. Ki, and Y. J. Sin, Transactions of KSAE, 15, 1 (2007).
  2. D. L. Seo, J. W. Park, E. J. Jun, and H. O. Ban, Proc. KSAE Conf., p. 1344, KSAE, Gyeongju, Korea (2012).
  3. G. Y. Lee, D. H. Bae, S. C. Park, and W. W. Jung, Proc. KSAE Conf. p. 102, KSAE, Pyeongchang, Korea (2004).
  4. D. H. Bae, G.Y. Lee, and W. S. Jung, Key engineering materials, 306-308, 459 (2006). https://doi.org/10.4028/www.scientific.net/KEM.306-308.459
  5. D. H. Bae, G. Y. Lee, W. S. Jung, S. C. Park, and W. W. Jung, Key Engineering Materials, 297-300, 357 (2005). https://doi.org/10.4028/www.scientific.net/KEM.297-300.357
  6. J. Matejicek, P. C. Brand, A. R. Drews, A. Krause, and C. Lowe-Ma, Materials Science and Engineering: A, 367, 306 (2004). https://doi.org/10.1016/j.msea.2003.10.322
  7. S. K. Das, N. K. Mukhioadhyay, B. Ravi Kumar, and D. K. Bhattacharya, Engineering Failure Analysis, 14, 158 (2007). https://doi.org/10.1016/j.engfailanal.2005.11.012
  8. L. Del Llano-Vizcaya, C. Rubio-Gonzalez, G. Mesmacque, and A. Banderas-Hernandez, Materials & design, 28, 1130 (2007). https://doi.org/10.1016/j.matdes.2006.01.033
  9. H. Mano, S. Kondo, and A. Matsumuro, Proc. 2006 International Symposium on Micro-NanoMechatronics and Human Science Conf., p. 1, IEEE, Nagoya, Japan (2006).
  10. G. J. Kim and M. S. Thesis, pp. 44-46, Korea Polytechnic University, Seoul (2001).
  11. M. S. Lim, Cold coil spring heat treatment method for improvement of inner side residual stress and fatigue life, 10-2013-0127481 (2013.10.25).
  12. M. S. Lim, Surface treatment method of coil spring, 10-2011-0116842 (2011.11.10).
  13. I. Kazuya, Compression coil spring and method for producing same, 10-2015-7009184 (2011.08.11).
  14. T. Akira, Coil spring for a suspension of an automobile and manufacturing method thereof, 10-2010-7006561 (2009. 06. 17).
  15. H. G. Go, Spring manufacturing method, 10-2014-0133138 (2014.10.02).
  16. W. Smith, Structure and properties of Engineering Alloys 2nd ed., pp. 29-32, McGraw-Hill, New York (1990).
  17. Y. Nakajima and K. Tone, Materials of Automotive, p. 122, Golden bell, Seoul (1997).

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