• Title/Summary/Keyword: superconducting transition temperature

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(TlPbBi)-(SrBa)-Ca-Cu-O superconducting films obtained by electrodeposition process

  • 백상민;이준호;김봉준;박기곤;김영철;정대영;심윤보
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.157-161
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    • 2003
  • We have performed the electrochemical method to fabricate high temperature superconducting (TlPbBi) -(SrBa)-Ca-Cu-O films. The precursors of the superconducting sample were codeposited at a periodic pulsed-potential cycle (1 second at -4V and 1 second at -1V) on a silver substrate. The variation of structure, microstructure and element were analysed by ICP and SEM techniques. The specimens were consisted predominantly of the Tl-1212 phase and have a transition temperature of 80~87 K in low magnetic field. It was showed that each grain has the stoichiometric ratio of $T1_{0.7}$Pb_$Bi_{0.3}$ $_Sr{0.1}$ $Ba_{2.4}$ $Ca_{0.2}$ $Cu_{1.2}$ $2.5/O_{x}$ by EDX analysis.sis.

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Fabrication of YBCO superconducting film with $CeO_{2}/BaTiO_{3}$double buffer layer ($CeO_{2}/BaTiO_{3}$ 이중완충막을 이용한 YBCO 박막 제작)

  • 김성민;이상렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.790-793
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    • 2000
  • We have fabricated good quality superconducting YBa$_2$Cu$_3$$O_{7-x}$(YBCO) thin films on Hastelloy(Ni-Cr-Mo alloys) metallic substrates with CeO$_2$and BaTiO$_3$buffer layers in-situ by pulsed laser deposition in a multi-target processing chamber. YBCO film with CeO$_2$ single buffer layer shows T$_{c}$ of 71.64 K and the grain size less than 0.1 ${\mu}{\textrm}{m}$. When BaTiO$_3$is used as a single buffer layer, the grain size of YBCO is observed to be larger than that of YBCO/CeO$_2$by 200 times and the transition temperature of the film is enhanced to be about 84 K. CeO$_2$/BaTiO$_3$double buffer layer has been adopted to enhance the superconducting properties, which results in the enhancement of the critical temperature and the critical current density to be about 85 K and 8.4 $\times$ 10$^4$ A/cm$^2$ at 77 K, respectively mainly due to the enlargement of the grain size of YBCO film.ilm.

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Fabrication of YBCO Superconducting Film with $CeO_2$/$BaTiO_3$Double Buffer Layer ($CeO_2$/$BaTiO_3$이중완충막을 이용한 YBCO 박막 제작)

  • 김성민;이상렬
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.11
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    • pp.959-962
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    • 2000
  • We have fabricated good quality superconducting YBa$_2$Cu$_3$$O_{7-x}$(YBCO) thin films on Hastelloy(Ni-Cr-Mo alloys) metallic substrates with CeO$_2$and BaTiO$_3$buffer layers in-situ by pulsed laser deposition in a multi-target processing chamber. YBCO film with CeO$_2$single buffer layer shows T$_{c}$ of 71.64 K and the grain size less than 0.1${\mu}{\textrm}{m}$. When BaTiO$_3$ is used as a single buffer layer, the grain size of YBCO is observed to be larger than that of YBCO/CeO$_2$by 200 times and the transition temperature of the film is enhanced to be about 84 K. CeO$_2$/BaTiO$_3$double buffer layer has been adopted to enhance the superconducting properties, which results in the enhancement of the critical temperature and the critical current density to be about 85 K and 8.4$\times$10$^4$ A/$\textrm{cm}^2$ at 77 K, respectively mainly due to the enlargement of the grain size of YBCO film.ilm.

