• 한국소음진동공학회논문집
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• 제13권7호
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• pp.555-561
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• 2003

An iterative modal analysis approach is developed to determine the effect of transverse open cracks on the dynamic behavior of simply supported Euler-Bernoulli beams with the moving masses. The influences of the velocities of moving masses, the distance between the moving masses and a crack have been studied on the dynamic behavior of a simply supported beam system by numerical method. The Presence of crack results In large deflection of beam. The crack section is represented by a local flexibility matrix connecting two undamaged beam segments i.e. the crack is modelled as a rotational spring. This flexibility matrix defines the relationship between the displacements and forces across the crack section and is derived by applying fundamental fracture mechanics theory. Totally, as the velocity of the moving masses and the distance between the moving masses are increased, the mid-span deflection of simply supported beam with the crack is decreased.

• 한국소음진동공학회논문집
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• 제26권1호
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• pp.27-38
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• 2016

The purpose of this study is to investigate the influence of moving mass on the vibration characteristics and the dynamic response of the simply supported beam. The three types of the moving mass(moving load, unsprung mass, and sprung mass) are applied to the vehicle-bridge interaction analysis. The numerical analyses are then conducted to evaluate the effect of the mass, spring and damper properties of the moving mass on natural frequencies and dynamic responses of the simply supported beam. Particularly, in the case of the sprung mass, variations of the natural frequency of simply supported beam are explored depending on the position of the moving mass and the frequency ratio of the moving mass and the beam. Finally the parametric studies on the resonance phenomena are performed with changing mass, spring and damper parameters through the dynamic interaction analyses.

• 한국실천공학교육학회논문지
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• 제4권2호
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• pp.24-32
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• 2012

본 연구에서는 온라인 학습환경에서 수강자들간 발생하는 스터디 그룹의 유형과 그 특성을 밝히고자 한다. 이를 위하여 Neiderman & Beise(1999)의 네 가지 이론적 유형(typology)을 바탕으로 연구분석틀을 구성하고, 실제 데이터를 활용하여 실증적 유형(taxanomy)을 도출하고자 하였다. 데이터는 259명의 두 개 대학교 대학생을 대상으로 구성된 46개 팀을 대상으로 하였다. 군집분석 결과 실증적 유형은 Neiderman & Beise(1999)의 이론적 유형에서 수동적 유형(inactive type)을 제외하고 세 가지의 유형이 도출되었다. 또한 학습성과 측면에서는 온오프라인 전방위활용(fully-supported) 유형의 성과가 상대적으로 가상중심형(highly-virtual) 유형 보다 높은 것으로 나타났다.

• 신재생에너지
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• 제2권4호
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• pp.64-69
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• 2006

There is a worldwide interest in the development and commercialization of polymer electrolyte membrane fuel cells [PEMFCs] for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the supporting of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an alloying process occurred during the successive reducing process. The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one [Johnson-Matthey] for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.213-213
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• 2011

Gold catalysts supported on TiO2 have shown a unique catalytic behavior on CO oxidation, depending on surface effects. Particle size has an influence on the surface activity. To make monodisperse Au nanoparticles, organic capping ligands, such as alkylthiols, were used by a "greener" synthesis method [1,2] and Au nanoparticles were deposited on TiO2. However, organic capping ligands must be removed for high catalytic activities by the Au nanoparticles without changing the Au size [3]. We used UV ozone treatment to decompose thiol ligands. The samples have been characterized by X-ray photoelectron spectroscopy to examine the surface modification by UV ozone treatment. We show the size distribution of the gold nanoparticles by light scattering analysis and transmission electron microscopy. Au/TiO2 have been prepared using the wetness impregnation method. The catalytic performance of CO oxidation over Au supported on TiO2 under oxidizing reaction conditions (40 Torr CO and 100 Torr O2) were tested. The results show that the catalytic activity depends on particle size and the time of UV ozone exposure, which suggests the role of sulfur bonding in determining the catalytic activity of Au/TiO2 catalysts.

• Molecules and Cells
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• 제22권1호
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• pp.78-88
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• 2006

The phylogeny of the subfamily Tephritinae (Diptera: Tephritidae) was reconstructed from mitochondrial 16S ribosomal RNA gene sequences using 53 species representing 11 currently recognized tribes of the Tephritinae and 10 outgroup species. The minimum evolution and Bayesian trees suggested the following phylogenetic relationships: (1) monophyly of the Tephritinae was strongly supported; (2) a sister group relationship between the Tephritinae and Plioreocepta was supported by the Bayesian tree; (3) the tribes Tephrellini, Myopitini, and Terelliini (excluding Neaspilota) were supported as monophyletic groups; (4) the non-monophyletic nature of the tribes Dithrycini, Eutretini, Noeetini, Tephritini, Cecidocharini, and Xyphosiini; and (5) recognition of 10 putative tribal groups, most of which were supported strongly by the statistical tests of the interior branches. Our results, therefore, convincingly suggest that an extensive rearrangement of the tribal classification of the Tephritinae is necessary. Since our sampling of taxa heavily relied on the current accepted classification, some lineages identified by the present study were severely under-sampled and other possible major lineages of the Tephritinae were probably not even represented in our dataset. We believe that our results provide baseline information for a more rigorous sampling of additional taxa representing all possible major lineages of the subfamily, which is essential for a comprehensive revision of the tephritine tribal classification.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3283-3290
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• 2010