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Analysis of the local superconducting properties in YBCO coated conductors with striations

  • Kim, Muyong;Park, Sangkook;Park, Heeyeon;Ri, Hyeong-Cheol
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.2
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    • pp.25-30
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    • 2015
  • In order to realize economical applications, it is important to reduce the ac loss of 2G high-temperature superconductor coated conductors. It seems to be reasonable that a multi-filamentary wire can decrease the magnetization loss. In this study, we prepared two samples of YBCO coated conductors with striations. We measured local superconducting properties of both samples by using Low Temperature Scanning Laser and Hall Probe Microscopy (LTSLHPM). The distribution of the local critical temperature of samples was analyzed from experimental results of Low Temperature Scanning Laser Microscopy (LTSLM) near the superconducting transition temperature. According to LTSLM results, spatial distributions of the local critical temperature of both samples are homogeneous. The local current density and the local magnetization in samples were explored from measuring stray fields by using Scanning Hall Probe Microscopy (SHPM). From SHPM results, the remanent field pattern of the one bridge sample in an external magnetic field confirms the Bean's critical state model and the three bridge sample has similar remanent field pattern of the one bridge sample. The local magnetization curve in the three bridge sample was measured from external fields from -500 Oe to 500 Oe. We visualized that the distribution of local hysteresis loss are related in the distribution of the remanent field of the three bridge sample. Although the field dependence of the critical current density must be taken into account, the relation of the local hysteresis loss and the remanent field from Bean's model was useful.

Effects of Nano FexC Addition on Superconducting Properties of MgB2 (MgB2 초전도 특성에 대한 나노 FexC 첨가 효과)

  • Lee, Dong-Gun;Lee, Ji-Hyun;Jun, Byung-Hyuk;Park, Soon-Dong;Uhm, Young-Rang;Park, Hai-Woong;Kim, Chan-Joong
    • Journal of Powder Materials
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    • v.19 no.2
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    • pp.146-150
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    • 2012
  • The effects of nano $Fe_xC$ addition to superconducting properties of $in$ $situ$ processed $MgB_2$ superconductors was examined. 0.1 wt.% and 1 wt.% nano $Fe_xC$ powders were mixed with boron and magnesium powders by ball milling. The powder mixtures were made into pellets by uniaxial pressing. The pellets were heat-treated at $700^{\circ}C-900^{\circ}C$ in argon atmosphere for $MgB_2$ formation. It was found by powder X-ray diffraction that the raw powders were completely converted into $MgB_2$ after the heat treatment. The superconducting transition temperature ($T_c$) and critical current density ($J_c$), estimated from susceptibility-temperature and $M-H$ curves, were decreased by nano $Fe_xC$ addition. The $T_c$ and $J_c$ decrease by nano $Fe_xC$ addition are attributed to the incorporation of iron and carbon with $MgB_2$ lattices (Fe substitution for Mg and C substitution for B) due to the high reactivity of the nano $Fe_xC$ powder.

Effect of CeO$_2$ buffer layer on the crystallization of YBCO thin film on Hastelloy substrate (비정질 금속 기판상에 증착된 YBCO 박막의 결정성에 대한 CEO$_2$ 완충막의 효과)

  • Kim, Sung-Min;Lee, Sang-Yeol
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.392-396
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    • 1999
  • Superconducting YBa$_2Cu_3O_{7-{\delta}}$(YBCO) thin films were grown on Hastelloy(Ni-Cr-Mo alloys) with CeO$_2$ buffer layer in-situ by pulsed laser deposition in a multi-target processing chamber. To apply superconducting property on power transmission line, we have deposited YBCO thin film on flexible metallic substrate. However, it is difficult to grow the YBCO films on flexible metallic substrates due to both interdiffusion problem between metallic substrate and superconducting overlayers and non-crystallization of YBCO on amorphous substrate. It is necessary to use a buffer layer to overcome the difficulties. We have chosen CeO$_2$ as a buffer layer which has cubic structure of 5.41 ${\AA}$ lattice parameter and only 0.2% of lattice mismatch with 3.82 ${\AA}$ of a-axis lattice parameter of YBCO on [110] direction of CeO$_2$ In order to enhance the crystallization of YBCO films on metallic substrates, we deposited CeO$_2$ buffer layers with varying temperature and 02 pressure. By XRD, it is observed that dominated film orientation is strongly depending on the deposition temperature of CeO$_2$ layer. The dominated orientation of CeO$_2$ buffer layer is changed from (200) to(111) by increasing the deposition temperature and this transition affects the crystallization of YBCO superconducting film on CeO$_2$ buffered Hastelloy.

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Normal-zone Propagation Properties in Oxide Superconductors (산화물 초전도선재의 상전도전파특성)

  • Kim, Seok-Beom;Ishiyama, Atsushi;Han, Kyung-Hee
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.41-43
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    • 1996
  • This paper describes on concerning electromagnetical and thermal behaviors during normal transition in Bi-2223/Ag superconducting multifilamentary tapes by conduction cooling. Some experiments were carried with operating temperature, 10-40K, and transport current as parameters in zero magnetic field. Sample tapes are transited normally with heater to intiate a quench. The voltage and temperature properties which accord to normal transition are measured by voltage taps and thermocouples attached to sample tapes, we also calculated longitudinal and transverse directions normal-zone propagation velocities from the voltage traces.

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Electrical Breakdown and Flashover Characteristics of Gaseous Helium at Cryogenic Temperature (극저온 헬륨가스의 절연파괴 및 연면방전 특성)

  • Kwag, Dong-Soon
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.3
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    • pp.38-42
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    • 2012
  • Fixtures such as bushings in terminations of high temperature superconducting(HTS) power cable systems are subjected to high voltages, which have to transition from ambient to cryogenic temperatures. As such it is imperative to ensure the integrity of the dielectrics under all operating conditions, including thermal aspects brought about by the passage of current. Gaseous helium(GHe) at high pressure is regarded as a potential coolant for superconducting cables. The dielectric aspects of cryogenic helium gas are both complex and demanding. In this experimental study we looked at the interface between a smooth epoxy surface and high pressure helium gas in a homogeneous electric field. The alternating current(AC) flashover voltages of epoxy samples are presented. The results have been analyzed by using Weibull statistics. In addition to the behavior of the epoxy in gaseous helium as a function of pressure and temperature we also present data of the characteristics of the epoxy in mineral oil and in liquid nitrogen($LN_2$). The breakdown characteristics of a uniform field gap in gaseous helium as a function of pressure and temperature under AC, direct current(DC) and lightning impulse voltages are also given. Electric field calculations have been made for one of the experimental geometries in an attempt to explain some of the anomalies in the experimental results.

Superconducting Bandpass Fitter Using Hairpin-type Microstrip Line with Narrow Bandwidth Centered at 14 GHz (14 GHz 헤어핀형 초전도 대역통과 필터)

  • Son, Seok-Cheon;Kim, Cheol-Su;Lee, Sang-Yeol;Yoon, Hyung-Kuk;Yoon, Young-Joong
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1852-1854
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    • 1999
  • In order to enhance satellite communication system performance, filters are required with the characteristics of sharp skirt, low insertion loss, and high power handling capability. But the performance of microwave passive filters is significantly declined by the conduction losses, especially in case of planar structures using film conductors. By using high temperature superconducting(HTS) film material as the conductor, higher performance could be expected. We have designed and developed narrow bandpass filters using haripin-type superconducting microstrip line for satellite communication. High quality superconducting YBCO thin films have been grown on MgO substrates by pulsed laser deposition(PLD) The deposited YBCO films were patterned by conventional wet-etching process. The transition temperatures of these films had shown 86 - 89 K. The film thicknesses were about 500 nm. Experimental results are presented for the insertion loss and return loss of the filter at 60 K.

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Superconducting Properties of (Sm/Y)-Ba-Cu-0 High Tc Composite Superconductors with CeO2 Additive by Zone-Melt Textured Growth (국부용융성장법으로 제조한 (Sm/Y)-Ba-Cu-0계 고온복합초전도체의 CeO2첨가에 따른 초전도특성)

  • 김소정
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.3
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    • pp.269-274
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    • 2002
  • (Sm/Y)-Ba-Cu-O system high Tc composite superconductors with/without $CeO_2$ additive were directionally grown by zone-melting process, haying large temperature gradient, In air atmosphere. Cylindrical green rods of $({Sm/y})_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(Sm/Y)1.8] composite oxides by cold isostatic pressing(CIP) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, SEM, TEM and SQUID magnetometer. The size of nonsuperconducting $({Sm/y})_2BaCuO_5$ inclusions of the melt-textured (Sm/Y)1.8 sample with CeO$_2$ additive were remarkably reduced and uniformly distributed within the superconducting (Sm/Y)1.8 matrix. Both samples, with/without $CeO_2$ additive, showed an onset Tc $\geq$ 90 K and sharp superconducting transition. The critical current density Jc value of the $CeO_2$ addictive were $1{\times}10^5A/\textrm{cm}^2$ in 77 K, 0 Tesla.