The gas-phase dehydration of glycerol to acrolein was carried out over 10 wt % HSiW catalysts supported on different supports, viz. $\gamma-Al_2O_3$, $SiO_2-Al_2O_3$, $TiO_2$, $ZrO_2$, $SiO_2$, AC, $CeO_2$ and MgO. The same reaction was also conducted over each support without HSiW for comparison. Several characterization techniques, $N_2$-physisorption, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), the temperature-programmed desorption of ammonia ($NH_3$-TPD), temperature-programmed oxidation (TPO) with mass spectroscopy and CHNS analysis were employed to characterize the catalysts. The glycerol conversion generally increased with increasing amount of acid sites. Ceria showed the highest 1-hydroxyacetone selectivity at $315^{\circ}C$ among the various metal oxides. The supported HSiW catalyst showed superior catalytic activity to that of the corresponding support. Among the supported HSiW catalysts, HSiW/$ZrO_2$ and HSiW/$SiO_2-Al_2O_3$ showed the highest acrolein selectivity. In the case of HSiW/$ZrO_2$, the initial catalytic activity was recovered after the removal of the accumulated carbon species at $550^{\circ}C$ in the presence of oxygen.

• 대한공간정보학회지
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• 제8권1호
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• pp.13-25
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• 2000

도로교통환경문제는 현대의 도시생활에 있어서 세계공통의 심각한 환경문제의 하나이다. 본 연구에서는 도로교통환경문제, 특히 도로교통에 기인하는 대기오염문제의 평가를 위한 지원시스템을 개발하였다. 본 개발시스템은 GIS, 교통관련의 대기오염시뮬레이션모델, 예비적 대책들의 데이타베이스로 구성되어 있다. 대기오염시뮬레이션모델의 구축에 있어서, GIS지원환경은 연구대상지역의 대량의 공간정보의 처리와 실제위치상에서의 보다 정확한 대기오염의 계산이라는 점에서 유용한 툴(tool)을 제공할 수 있다. GIS지원시스템의 이러한 역할은 보다 효율적인 분석과 보다 합리적인 결정을 위하여 매우 유용한 것이다. 본 연구에서 개발된 시스템의 실용성은 이집트 카이로시의 도시권을 연구대상지역으로 적용함으로써 그 가능성을 확인할 수 있었다.

• 한국응용과학기술학회지
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• 제25권1호
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• pp.65-72
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• 2008

The ion exchangers supported on silica gel containing primary, secondary, or tertiary amine groups show a behaviour that is weakly acidic, while the quaternary salts are strongly acidic. These properties change according to the hydrophilicities of the modifier functional groups. Ammonium salt derivatives supported on silica gel were prepared from silica modified with 3-Aminopropyltriethoxysiliane and N-3-(Trimethoxysilyl)propylehtylene diamine. The preparation and the ion exchange properties of two systems were discussed. Two systems have different hydrophilicities and contain ammonium chloride derivatives of 3-amminopropyltriethoxysilane and N-3-(triehtoxysilyl)propyl ethylene diamine supported on silica gel, $SA^+/Cl^-$ and $SA^+/Cl^-$, respectively. The high affinity to perchlorate ion presented by the $SA^+/Cl^-$ through the equilibrium studies of ion exchange led us to its application as an ion selective electrode for the perchlorate ion. The determination of the perchlorate ion in the presence of other anions and in complexes is very difficult. Few analytical methods are available and most of them are indirect. Both materials showed potential use as an ion exchanger; they are thermically stable, achieve equilibrium rapidly in the presence of suitable exchanger ions, and are easily recovered.

• Carbon letters
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• 제8권2호
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• pp.120-126
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• 2007

The effect of cobalt precursor on the structure of Co supported multi-walled carbon nanotubes (MWCNTs) were studied by using X-ray photoelectron spectroscopy (XPS). MWCNTs were treated with a mixture of nitric and sulfuric acids and decorated with cobalt and/or cobalt oxides via aqueous impregnation solutions of cobalt nitrate or cobalt acetate followed by reduction in hydrogen. XPS was mainly used to investigate the phase of cobalt on MWCNTs after reduction with $H_2$ flow at $400^{\circ}C$ for 2 h. Higher cobalt-nanoparticle dispersion was found in the MWCNTS prepared via cobalt nitrate decomposition. A typical XPS spectrum of Co 2p showed the peaks at binding energy (BE) values equal to 781 and 797 eV, respectively. It is found that cobalt nitrate supported MWCNTs is more dispersive and have catalytic activity than that of cobalt acetate supported MWCNTs at same preparation condition such as concentration of precursor solution and reduction environment.